journal article·2023-12

One-step synthesis of ultrathin Ag nanowires with high aspect ratio and their application in transparent conductive films

Tingting Yang, Liqun Zhao, Hao Su, Xiaolei Song, Yijia Ma, Meng Hao, Donglin Jiang, Yuanbo Chen, Ying Song

Journal of Nanoparticle Research· Volume 25· Issue 12
Publisher page

Abstract

Herein, ultrathin silver nanowires (AgNWs) with high aspect ratio have been obtained by a facile one-step polyol method using FeCl3, NaBr, and NaCl as co-nucleants. Firstly, ultralong AgNWs with length in the range of 110–400 μm were synthesized by adjusting the amount of FeCl3. On the basis, NaBr and NaCl were further added to reduce the diameter of the nanowires. Eventually, ultrafine AgNWs with an average diameter in the range of 15–40 nm, length up to 110 µm, and the aspect ratio as high as 3200 have been successfully developed. The nucleation process of nanowires dependent on oxidation etching was revealed by scanning electron microscope (SEM). Flexible transparent conductive film prepared using these AgNWs owned a transmittance about 88% and square resistances of 16.5 Ω/sq. Compared with commercial ITO, transparent conductive films (TCFs) based on these AgNWs have an excellent performance and are expected to become promising candidates for flexible electronic devices.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanomaterials and Printing Technologies · Advanced Sensor and Energy Harvesting Materials · Advanced Materials and Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (30)

Show source-provided references
1. Gaynor W, Hofmann S, Christoforo MG, Sachse C, Mehra S, Salleo A, Mcgehee MD, Gather MC, Lüssem BR, Müller-Meskamp L (2013) Color in the corners: ITO-free white OLEDs with angular color stability 25:4006-401310.1002/adma.201300923 ↗
2. Zhang Y, Sun Z, Cheng S, Yan F (2016) Plasmon-induced broadband light-harvesting for dye-sensitized solar cells using a mixture of gold nanocrystals 9:813-81910.1002/cssc.201600110 ↗
3. Kim S, Kim B, Im I, Kim D, Lee H, Nam J, Kyoon Chung H, Lee H-J, Min Cho S (2017) Employment of gold-coated silver nanowires as transparent conductive electrode for organic light emitting diodes 28:345201-34521410.1088/1361-6528/aa7ba0 ↗
4. Lei T, Peng R, Song W, Hong L, Huang J, Fei N, Ge Z (2019) Bendable and foldable flexible organic solar cells based on Ag nanowire films with 10.30% efficiency 7:3737-374410.1039/C8TA11293B ↗
5. Wang S, Tian Y, Wang C, Hang C, Huang Y Liao C (2019) Chemical and thermal robust tri-layer rGO/Ag NWs/GO composite film for wearable heaters 174:76-8310.1016/j.compscitech.2019.02.022 ↗
6. Wang Y, Du D, Yang X, Zhang X, Zhao Y (2019) Optoelectronic and electrothermal properties of transparent conductive silver nanowires films 9:904-91510.3390/nano9060904 ↗
7. Liu C-H, Yu X (2011) Silver nanowire-based transparent, flexible, and conductive thin film 6:7510.1186/1556-276X-6-75 ↗
8. Lee C, Kim H, Hwang B (2019) Fracture behavior of metal oxide/silver nanowire composite electrodes under cyclic bending 773:361-36610.1016/j.jallcom.2018.09.212 ↗
9. Chapi S (2020) Optical, electrical and electrochemical properties of PCL5/ITO transparent conductive films deposited by spin-coating - materials for single-layer devices 5:322-32910.1016/j.jsamd.2020.07.005 ↗
10. Im HG, Jang J, Jeon Y, Noh J, Jin J, Lee JY, Bae BS (2020) Flexible transparent crystalline-ITO/Ag nanowire hybrid electrode with high stability for organic optoelectronics 12:56462-5646910.1021/acsami.0c17130 ↗
11. Chapi S (2021) Influence of Co2+ on the structure, conductivity, and electrochemical stability of poly(ethylene oxide)-based solid polymer electrolytes: energy storage devices 50:1558-157110.1007/s11664-020-08706-6 ↗
12. Li J, Otsuka K, Zhang X, Maruyama S, Liu J (2016) Selective synthesis of large diameter, highly conductive and high density single-walled carbon nanotubes by a thiophene-assisted chemical vapor deposition method on transparent substrates 8:14156-1416210.1039/C6NR03642B ↗
13. Savchak M, Borodinov N, Burtovyy R, Anayee M, Hu K, Ma R, Grant A, Li H, Cutshall DB, Wen Y, Koley G, Harrell WR, Chumanov G, Tsukruk V, Luzinov I (2018) Highly conductive and transparent reduced graphene oxide nanoscale films via thermal conversion of polymer-encapsulated graphene oxide sheets 10:3975-398510.1021/acsami.7b16500 ↗
14. Chebotareva AB, Untila GG, Kost TN, Stepanov AS, Salazkin SN Shaposhnikova VV (2017) Transparent conductive polymers for laminated multi-wire metallization of bifacial concentrator crystalline silicon solar cells with TCO layers 165:1-810.1016/j.solmat.2017.02.025 ↗
15. Yang J, Bao C, Zhu K, Yu T, Xu Q (2018) High-performance transparent conducting metal network electrodes for perovksitephotodetectors 10:1996-200310.1021/acsami.7b15205 ↗
16. Bai S, Guo X, Chen T, Zhang Y, Yang H (2020) Solution process fabrication of silver nanowire composite transparent conductive films with tunable work function 70910.1016/j.tsf.2020.138096 ↗
17. Wang J, Jiu J, Sugahara T, Nagao S, Nogi M, Koga H, He P, Suganuma K, Uchida H (2015) Highly reliable silver nanowire transparent electrode employing selectively patterned barrier shaped by self-masked photolithography 7:23297-2330410.1021/acsami.5b07619 ↗
18. Jon S, Sin G, Kim G, Jong G, Ri J (2020) Flexible perovskite solar cells based on AgNW/ATO composite transparent electrodes 26210.1016/j.synthmet.2019.116286 ↗
19. Li Z, Zhang X, Shan J, Liu C, Guo X, Zhao X Yang H (2022) Facile fabrication of large-scale silver nanowire transparent conductive films by screen printing 910.1088/2053-1591/ac7288 ↗
20. Bergin SM, Chen Y-H, Rathmell AR, Charbonneau P, Li Z-Y, Wiley BJ (2012) The effect of nanowire length and diameter on the properties of transparent, conducting nanowire films 4:1996-200410.1039/c2nr30126a ↗
21. Zhan K, Su R, Bai S, Yu Z, Cheng N, Wang C, Xu S, Liu W, Guo S, Zhao X-Z (2016) One-pot stirring-free synthesis of silver nanowires with tunable lengths and diameters via a Fe3+ & Cl− co-mediated polyol method and their application as transparent conductive films 8:18121-1813310.1039/C6NR04972A ↗
22. Tsuji M, Nishizawa Y, Matsumoto K, Kubokawa M, Miyamae N, Tsujiq T (2006) Effects of chain length of polyvinylpyrrolidone for the synthesis of silver nanostructures by a microwave-polyol method 60:834-83810.1016/j.matlet.2005.10.027 ↗
23. Zhu JJ, Kan CX, Wan JG, Han M, Wang GH (2011) High-yield synthesis of uniform Ag nanowires with high aspect ratios by introducing the long-chain PVP in an improved polyol process 2011:1-710.1155/2011/982547 ↗
24. Zeng X, Zhou B, Gao Y, Wang C, Li S, Yeung CY, Wen W (2014) Structural dependence of silver nanowires on polyvinyl pyrrolidone (PVP) chain length 25:495601-49560510.1088/0957-4484/25/49/495601 ↗
25. Ma J, Zhan M (2014) Rapid production of silver nanowires based on high concentration of AgNO3 precursor and use of FeCl3 as reaction promoter 4:21060-2107110.1039/c4ra00711e ↗
26. Lee EJ, Chang MH, Kim YS, Kim JY (2013) High-pressure polyol synthesis of ultrathin silver nanowires: electrical and optical properties 1:42118-4211810.1063/1.4826154 ↗
27. Zhang K, Du Y, Chen S (2015) Sub 30nm silver nanowire synthesized using KBr as co-nucleant through one-pot polyol method for optoelectronic applications 26:380-38510.1016/j.orgel.2015.08.008 ↗
28. Li Y, Yuan X, Yang H, Chao Y, Guo S, Wang (2019) One-step synthesis of silver nanowires with ultra-long length and thin diameter to make flexible transparent conductive films 12:401-41210.3390/ma12030401 ↗
29. Sun Y, Yin Y, Mayers BT, Herricks T, Xia Y (2002) Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone) 14:4736-474510.1021/cm020587b ↗
30. Jia D, Zhao Y, Wei W, Chen C, Lei G, Wan M, Tao J, Li S, Ji S, Ye C (2017) Synthesis of very thin Ag nanowires with fewer particles by suppressing secondary seeding 19:148-15310.1039/C6CE02075E ↗