Getting saturation magnetization of superparamagnetic nanoparticles more accurately from room-temperature magnetization curve
Source abstract
Abstract
The saturation magnetization ((M_s)) of a superparamagnetic (SPM) nanoparticle system is an important factor that affects the performance of nanoparticles and can reflect their other physical properties. In this work, we make a comparison between two functions that can be used to extrapolate the room temperature curve of magnetization versus the inverse magnetic field ((M-1/H) curve) to get saturation magnetization. The functions are the common linear function and the Mittag-Leffler function. Simulated (M-1/H) curves of various systems of SPM nanoparticles were fitted to the functions, and extrapolated (M_s) was obtained. For each fitting procedure, the average absolute deviations (AADs) were calculated. The systems include core-shell iron-oxide nanoparticles with mono-disperse, multi-disperse, log-normal, and bi-log-normal size distributions. The used magnetization fields were up to 20 kOe. The results showed that for each function and each system, the extrapolated (M_s) depends on the number of points of the (M-1/H) curve used in the fitting procedure. However, there are characteristic marks on the diagrams of (M_s) and AAD versus the number of points from which the correct value of (M_s) can be determined. Moreover, for mono-disperse systems with 3nm nanoparticles, the linear function leads to a better result for extrapolated (M_s) than the Mittag-Leffler function. However, for log-normal and bi-log-normal with broad size distributions, the results of the Mittag-Leffler function are better. In the other cases, investigated here, both functions lead to similar and reasonable results. Exploration of (M_s) was also performed for eight samples of iron-oxide nanoparticles that were synthesized by the co-precipitation method. The obtained results from the two functions were compared. The correct value of (M_s) for each sample was determined according to the characteristic mark on the (M_s) and AAD curves versus the number of points. According to the results of this work, we suggest using both functions together to determine the saturation magnetization of magnetic nanoparticles in practical cases.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Characterization and Applications of Magnetic Nanoparticles · Magnetic Properties and Synthesis of Ferrites · Magnetic properties of thin films
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (32)
Show source-provided references
1. Reyes-Ortega F, Delgado ÁV, Iglesias GR (2021) Modulation of the magnetic hyperthermia response using different superparamagnetic iron oxide nanoparticle morphologies. Nanomaterials 11(3):62710.3390/nano11030627 ↗
2. Soleymani M, Velashjerdi M, Shaterabadi Z, Barati A (2020) One-pot preparation of hyaluronic acid-coated iron oxide nanoparticles for magnetic hyperthermia therapy and targeting cd44-overexpressing cancer cells. Carbohydrate polymers 237:11613010.1016/j.carbpol.2020.116130 ↗
3. Asgari M, Soleymani M, Miri T, Barati A (2021) Design of thermosensitive polymer-coated magnetic mesoporous silica nanocomposites with a core-shell-shell structure as a magnetic/temperature dual-responsive drug delivery vehicle. Polymers for Advanced Technologies 32(10):4101–410910.1002/pat.5417 ↗
4. Oltolina F, Peigneux A, Colangelo D, Clemente N, D’Urso A, Valente G, Iglesias GR, Jiménez-Lopez C, Prat M (2020) Biomimetic magnetite nanoparticles as targeted drug nanocarriers and mediators of hyperthermia in an experimental cancer model. Cancers 12(9):256410.3390/cancers12092564 ↗
5. Choi J, Gani AW, Bechstein DJ, Lee J-R, Utz PJ, Wang SX (2016) Portable, one-step, and rapid gmr biosensor platform with smartphone interface. Biosensors and Bioelectronics 85:1–710.1016/j.bios.2016.04.046 ↗
6. Sun X, Lei C, Guo L, Zhou Y (2016) Separable detecting of escherichia coli o157h: H7 by a giant magneto-resistance-based bio-sensing system. Sensors and Actuators B: Chemical 234:485–49210.1016/j.snb.2016.04.183 ↗
7. Arabi H, ASNAASHARI EH (2014) Applying a suitable route for preparation fe3o4 nanoparticles by ammonia and investigation of their physical and different magnetic properties
8. Eivari HA, Rahdar A (2013) Some properties of iron oxide nanoparticles synthesized in different conditions. World Appl. Program 3(2):52–55
9. Shaterabadi Z, Nabiyouni G, Goya GF, Soleymani M (2022) The effect of the magnetically dead layer on the magnetization and the magnetic anisotropy of the dextran-coated magnetite anoparticles. Applied Physics A 128(8):1–1010.1007/s00339-022-05675-x ↗
10. Kolhatkar AG, Jamison AC, Litvinov D, Willson RC, Lee TR (2013) Tuning the magnetic properties of nanoparticles. International journal of molecular sciences 14(8):15977–1600910.3390/ijms140815977 ↗
11. Jang J-t, Nah H, Lee J-H, Moon SH, Kim MG, Cheon J (2009) Critical enhancements of mri contrast and hyperthermic effects by dopantcontrolled magnetic nanoparticles. Angewandte Chemie International Edition 48(7):1234–123810.1002/anie.200805149 ↗
12. Hadadian Y, Masoomi H, Dinari A, Ryu C, Hwang S, Kim S, Cho Bk, Lee JY, Yoon J (2022) From low to high saturation magnetization in magnetite nanoparticles: The crucial role of the molar ratios between the chemicals. ACS omega10.1021/acsomega.2c01136 ↗
13. Unni M, Uhl AM, Savliwala S, Savitzky BH, Dhavalikar R, Garraud N, Arnold DP, Kourkoutis LF, Andrew JS, Rinaldi C (2017) Thermal decomposition synthesis of iron oxide nanoparticles with diminished magnetic dead layer by controlled addition of oxygen. ACS nano 11(2):2284–230310.1021/acsnano.7b00609 ↗
14. Eivari H, Rahdar A, Arabi H (2012) Preparation of superparamagnetic iron oxide nanoparticles and investigation their magnetic properties. Int. J. Sci. Eng. Investig 1(3):70–72
15. Karaagac O, Yildiz BB, Köçkar H (2019) The influence of synthesis parameters on one-step synthesized superparamagnetic cobalt ferrite nanoparticles with high saturation magnetization. Journal of Magnetism and Magnetic Materials 473:262–26710.1016/j.jmmm.2018.10.063 ↗
16. Amirabadizadeh A, Salighe Z, Sarhaddi R, Lotfollahi Z (2017) Synthesis of ferrofluids based on cobalt ferrite nanoparticles: Influence of reaction time on structural, morphological and magnetic properties. Journal of Magnetism and Magnetic Materials 434:78–8510.1016/j.jmmm.2017.03.023 ↗
17. Jin Z-Q, Tang W, Zhang J-R, Qin H-X, Du Y-W (1998) Effective magnetic anisotropy of nanocrystalline nd-fe-ti-n hard magnetic alloys. The European Physical Journal B-Condensed Matter and Complex Systems 3(1):41–4410.1007/s100510050282 ↗
18. Corrêa BS, Costa MS, Cabrera-Pasca GA, Sena C, Holanda Pinto RH, Silva APS, Carvalho Junior RN, Ishida L, Ramon JG, Freitas RS et al (2020) High-saturation magnetization in small nanoparticles of fe3o4 coated with natural oils. Journal of Nanoparticle Research 22(3):1–1510.1007/s11051-020-4761-5 ↗
19. Safronov A, Beketov I, Komogortsev S, Kurlyandskaya G, Medvedev A, Leiman D, Larrañaga A, Bhagat S, (2013) Spherical magnetic nanoparticles fabricated by laser target evaporation. AIP Advances 3(5):05213510.1063/1.4808368 ↗
20. Cullity BD, Graham CD (2011) Introduction to Magnetic Materials. John Wiley & Sons
21. Miyazaki T, Jin H (2012) The Physics of Ferromagnetism vol. 158. Springer10.1007/978-3-642-25583-0 ↗
22. Köferstein R, Walther T, Hesse D, Ebbinghaus SG (2014) Crystallitegrowth, phase transition, magnetic properties, and sintering behaviour of nano-cufe2o4 powders prepared by a ombustion-like process. Journal of Solid State Chemistry 213:57–6410.1016/j.jssc.2014.02.010 ↗
23. Ryapolov PA, Postnikov EB (2021) Mittag-leffler function as an approximant to the concentrated ferrofluid’s magnetization curve. Fractal and Fractional 5(4):14710.3390/fractalfract5040147 ↗
24. Bender P, Balceris C, Ludwig F, Posth O, Bogart LK, Szczerba W, Castro A, Nilsson L, Costo R, Gavilán H et al (2017) Distribution functions of magnetic nanoparticles determined by a numerical inversion method. New Journal of Physics 19(7):07301210.1088/1367-2630/aa73b4 ↗
25. Bradbury A, Menear K, O’Grady K, Chantrell R (1984) Magnetic size determination for interacting fine particle systems. IEEE Transactions on Magnetics 20(5):1846–184810.1109/TMAG.1984.1063338 ↗
26. Eivari HA, Arabi H (2013) Preparation iron oxide nanoparticles by coprecipitation method and envestigation the effect of concentraion ratio of reactant on physical and magnetic properties of nanoparticles. Iranian Journal of Ceramic Science and Engineering 2(1)
27. Mohammad-Beigi H, Yaghmaei S, Roostaazad R, Bardania H, Arpanaei A (2011) Effect of ph, citrate treatment and silane-coupling agent concentration on the magnetic, structural and surface properties of functionalized silica-coated iron oxide nanocomposite particles. Physica E: Low-dimensional Systems and Nanostructures 44(3):618–62710.1016/j.physe.2011.10.015 ↗
28. Ramadan W, Kareem M, Hannoyer B, Saha S (2011) Effect of ph on the structural and magnetic properties of magnetite nanoparticles synthesised by co-precipitation. In: Advanced Materials Research, vol. 324, pp. 129–132. Trans Tech Publ10.4028/www.scientific.net/AMR.324.129 ↗
29. Arabi H, Asnaashari Eivari H (2014) Applying a suitable route for preparation fe3o4 nanoparticles by ammonia and investigation of their physical and different magnetic properties. International Journal of Nano Dimension 5(Issue 3): 297–303. https://doi.org/10.7508/ijnd.2014.03.01310.7508/ijnd.2014.03.013 ↗
30. Kale A, Gubbala S, Misra R (2004) Magnetic behavior of nanocrystalline nickel ferrite synthesized by the reverse micelle technique. Journal of Magnetism and Magnetic Materials 277(3):350–35810.1016/j.jmmm.2003.11.015 ↗
31. López-López M, Durán J, Delgado A, González-Caballero F (2005) Stability and magnetic characterization of oleate-covered magnetite ferrofluids in different nonpolar carriers. Journal of Colloid and Interface Science 291(1):144–15110.1016/j.jcis.2005.04.099 ↗
32. Karaagac O, Kockar H (2016) A simple way to obtain high saturation magnetization for superparamagnetic iron oxide nanoparticles synthesized in air atmosphere: Optimization by experimental design. Journal of Magnetism and Magnetic Materials 409:116–12310.1016/j.jmmm.2016.02.076 ↗