journal article·2020-05

Electropolishing and anodization of titanium in water/ethylene glycol baths for the production of TiO2 nanotubes

Oliver Rodríguez-Martínez, Luz María Martínez, Marcelo Videa

Journal of Nanoparticle Research· Volume 22· Issue 5
Publisher page

Abstract

A greener methodology to grow TiO2 nanotubes in a non-corrosive, low-hazard, fluoride-free ethylene glycol/water electrolytic bath is presented. Results demonstrate that the formation of nanostructures by anodization of Ti foils in NaCl solutions requires glycol/water solutions with water contents (> 50%) and moderate voltages (< 30 V). Nanotube growth was dependent on the surface characteristics; anodization performed on mechanically polished surfaces showed that randomly oriented nanotubes grow on pits while vertically oriented TiO2 nanotubes were obtained on electropolished surfaces. An electropolishing methodology was developed to obtain surfaces with submicrometer roughness that favours the growth control of vertically oriented TiO2 nanotubes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Anodic Oxide Films and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Aguirre OR, Félix Echeverría E (2018a) Effects of fluoride source on the characteristics of titanium dioxide nanotubes, vol 445. ISSN 0169-433210.1016/j.apsusc.2018.03.139 ↗
2. Aguirre R, Echeverry-Rendón M, Quintero D, Juan G, Castano MC, Harmsen SR, Fédix Echeverría E (2018b) Formation of nanotubular TiO2 structures with varied surface characteristics for biomaterial applications. J Biomed Mater Res Part A 106(5):1341–135410.1002/jbm.a.36331 ↗
3. Allam NK, Grimes CA (2007) Formation of vertically oriented TiO2 nanotube arrays using a fluoride free HCl aqueous electrolyte. J Phys Chem C 111(35):13028–1303210.1021/jp073924i ↗
4. Asgari V, Noormohammadi M, Ramazani A, Kashi MA (2018) A new approach to electropolishing of pure Ti foil in acidic solution at room temperature for the formation of ordered and long TiO2nanotube arrays. Corros Sci 136:38–46. ISSN 0010-938X10.1016/j.corsci.2018.02.040 ↗
5. Bavykin DV, Parmon VN, Lapkin AA, Walsh FC (2004) The effect of hydrothermal conditions on the mesoporous structure of TiO2 nanotubes. J Mater Chem 14(22):3370–810.1039/b406378c ↗
6. Cai Q, Paulose M, Varghese OK, Grimes CA (2005) The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation. J Mater Res 20 (01):230–23610.1557/JMR.2005.0020 ↗
7. Chen J-Z, Ko W-Y, Yen Y-C, Chen P-H, Lin K-J (2012) Hydrothermally processed TiO2 nanowire electrodes with antireflective and electrochromic properties. ACS Nano 6(8):6633–663910.1021/nn300787r ↗
8. Fushimi K, Hiroki H (2008) Anodic dissolution of titanium in NaCl-containing ethylene glycol. Electrochim Acta 53(8):3371–337610.1016/j.electacta.2007.11.074 ↗
9. Ge M, Cao C, Huang J, Li S, Chen Z, Zhang K-Q, Al-Deyab SS, Lai Y (2016) A review of one-dimensional TiO2 nanostructured materials for environmental and energy applications. J Mater Chem A 4:6772–680110.1039/C5TA09323F ↗
10. Gressel-Michel E, Chaumont D, Stuerga D (2005) From a microwave flash-synthesized TiO2 colloidal suspension to TiO2 thin films. J Colloid Interface Sci 285(2):674–67910.1016/j.jcis.2004.12.055 ↗
11. Grimes CA, Mor GK (2009) TiO2 nanotube arrays. Synthesis, Properties, and Applications. Springer10.1007/978-1-4419-0068-5 ↗
12. Hashimoto K, Hiroshi I, Akira F (2005) Tio2 photocatalysis: a historical overview and future prospects. Jpn J Appl Phys 44(12):8269–828510.1143/JJAP.44.8269 ↗
13. Hoffmann MR, Martin ST, Choi W (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95(1):69–9610.1021/cr00033a004 ↗
14. Khataee AR, Ali Mansoori G (2012) Nanostructured titanium dioxide materials: properties, preparation and applications. World Scientific Publishing Company Incorporated10.1142/8325 ↗
15. Legrand-Buscema C, Malibert C, Bach S (2002) Elaboration and characterization of thin films of TiO2 prepared by sol–gel process. Thin Solid Films 418(2):79–8410.1016/S0040-6090(02)00714-9 ↗
16. Lou Y, Chen J (2014) Recent developments in one dimensional (1D) nanostructured TiO2 for photoelectrochemical water splitting. Nanosci Nanotechnol Lett 6(5):361–371. ISSN 1941-490010.1166/nnl.2014.1781 ↗
17. Nasr M, Eid C, Habchi R, Miele P, Bechelany M (2018) Recent progress on titanium dioxide nanomaterials for photocatalytic applications. ChemSusChem 11(18):3023– 304710.1002/cssc.201800874 ↗
18. Nguyen QA, Bhargava YV, Devine TM (2008) Titania nanotube formation in chloride and bromide containing electrolytes. Electrochem Commun 10(3):471–475. ISSN 1388-248110.1016/j.elecom.2008.01.010 ↗
19. Nguyen QAS, Bhargava YV, Devine TM (2009) Initiation of organized nanopore/nanotube arrays in anodized titanium oxide. J Electrochem Soc 156(3):E55–E6110.1149/1.3049341 ↗
20. Pang YL, Lim S, Ong HC, Chong WT (2014) A critical review on the recent progress of synthesizing techniques and fabrication of TiO2-based nanotubes photocatalysts. Appl Catal A Gen 481:127–14210.1016/j.apcata.2014.05.007 ↗
21. Paulose M, Shankar K, Yoriya S (2006) Anodic growth of highly ordered TiO2 nanotube arrays to 134 μ m in length. J Phys Chem B 110(33):16179–1618410.1021/jp064020k ↗
22. Raja KS, Gandhi T, Misra M (2007) Effect of water content of ethylene glycol as electrolyte for synthesis of ordered titania nanotubes. Electrochem Commun 9(5):1069–1076. ISSN 1388-248110.1016/j.elecom.2006.12.024 ↗
23. Regonini D, Jaroenworaluck A, Stevens R, Bowen CR (2010) Effect of heat treatment on the properties and structure of TiO2 nanotubes: phase composition and chemical composition. Surf Interface Anal 42(3):139–14410.1002/sia.3183 ↗
24. Shah UH, Deen KM, Asgar H, Rahman Z, Haider W (2017) Understanding the mechanism of TiO2 nanotubes formation at low potentials (le8 v) through electrochemical methods. J Electroanal Chem 807:228–234. ISSN 1572-665710.1016/j.jelechem.2017.11.014 ↗
25. Skowronski L, Wachowiak AA, Grabowski A (2016) Characterization of optical and microstructural properties of semitransparent TiO2/ti/glass interference decorative coatings. Appl Surf Sci 388:731–740. ISSN 0169-433210.1016/j.apsusc.2016.05.159 ↗
26. Taguchi Y, Tsuji E, Aoki Y, Hiroki H (2012) Photo-induced properties of non-annealed anatase TiO2 mesoporous film prepared by anodizing in the hot phosphate/glycerol electrolyte. Appl Surf Sci 258(24):9810–981510.1016/j.apsusc.2012.06.035 ↗
27. Taveira LV, Macak JM, Sirotna K, Dick LFP, Schmuki P (2006) Voltage oscillations and morphology during the galvanostatic formation of self-organized TiO2 nanotubes. J Electrochem Soc 153(4):B137–B143. ISSN 0013-465110.1149/1.2172566 ↗
28. Wang X, Zhao Y, Mølhave K, Sun H (2017) Engineering the surface/interface structures of titanium dioxide micro and nano architectures towards environmental and electrochemical applications. Nanomaterials 7(11):382. ISSN 2079-499110.3390/nano7110382 ↗
29. Zhang WF, He YL, Zhang MS, Yin Z, Chen Q (2000) Raman scattering study on anatase TiO2 nanocrystals. J Phys D Appl Phys 33(8):91210.1088/0022-3727/33/8/305 ↗