Cavitating inside spherical boron nitride nanoparticles dependent on controllably follow-up treated atmospheres
Source abstract
Abstract
A novel two-step method is developed for the facile preparation of hollow nano-spherical boron nitride (BN). BN nanospheres prepared by the traditional chemical vapor deposition reaction of ammonia and trimethyl borate were hollowed out. The average size of solid BN nanospheres precursor was ~ 130 nm. Boron nitride phase, morphology, and surface functionalization characterization along with the measurement of O content, and surface functionality were used to illustrate the final differences among various cavitating BN nanospheres treated with different gas flows at a higher temperature. Several possible formation mechanisms for the BN cavitating structures were proposed. This work provides direction for the controllable preparation of hollow-type BN particles.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Boron and Carbon Nanomaterials Research · Graphene research and applications · Diamond and Carbon-based Materials Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. Baraton MI, Boulanger L, Cauchetier M, Lorenzelli V, Luce M, Merle T, Quintard P, Zhou YH (1994) Nanometric boron nitride powders: laser synthesis, characterization and FT-IR surface study. J Eur Ceram Soc 13:371–378. https://doi.org/10.1016/0955-2219(94)90013-210.1016/0955-2219(94)90013-2 ↗
2. Chen L, Gu Y, Shi L, Yang Z, Ma J, Qian Y (2004) A room-temperature approach to boron nitride hollow spheres. Solid State Commun 130:537–540. https://doi.org/10.1016/j.ssc.2004.03.00910.1016/j.ssc.2004.03.009 ↗
3. Chen Z-G, Zou J, Liu G, Li F, Chen H-M, Sekiguchi T, Gu M, Yao X-D, Wang L-Z, Lu G (2009) Long wavelength emissions of periodic yard-glass shaped boron nitride nanotubes. Appl Phys Lett 94:023105. https://doi.org/10.1063/1.306927810.1063/1.3069278 ↗
4. Feng S, Zhang H, Xu S, Zhi C, Nakanishi H, Gao X-D (2019) Folate-conjugated, mesoporous silica functionalized boron nitride nanospheres for targeted delivery of doxorubicin. Mater Sci Eng C 96:552–560. https://doi.org/10.1016/j.msec.2018.11.06310.1016/j.msec.2018.11.063 ↗
5. Firestein KL, Kvashnin DG, Kovalskii AM, Popov ZI, Sorokin PB, Golberg DV, Shtansky DV (2018) Compressive properties of hollow BN nanoparticles: theoretical modeling and testing in a high-resolution transmission electron microscope. Nanoscale 10:8099–8105. https://doi.org/10.1039/C8NR00857D10.1039/C8NR00857D ↗
6. Geick R, Perry CH, Rupprecht G (1966) Normal modes in hexagonal boron nitride. Phys Rev 146:543–547. https://doi.org/10.1103/PhysRev.146.54310.1103/PhysRev.146.543 ↗
7. Golberg D, Bando Y, Huang Y, Terao T, Mitome M, Tang C, Zhi C (2010) Boron nitride nanotubes and nanosheets. ACS Nano 4:2979–2993. https://doi.org/10.1021/nn100649510.1021/nn1006495 ↗
8. Huang MT, Ishida H (2005) Surface study of hexagonal boron nitride powder by diffuse reflectance Fourier transform infrared spectroscopy. Surf Interface Anal 37:621–627. https://doi.org/10.1002/sia.205510.1002/sia.2055 ↗
9. Huang W, Lai W, Xie D (2008) First-principles study of decomposition of NH3 on Ir(100). Surf Sci 602:1288–1294. https://doi.org/10.1016/j.susc.2008.01.02910.1016/j.susc.2008.01.029 ↗
10. Li M, Xu L, Yang L, Bai Z, Qian Y (2009) Growth of cubic and hexagonal BN particles by using BBr3, NH4Br and metallic Na as reactants. Diam Relat Mater 18:1421–1425. https://doi.org/10.1016/j.diamond.2009.08.01110.1016/j.diamond.2009.08.011 ↗
11. Li X, Wang X, Zhang J, Hanagata N, Wang X, Weng Q, Ito A, Bando Y, Golberg D (2017) Hollow boron nitride nanospheres as boron reservoir for prostate cancer treatment. Nat Commun 8:13936. https://doi.org/10.1038/ncomms1393610.1038/ncomms13936 ↗
12. Lian G, Zhang X, Zhang S, Liu D, Cui D, Wang Q (2012) Controlled fabrication of ultrathin-shell BN hollow spheres with excellent performance in hydrogen storage and wastewater treatment. Energy Environ Sci 5:7072–7080. https://doi.org/10.1039/c2ee03240f10.1039/c2ee03240f ↗
13. Lindquist DA, Kodas TT, Smith DM, Xiu X, Hietala SL, Paine RT (1991) Boron nitride powders formed by aerosol decomposition of poly(borazinylamine) solutions. J Am Ceram Soc 74:3126–3128. https://doi.org/10.1111/j.1151-2916.1991.tb04310.x10.1111/j.1151-2916.1991.tb04310.x ↗
14. Liu Z, Fang Y, Jia H, Wang C, Song Q, Li L, Lin J, Huang Y, Yu C, Tang C (2018) Novel multifunctional cheese-like 3D carbon-BN as a highly efficient adsorbent for water purification. Sci Rep 8:1104. https://doi.org/10.1038/s41598-018-19541-510.1038/s41598-018-19541-5 ↗
15. Panicker CY, Varghese HT, John A, Philip D, Nougueira HIS (2002) Vibrational spectra of melamine diborate, C3N6H62H3BO3. Spectrochim Acta A 58:1545–1551. https://doi.org/10.1016/s1386-1425(01)00608-410.1016/s1386-1425(01)00608-4 ↗
16. Pruss EA, Wood GL, Kroenke WJ, Paine RT (2000) Aerosol assisted vapor synthesis of spherical boron nitride powders. Chem Mater 12:19–21. https://doi.org/10.1021/cm990562l10.1021/cm990562l ↗
17. Reeves CJ, Menezes PL, Lovell MR, Jen T-C (2013) The size effect of boron nitride particles on the tribological performance of biolubricants for energy conservation and sustainability. Tribol Lett 51:437–452. https://doi.org/10.1007/s11249-013-0182-210.1007/s11249-013-0182-2 ↗
18. Salles V, Bernard S, Li J, Brioude A, Chehaidi S, Foucaud S, Miele P (2009) Design of highly dense boron nitride by the combination of spray-pyrolysis of borazine and additive-free sintering of derived ultrafine powders. Chem Mater 21:2920–2929. https://doi.org/10.1021/cm900641s10.1021/cm900641s ↗
19. Si H, Lian G, Wang J, Li L, Wang Q, Cui D, Wong C-P (2016) Synthesis of few-atomic-layer BN hollow nanospheres and their applications as nanocontainers and catalyst support materials. ACS Appl Mater Interfaces 8:1578–1582. https://doi.org/10.1021/acsami.5b1097810.1021/acsami.5b10978 ↗
20. Song Q, Fang Y, Liu Z, Li L, Wang Y, Liang J, Huang Y, Lin J, Hu L, Zhang J, Tang C (2017) The performance of porous hexagonal BN in high adsorption capacity towards antibiotics pollutants from aqueous solution. Chem Eng J 325:71–79. https://doi.org/10.1016/j.cej.2017.05.05710.1016/j.cej.2017.05.057 ↗
21. Späth F, Gebhardt J, Düll F, Bauer U, Bachmann P, Gleichweit C, Görling A, Steinrück H-P, Papp C (2017) Hydrogenation and hydrogen intercalation of hexagonal boron nitride on Ni (111): reactivity and electronic structure. 2D Mater 4:035026. https://doi.org/10.1088/2053-1583/aa7d6b10.1088/2053-1583/aa7d6b ↗
22. Sukhorukova IV, Zhinyak IY, Kovalskii AM, Matveev AT, Lebedev OI, Li X, Gloushankova NA, Golberg D, Shtansky DV (2015) Boron nitride nanoparticles with a petal-like surface as anticancer drug-delivery systems. ACS Appl Mater Interfaces 7:17217–17225. https://doi.org/10.1021/acsami.5b0410110.1021/acsami.5b04101 ↗
23. Tang C, Bando Y, Golberg D (2002) Large-scale synthesis and structure of boron nitride sub-micron spherical particle. Chem Commun 23:2826–2827. https://doi.org/10.1039/b208785e10.1039/b208785e ↗
24. Tang C, Bando Y, Liu C, Fan S, Zhang J, Ding X, Golberg D (2006a) Thermal conductivity of nanostructured boron nitride materials. J Phys Chem B 110:10354–10357. https://doi.org/10.1021/jp060701410.1021/jp0607014 ↗
25. Tang C, Bando Y, Shen G, Zhi C, Golberg D (2006b) Single-source precursor for chemical vapour deposition of collapsed boron nitride nanotubes. Nanotechnology 17:5882–5888. https://doi.org/10.1088/0957-4484/17/23/02810.1088/0957-4484/17/23/028 ↗
26. Tang C, Bando Y, Huang Y, Zhi C, Golberg D (2008) Synthetic routes and formation mechanisms of spherical boron nitride nanoparticle. Adv Funct Mater 18:3653–3661. https://doi.org/10.1002/adfm.20080049310.1002/adfm.200800493 ↗
27. Thangasamy P, Sathish M (2015) Supercritical fluids processing: a rapid, one-pot exfoliation for surfactant-free hexagonal boron nitride nanosheets. CrystEngComm 17:5895–5899. https://doi.org/10.1039/c5ce00926j10.1039/c5ce00926j ↗
28. Tian Y, Xu B, Yu D, Ma Y, Wang Y, Jiang Y, Hu W, Tang C, Gao Y, Luo K, Zhao Z, Wang L-M, Wen B, He J, Liu Z (2013) Ultrahard nanotwinned cubic boron nitride. Nature 493:385–388. https://doi.org/10.1038/nature1172810.1038/nature11728 ↗
29. Wang Y, Yamamoto Y, Kiyono H, Shimada S (2009) Effect of ambient gas and temperature on crystallization of boron nitride spheres prepared by vapor phase pyrolysis of ammonia borane. J Am Ceram Soc 92:787–792. https://doi.org/10.1111/j.1551-2916.2009.02941.x10.1111/j.1551-2916.2009.02941.x ↗
30. Wang W, Lin J, Xing C, Chai R, Abbas S, Song T, Tang C, Huang Y (2017a) Fe3O4 nanoparticle-coated boron nitride nanospheres: synthesis, magnetic property and biocompatibility study. Ceram Int 43:6371–6376. https://doi.org/10.1016/j.ceramint.2017.02.04710.1016/j.ceramint.2017.02.047 ↗
31. Wang N, Wang H, Tang C, Lei S, Shen W, Wang C, Wang G, Wang Z, Wang L (2017b) Toxicity evaluation of boron nitride nanospheres and water-soluble boron nitride in Caenorhabditis elegans. Int J Nanomedicine 12:5941–5957. https://doi.org/10.2147/IJN.S13096010.2147/IJN.S130960 ↗
32. Wei M, Fu Q, Wu H, Dong A, Bao X (2016) Hydrogen intercalation of graphene and boron nitride monolayers grown on Pt (111). Top Catal 59:543–549. https://doi.org/10.1007/s11244-015-0516-410.1007/s11244-015-0516-4 ↗
33. Wen G, Zhong B, Huang X, Yu H, Zhang X, Zhang T, Bai H (2010) Novel BN hollow microspheres with open mouths-facile synthesis, growth mechanism, resonant Raman scattering effect, and cathodoluminescence performance. Eur J Inorg Chem 35:5538–5544. https://doi.org/10.1002/ejic.20100070310.1002/ejic.201000703 ↗
34. Xiao F, Naficy S, Casillas G, Khan MH, Katkus T, Jiang L, Liu H, Li H, Huang Z (2015) Edge-hydroxylated boron nitride nanosheets as an effective additive to improve the thermal response of hydrogels. Adv Mater 27:7196–7203. https://doi.org/10.1002/adma.20150280310.1002/adma.201502803 ↗
35. Xue Y, Zhou X, Zhan T, Jiang B, Guo Q, Fu X, Shimamura K, Xu Y, Mori T, Dai P, Bando Y, Tang C, Golberd D (2018) Densely interconnected porous BN frameworks for multifunctional and isotropically thermoconductive polymer composites. Adv Funct Mater 28:1801205. https://doi.org/10.1002/adfm.20180120510.1002/adfm.201801205 ↗
36. Zhang H, Yamazaki T, Zhi C, Hanagata N (2012) Identification of a boron nitride nanosphere-binding peptide for the intracellular delivery of CpG oligodeoxynucleotides. Nanoscale 4:6343–6350. https://doi.org/10.1039/C2NR31189E10.1039/C2NR31189E ↗
37. Zhi C, Bando Y, Tang C, Golberg D, Xie R, Sekigushi T (2005) Phonon characteristics and cathodolumininescence of boron nitride nanotubes. Appl Phys Lett 86:213110. https://doi.org/10.1063/1.193800210.1063/1.1938002 ↗
38. Zhi C, Bando Y, Tang C, Honda S, Sato K, Kuwahara H, Golberg D (2006) Purification of boron nitride nanotubes through polymer wrapping. J Phys Chem B 110:1525–1528. https://doi.org/10.1021/jp054941f10.1021/jp054941f ↗
39. Zhi C, Xu Y, Bando Y, Golberg D (2011) Highly thermo-conductive fluid with boron nitride nanofillers. ACS Nano 5:6571–6577. https://doi.org/10.1021/nn201946x10.1021/nn201946x ↗
40. Zhong B, Tang X, Huang X, Xia L, Zhang X, Wang C, Wen G (2015) Boron nitride hollow nanospheres: synthesis, formation mechanism and dielectric property. Mater Res Bull 64:61–67. https://doi.org/10.1016/j.materresbull.2014.12.04810.1016/j.materresbull.2014.12.048 ↗
41. Zhong B, Zhang X, Xia L, Yu Y, Wen G (2017) Large-scale fabrication and utilization of novel hexagonal/turbostratic composite boron nitride nanosheets. Mater Des 120:266–272. https://doi.org/10.1016/j.matdes.2017.02.03510.1016/j.matdes.2017.02.035 ↗
42. Zhu Y-C, Bando Y, Yin L-W, Golberg D (2004) Hollow boron nitride (BN) nanocages and BN-nanocages-encapsulated nanocrystals. Chem Eur J 10:3667–3672. https://doi.org/10.1002/chem.20040000210.1002/chem.200400002 ↗