journal article·2016-12

Gas phase synthesis of core-shell Fe@FeO x magnetic nanoparticles into fluids

Sitki Aktas, Stuart C. Thornton, Chris Binns, Phil Denby

Journal of Nanoparticle Research· Volume 18· Issue 12
Publisher page

Abstract

Sorbitol, short chain molecules, have been used to stabilise of Fe@FeO x nanoparticles produced in the gas phase under the ultra-high vacuum (UHV) conditions. The sorbitol coated Fe@FeO x nanoparticles produced by our method have a narrow size distribution with a hydrodynamic diameter of 35 nm after NaOH is added to the solution. Magnetisation measurement shows that the magnetic nanoparticles are superparamagnetic at 100 K and demonstrate hysteresis at 5 K with an anisotropy constant of 5.31 × 104 J/m3 (similar to bulk iron). Also, it is shown that sorbitol is only suitable for stabilising the Fe@FeO x suspensions, and it does not prevent further oxidation of the metallic Fe core. According to MRI measurement, the nanoparticles have a high transverse relaxation rate of 425 mM−1 s−1.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Characterization and Applications of Magnetic Nanoparticles · Geomagnetism and Paleomagnetism Studies · Iron oxide chemistry and applications

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