journal article·2014-03

Novel one-dimensional polyaniline/Ni0.5Zn0.5Fe2O4 hybrid nanostructure: synthesis, magnetic, and electromagnetic wave absorption properties

Cui-Ping Wang, Chuan-Hao Li, Hong Bi, Ju-Chuan Li, Hui Zhang, An-Jian Xie, Yu-Hua Shen

Journal of Nanoparticle Research· Volume 16· Issue 3
Publisher page

Abstract

For the first time, the novel one-dimensional uniform polyaniline (PANI)/Ni0.5Zn0.5Fe2O4 (NZFO) hybrid nanorods were synthesized by an in situ polymerization approach with the assistance of ultrasound and magnetic field. Owing to the unique shape, structure, and chemical composition, the as-synthesized hybrid nanorods with different PANI/NZFO mass ratios possess adjustable magnetic properties, high-saturated magnetization, and coercivity. In addition, these hybrid nanorods present stronger reflection loss and a wider absorption band than pure NZFO. Especially, the hybrid nanorods containing 59 wt% NZFO exhibit excellent microwave absorption properties, with a maximum reflection loss (R L) of −27.5 dB observed at 6.2 GHz. And the widest absorption band (R L ≤ −10 dB) is 8.1 GHz, corresponding to a matching thin thickness of 2 mm. It is superior to the previously reported value of PANI/ferrite. Therefore, these PANI/NZFO hybrid nanorods may be candidates for lightweight, low-cost, broadband, and highly efficient microwave-absorbing materials.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electromagnetic wave absorption materials · Conducting polymers and applications · Advanced Antenna and Metasurface Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Cavaliere S, Salles V, Brioude A, Lalatonne Y, Motte L, Monod P, Cornu D, Miele P (2010) Elaboration and characterization of magnetic nanocomposite fibers by electrospinning. J Nanopart Res 12:2735–274010.1007/s11051-010-0053-9 ↗
2. Che RC, Peng LM, Duan XF, Chen Q, Liang XL (2004) Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Adv Mater 16:401–40510.1002/adma.200306460 ↗
3. Chen YJ, Gao P, Wang RX, Zhu CL, Cao MS, Jin HB (2009) Porous Fe3O4/SnO2 core/shell nanorods: synthesis and electromagnetic properties. J Phys Chem C 113:10061–1006410.1021/jp902296z ↗
4. Ding HJ, Long YZ, Shen JY, Wan MX (2010) Fe2(SO4)3 as a binary oxidant and dopant to thin polyaniline nanowires with high conductivity. J Phys Chem B 114:115–11910.1021/jp908847u ↗
5. Guo JL, Wang XL, Miao PL, Liao XP, Zhang WH, Shi B (2012) One-step seeding growth of controllable Ag@Ni core-shell nanoparticles on skin collagen fiber with introduction of plant tannin and their application in high-performance microwave absorption. J Mater Chem 22:11933–1194210.1039/c2jm30370a ↗
6. Hagen R, Lorrmann H, Möller KC, Mathur S (2012) Electrospun LiFe1−y Mny PO4/C nanofiber composites as self-supporting cathodes in Li-ion batteries. Adv Energy Mater 2:553–55910.1002/aenm.201100534 ↗
7. Han H, Sutherland AM, Yaghmaie F, Davis CE (2009) Development of a lead oxide photopatternable organic-inorganic film. Appl Phys Lett 94(14):114106–114108
8. He D, Zeng C, Xu C, Cheng NC, Li HG, Mu SC, Pan M (2011) Polyaniline-functionalized carbon nanotube supported platinum catalysts. Langmuir 27:5582–558810.1021/la2003589 ↗
9. Hwang Y (2006) Microwave absorbing properties of NiZn-ferrite synthesized from waste iron oxide catalyst. Mater Lett 60:3277–328010.1016/j.matlet.2006.03.010 ↗
10. Jiang J, Li LC, Xu F (2007) Polyaniline-LiNi ferrite core-shell composite: preparation, characterization and properties. Mater Sci Eng A 456:300–30410.1016/j.msea.2006.11.143 ↗
11. Korth BD, Keng P, Shim I, Bowles SE, Tang CB, Kowalewski T, Nebesny K, Pyun J (2006) Polymer-coated ferromagnetic colloids from well-defined macromolecular surfactants and assembly into nanoparticle chains. J Am Chem Soc 128:6562–656310.1021/ja0609147 ↗
12. Li GJ, Yan SF, Zhou EL, Chen YM (2006) Preparation of magnetic and conductive NiZn ferrite-polyaniline nanocomposites with core-shell structure. Colloid Surf a-Physicochem Eng Asp 276:40–4410.1016/j.colsurfa.2005.10.010 ↗
13. Li YX, Zhang HW, Liu YL, Wen QY, Li J (2008) Rod-shaped polyaniline-barium ferrite nanocomposite: preparation, characterization and properties. Nanotechnology 19:10560510.1088/0957-4484/19/10/105605 ↗
14. Lim TH, Oh KW, Kim SH (2012) Self-assembly supramolecules to enhance electrical conductivity of polyaniline for a flexible organic solar cells anode. Sol Energ Mat Sol C 101:232–24010.1016/j.solmat.2012.01.040 ↗
15. Liu JW, Che RC, Chen HJ, Zhang F, Xia F, Wu QS, Wang M (2012) Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe3O4 cores and anatase TiO2 shells. Small 8:1214–122110.1002/smll.201102245 ↗
16. Sarangi PP, Vadera SR, Patra MK, Ghosh NN (2010) Synthesis and characterization of pure single phase Ni–Zn ferrite nanopowders by oxalate based precursor method. Powder Technol 23:348–35310.1016/j.powtec.2010.05.027 ↗
17. Sun G, Dong B, Cao MH, Wei BQ, Hu CW (2011) Hierarchical dendrite-like magnetic materials of Fe3O4, γ-Fe2O3, and Fe with high performance of microwave absorption. Chem Mater 23:1587–159310.1021/cm103441u ↗
18. Tao YL, Shen YH, Yang LB, Han B, Huang FZ, Li SK, Chu ZW (2012) Hierarchical self-assembly of hexagonal single-crystal nanosheets into 3D layered superlattices with high conductivity. Nanoscale 4:3729–373310.1039/c2nr30743j ↗
19. Ting TH, Yu RP, Jau YN (2011) Synthesis and microwave absorption characteristics of polyaniline/NiZn ferrite composites in 2–40 GHz. Mater Chem Phys 126:364–36810.1016/j.matchemphys.2010.11.011 ↗
20. Wang XF, Shen YH, Xie AJ, Li SK, Cai Y, Wang Y, Shu HY (2011a) Assembly of dandelion-like Au/PANI nanocomposites and their application as SERS nanosensors. Biosens Bioelectron 26:3063–306710.1016/j.bios.2010.11.044 ↗
21. Wang XF, Shen YH, Xie AJ, Qiu LG, Li SK, Wang Y (2011b) Novel structure CuI/PANI nanocomposites with bifunctions: superhydrophobicity and photocatalytic activity. J Mater Chem 21:9641–964610.1039/c0jm04558f ↗
22. Wen FS, Zhang F et al (2011) Investigation on microwave absorption properties for multiwalled carbon nanotubes/Fe/Co/Ni nanopowders as lightweight absorbers. J Phys Chem C 115:14025–1403010.1021/jp202078p ↗
23. Wu KH, Shin YM, Yang CC, Wang GP, Horng DN (2006) Preparation and ferromagnetic properties of Ni0.5Zn0.5Fe2O4/polyaniline core–shell nanocomposites. J Polymer Sci Part A 44:2657–266410.1002/pola.21384 ↗
24. Yuan J, Gao H, Schacher F, Xu Y, Richter R, Tremel W (2009) Alignment of tellurium nanorods via a magnetization-alignment-demagnetization (MAD) process assisted by an external magnetic field. ACS Nano 3:1441–145010.1021/nn9002715 ↗
25. Yuan JY, Xu YY, Muller AHE (2011) One-dimensional magnetic inorganic-organic hybrid nanomaterials. Chem Soc Rev 40:640–65510.1039/c0cs00087f ↗
26. Yuan WZ, Yuan JY, Zhou LL, Wu SZ, Hong XY (2010) Fe3O4@poly(2-hydroxyethyl methacrylate)-graft-poly(epsilon-caprolactone) magnetic nanoparticles with branched brush polymeric shell. Polymer 51:2540–254710.1016/j.polymer.2010.04.016 ↗
27. Zhang C, Tjiu WW, Liu TX, Lui WY, Phang IY, Zhang WD (2011) Dramatically enhanced mechanical performance of nylon-6 magnetic composites with nanostructured hybrid one-dimensional carbon nanotube-two-dimensional clay nanoplatelet heterostructures. J Phys Chem B 115:3392–339910.1021/jp112284k ↗
28. Zhang XY, MacDiarmid AG, Manohar SK (2005) Chemical synthesis of PEDOT nanofibers. Chemcomm 14:5328–5330
29. Zhao MQ, Zhang Q, Huang JQ, Wei F (2012) Hierarchical nanocomposites derived from nanocarbons and layered double hydroxides properties, synthesis, and applications. Adv Funct Mater 22:675–69410.1002/adfm.201102222 ↗
30. Zhou JF, Meng LJ, Feng XL, Zhang XK, Lu QH (2010) One-pot synthesis of highly magnetically sensitive nanochains coated with a highly cross-linked and biocompatible polymer. Angew Chem 122:8654–865710.1002/ange.201003820 ↗
31. Zhu CL, Zhang ML, Qiao YJ, Xiao G, Zhang F, Chen YJ (2010) Fe3O4/TiO2 core/shell nanotubes: synthesis and magnetic and electromagnetic wave absorption characteristics. J Phys Chem C 114:16229–1623510.1021/jp104445m ↗
32. Zhu HL, Bai YJ, Liu R, Lun N, Qi YX, Han FD, Bi JQ (2011) In situ synthesis of one-dimensional MWCNT/SiC porous nanocomposites with excellent microwave absorption properties. J Mater Chem 21:13581–1358710.1039/c1jm11747e ↗