DataVXJournal of Nanoparticle ResearchPaper
journal article·2020-08

Selective uptake of Ag(I) from aqueous solutions using ionic liquid-modified iron oxide nanoparticles

Abiodun D. Aderibigbe, Richard A. Crane, Martin R. Lees, Andrew J. Clark

Journal of Nanoparticle Research· Volume 22· Issue 8
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Source abstract

Abstract

Surface functionalized magnetic nanoparticles represent a potentially highly valuable tool for the selective recovery of metals from the aqueous phase, due to their ability to be manipulated and then recovered using an externally applied magnetic field. Ionic liquids are ideal candidates for such surface functionalization for a range of reasons, including their enhanced selectivity, low water consumption and high chemical stability. Herein the removal of Ag + onto [MTESPIm] + [Cl] − on Fe 3 O 4 @SiO 2 _{} as a function of pH, exposure time, nanosorbent concentration and type of stripping agent has been investigated. Ag + removal was recorded to fit the Langmuir isotherm indicating monolayer formation, with a saturation capacity of 23.69 mg/g. Moreover, optimum conditions for the selective removal of Ag + in preference to Cu 2+ and Pb 2+ , were recorded at pH 3, exposure time ranging between 0-15 min and with the highest nanosorbent concentration tested (80 mg/10ml of adsorbate solution). In addition, the most efficient stripping agent for the sorbed Ag + was determined to be thiourea at 0.6 M. Overall the results indicate that [MTESPIm] + [Cl] − on Fe 3 O 4 @SiO 2 is a highly adaptable and efficient agent for the selective recovery of Ag from the aqueous phase.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

Nanomaterials

OpenAlex topics: Extraction and Separation Processes · Nanomaterials for catalytic reactions · Ionic liquids properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (52)

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