journal article·2013-11

A facile preparation of Pt–Ru nanoparticles supported on polyaniline modified fullerene [60] for methanol oxidation

Zhengyu Bai, Min Shi, Lu Niu, Zhichao Li, Libin Jiang, Lin Yang

Journal of Nanoparticle Research· Volume 15· Issue 11
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Abstract

The use of fullerene [60] (C60) as carbon support material for the dispersion of catalysts, which provides new ways to develop the advanced electrocatalyst materials for its distorted structure. In this article, polyaniline (PANI)-modified C60 (abbreviated as PANI-C60) is introduced, and the platinum–ruthenium alloy nanoparticles are successfully supported on PANI-C60. According to the transmission electron microscopy measurements, the average particle size of the as-prepared nanoparticles dispersed on PANI-C60 is 2.4 nm. Electrochemical studies reveal that the Pt-Ru/PANI-C60 nanocomposites show excellent electrocatalytic activity toward methanol oxidation, showing that the PANI-C60 may be a better potential candidate to be used as the supports of catalyst for electrochemical oxidation.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Conducting polymers and applications · Advanced battery technologies research

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References (20)

Show source-provided references
1. Antolini E, Gonzalez ER, Salgado JRC (2006) The methanol oxidation reaction on platinum alloys with the first row transition metals: The case of Pt–Co and –Ni alloy electrocatalysts for DMFCs: a short review. Appl Catal B 63:137–14910.1016/j.apcatb.2005.09.014 ↗
2. Bai ZY, Guo YM, Yang L, Li L, Lv J, Hu CG (2011a) Highly dispersed Pd nanoparticles supported on 1,10-phenanthroline-functionalized multi-walled carbon nanotubes for electrooxidation of formic acid. J Power Sources 196:6232–623710.1016/j.jpowsour.2011.03.020 ↗
3. Bai ZY, Yang L, Guo YM, Hu CG (2011b) High-efficiency palladium catalysts supported on ppy-modified C60 for formic acid oxidation. Chem Commun 47:1752–175410.1039/C0CC04781C ↗
4. Bashyam R, Zelenay P (2006) A class of non-precious metal composite catalysts for fuel cells. Nature 443:63–6610.1038/nature05118 ↗
5. Dihrab SS, Sopian K, Alghoul MA, Sulaiman MY (2009) Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells. Renew Sustain Energy Rev 13:1663–166810.1016/j.rser.2008.09.029 ↗
6. Geng DS, Hu YH, Li YL, Li RY, Sun XL (2012) One-pot solvothermal synthesis of doped graphene with the designed nitrogen type used as a Pt support for fuel cells. Electrochem Commun 22:65–6810.1016/j.elecom.2012.05.033 ↗
7. Han DM, Guo ZP, Zhao ZW, Zeng R, Meng YZ, Shu D, Liu HK (2008) Polyoxometallate-stabilized Pt–Ru catalysts on multiwalled carbon nanotubes: Influence of preparation conditions on the performance of direct methanol fuel cells. J Power Sources 184:361–36910.1016/j.jpowsour.2008.03.051 ↗
8. Huang T, Jiang R, Liu J, Zhuang J, Cai W, Yu A (2009) Synthesis of well-dispersed PtRuSnOx by ultrasonic-assisted chemical reduction and its property for methanol electrooxidation. Electrochem Acta 54:4436–444010.1016/j.electacta.2009.03.020 ↗
9. Kageyama S, Seino S, Nakagawa T, Nitani H, Ueno K, Daimon H, Yamamoto TA (2011) Formation of PtRu alloy nanoparticle catalyst by radiolytic process assisted by addition of dl-tartaric acid and its enhanced methanol oxidation activity. J Nanopart Res 13:5275–528710.1007/s11051-011-0513-x ↗
10. Kim M, Fang B, Chaudhari NK, Song M, Bae T, Yu J (2010) A highly efficient synthesis approach of supported Pt–Ru catalyst for direct methanol fuel cell. Electrochim Acta 55:4543–455010.1016/j.electacta.2010.03.007 ↗
11. Lee GH, Shim JH, Kang H, Nam KM, Song H, Park JT (2009) Monodisperse Pt and PtRu/C60 hybrid nanoparticles for fuel cell anode catalysts. Chem Commun 33:5036–5038
12. Liu FJ, Huang LM, Wen TC, Gopalan A (2007) Large-area network of polyaniline nanowires supported platinum nanocatalysts for methanol oxidation. Synth Met 157:651–65810.1016/j.synthmet.2007.07.001 ↗
13. Millána WM, Thompsona TT, Arriagab LG, Smita MA (2009) Characterization of composite materials of electroconductive polymer and cobalt as electrocatalysts for the oxygen reduction reaction. Int J Hydrogen Energy 34:694–70210.1016/j.ijhydene.2008.11.006 ↗
14. Ohkubo Y, Kageyama S, Seino S, Nakagawa T, Kugai J, Nitani H, Ueno K, Yamamoto TA (2013) Radiolytic synthesis of carbon-supported PtRu nanoparticles using high-energy electron beam: effect of pH control on the PtRu mixing state and the methanol oxidation activity. J Nanopart Res 15:1597–160810.1007/s11051-013-1597-2 ↗
15. Ohno TR, Chen Y, Harvey SE, Weaver JH, Haufler RE, Smalley RE (1991) C60 bonding and energy-level alignment on metal and semiconductor surfaces. Phys Rev B 44:13747–1375510.1103/PhysRevB.44.13747 ↗
16. Sevilla M, Lota G, Fuertes AB (2007) Saccharide-based graphitic carbon nanocoils as supports for PtRu nanoparticles for methanol electrooxidation. J Power Sources 171:546–55110.1016/j.jpowsour.2007.05.096 ↗
17. Wang ZB, Yin GP, Shi PF (2005) The influence of three groups of Pt–Ru/C catalyst’s precursors on its performance for direct methanol fuel cell. Acta Phys-Chim Sin 21:1156–116010.3866/PKU.WHXB20051019 ↗
18. Wang X, Tang YW, Gao Y, Lu TH (2008) Carbon-supported Pd–Ir catalyst as anodic catalyst in direct formic acid fuel cell. J Power Sources 175:784–78810.1016/j.jpowsour.2007.10.011 ↗
19. Wu BH, Hu D, Kuang J, Chen JH (2009) Functionalization of carbon nanotubes by an ionic-liquid polymer: dispersion of Pt and PtRu nanoparticles on carbon nanotubes and their electrocatalytic oxidation of methanol. Angew Chem Int Ed 48:4751–475410.1002/anie.200900899 ↗
20. Yang WQ, Yang SH, Guo JS, Sun GQ, Xin Q (2007) Comparison of CNF and XC-72 carbon supported palladium electrocatalysts for magnesium air fuel cell. Carbon 45:397–40110.1016/j.carbon.2006.09.003 ↗