Fabrication and characterization of Pd/Ag alloy hollow spheres by the solvothermal method
Source abstract
Abstract
Pd/Ag alloy hollow spheres have been synthesized in ethylene glycol solution by the solvothermal method and have been characterized extensively. TEM results have revealed the formation of Pd/Ag hollow spheres. Moreover, HRTEM results confirmed the formation of Pd/Ag alloy spheres, where the lattice fringe spacing is 0.229 nm corresponding to the (111) plane of Pd/Ag alloy. SEM, XRD and UV–vis results have further suggested the formation of alloy hollow spheres. The preliminary results showed the reaction time may be an importance factor influencing the formation of Pd/Ag alloy hollow spheres.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Polymer Surface Interaction Studies · Nanomaterials and Printing Technologies · Gold and Silver Nanoparticles Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Bamnolker H, Nitzan B, Gura S, Margel S (1997) New solid and hollow, magnetic and non-magnetic, organic–inorganic monodispersed hybrid microspheres: synthesis and characterization. J Mater Sci Lett 16:1412–141510.1023/A:1018565428355 ↗
2. Chen X, Fan R (2001) Low-temperature hydrothermal synthesis of transition metal dichalcogenides. Chem Mater 13:802–80510.1021/cm000517+ ↗
3. Chen MH, Gao L (2005) Synthesis and characterization of wurtzite ZnSe one-dimensional nanocrystals through molecular precursor decomposition by solvothermal method. Mater Chem Phys 91:437–44110.1016/j.matchemphys.2004.12.005 ↗
4. Chen JY, Wiley B, Mclellan J, Xiong YJ, Li ZY, Xia YN (2005) Optical properties of Pd–Ag and Pt–Ag nanoboxes synthesized via galvanic replacement reactions. Nano Lett 5:2058–206210.1021/nl051652u ↗
5. Doudna CM, Bertino MF, Tokuhiro AT (2002) Structural investigation of Ag–Pd clusters synthesized with the radiolysis method. Langmuir 18:2434–243510.1021/la0155404 ↗
6. Gautam UK, Ghosh M, Rajamathi M, Seshadri R (2002) Solvothermal routes to capped oxide and chalcogenide nanoparticles. Pure Appl Chem 74:1643–164910.1351/pac200274091643 ↗
7. Giersig M., LM Liz-Marzan, Ung T, DS Su, Mulvaney P, Bunsenges Ber (1997) Chemistry of nanosized silica-coated metal particles-EM study. Phys Chem 101:1617–1620
8. Hall SR, Davis SA, Mann S (2000) Condensation of organosilica hybrid shells on nanoparticle templates: a direct synthetic route to functionalized core-shell colloids. Langmuir 16:1454–145610.1021/la9909143 ↗
9. Huang CY, Chiang HJ, Huang JC, Sheen SR (1998) Synthesis of nanocrystalline Ag–Pd alloys by chemical reduction method. Nanostruct Mater 10:1393–140010.1016/S0965-9773(99)00018-5 ↗
10. Hu JS, Guo YG, Liang HP, Wan LJ, Bai CL, Wang YG (2004) Interface assembly synthesis of inorganic composite hollow spheres. J Phys Chem B 108:9734–973810.1021/jp038050o ↗
11. Huang H, Remsen EE, Kowalewski T, Wooley KL (1999) Nanocages derived from shell cross-linked micelle templates. J Am Chem Soc 121:3805–380610.1021/ja983610w ↗
12. Imhof A (2001) Preparation and characterization of titania-coated polystyrene spheres and hollow titania shells. Langmuir 17:3579–358510.1021/la001604j ↗
13. Lewis FA (1967) The palladium hydrogen system. Academic Press, London
14. Liu ZP, Yang Y, Liang JB, Hu ZK, Li S, Peng S, Qian YT (2003a) Synthesis of copper nanowires via a complex-surfactant-assisted hydrothermal reduction process. J Phys Chem B 107:12658–1266110.1021/jp036023s ↗
15. Liu ZP, Li S, Yang Y, Peng S, Hu ZK, Qian YT (2003b) Complex-surfactant-assisted hydrothermal route to ferromagnetic nickel nanobelts. Adv Mater 15:1946–194810.1002/adma.200305663 ↗
16. Løvvik OM, Olsen RA (2002) Density functional calculations on hydrogen in palladium–silver alloys. J Alloys Compd 330–332:332–33710.1016/S0925-8388(01)01491-8 ↗
17. Makarova OV, Ostafin AE, Miyoshi H, Norris JR, Meisel D (1999) Adsorption and encapsulation of fluorescent probes in nanoparticles. J phys Chem B 103:9080–908410.1021/jp9900786 ↗
18. Mandal TK, Fleming MS, Walt DR (2000) Production of hollow polymeric microspheres by surface-confined living radical polymerization on silica templates. Chem Mater 12:3481–348710.1021/cm000514x ↗
19. Mandal M, Kundu S, Ghosh SK, Pal T (2004) Micelle-mediated UV-photoactivation route for the evolution of Pdcore–Aushell and Pdcore–Agshell bimetallics from photogenerated Pd nanoparticles. J Photochem Photobio A: chemistry 167:17–2210.1016/j.jphotochem.2004.04.002 ↗
20. Michaelis M, Henglein A, Mulvancy P (1994) Composite Pd–Ag particles in aqueous solution. J Phys Chem 98:6212–621510.1021/j100075a025 ↗
21. Muthusamy E, Walsh D, Mann S (2002) Morphosynthesis of organoclay microspheres with sponge-like or hollow interiors. Adv Mater 14:969–97210.1002/1521-4095(20020704)14:13/14<969::AID-ADMA969>3.0.CO;2-4 ↗
22. Ostafin AE, Siegel M, Wang Q, Mizukami H (2003) Fluorescence of cascade blue inside nano-sized porous shells of silicate. Microporous Mesoporous Mater 57:47–5510.1016/S1387-1811(02)00502-4 ↗
23. Pastoriza-Santos I, Koktysh DS, Mamedov AA, Giersig M, Kotov NA, Liz-Marzan LM (2000) One-pot synthesis of Ag@TiO2 core-shell nanoparticles and their layer-by-layer assembly. Langmuir 16:2731–273510.1021/la991212g ↗
24. Peng YY, Meng ZY, Zhong C, Lu J, Yang ZP, Qian YT (2002) Tube- and ball-like amorphous MoS2 prepared by a solvothermal method. Mater Chem Phys 73:327–32910.1016/S0254-0584(01)00364-9 ↗
25. Powder Diffraction File Hanawalt Search Manual, Inorganic Phase, Sets, 1–42 (1992) International Centre for Diffraction Data. Pennsylvania
26. Qian YT (1999) Solvothermal synthesis of nanocrystalline III-V semiconductors. Adv Mater 11:1101–110210.1002/(SICI)1521-4095(199909)11:13<1101::AID-ADMA1101>3.0.CO;2-O ↗
27. Shiho H, Kawahashi N (2000) Iron compounds as coatings on polystyrene latex and as hollow spheres. J Colloid Interf Sci 226:91–9710.1006/jcis.2000.6789 ↗
28. Sun YG, Tao ZL, Chen J, Herricks T, Xia YN (2004) Ag nanowires coated with Ag/Pd alloy sheaths and their use as substrates for reversible absorption and desorption of hydrogen. J Am Chem Soc 126:5940–594110.1021/ja0495765 ↗
29. Thimmaiah S, Rajamathi M, Singh N, Bera P, Meldrum F, Chandrasekhar N, Seshadri R (2001) A solvothermal route to capped nanoparticles of γ-Fe2O3 and CoFe2O4. J Mater Chem 11:3215–322110.1039/b104070g ↗
30. Tissot I, Novat C, Lefebvre F, Bourgeat-Lami E (2001) Hybrid latex particles coated with silica. Macromolecules 34:5737–573910.1021/ma010278r ↗
31. Tissot I, Reymond JP, Lefebvre F, Bourgeat-Lami E (2002) Sioh-functionalized polystyrene latexes, a step toward the synthesis of hollow silica nanoparticles. Chem Mater 14:1325–133110.1021/cm0112441 ↗
32. Torigoe K, Esumi K (1993) Preparation of bimetallic silver–palladium colloids from silver(I) bis(oxalato)palladate(II). Langmuir 9:1664–166710.1021/la00031a011 ↗
33. Uemiya S, Matsuda T, Kikuchi E (1991) Hydrogen permeable palladium–silver alloy membrane supported on porous ceramics. J Membr Sci 56:315–32510.1016/S0376-7388(00)83041-0 ↗
34. Ung T, Liz-Marzan LM, Mulvaney P (1998) Controlled method for silica coating of silver colloids. Influence of coating on the rate of chemical reactions. Langmuir 14:3740–374810.1021/la980047m ↗
35. Wang WZ, Geng Y, Yan P, Liu FY, Xie Y, Qian YT (1999) Synthesis and characterization of MSe(M=Zn, Cd) nanorods by a new solvothermal method. Inorgan Chem Commun 2:83–8510.1016/S1387-7003(99)00015-5 ↗
36. Wang QQ, Zhao GL, Han GR (2005) Title synthesis of single crystalline CdS nanorods by a PVP-assisted solvothermal method source. Mater Lett 21:2625–2629
37. Weiss A, Ramaprabhu S, Rajalakshmi N (1997) The solubility and thermodynamics of hydrogen in Palladium substitutional solid solution alloys. Z Phys Chem 199:165–21210.1524/zpch.1997.199.Part_2.165 ↗
38. Xiong YJ, Wiley B, Chen JY, Li ZY, Yin YD, Xia YN (2005) Corrosion-based synthesis of single-crystal Pd nanoboxes and nanocages and their surface plasmon properties Angew. Chem Int Ed 44:7913–791710.1002/anie.200502722 ↗
39. Yang J, Cheng GH, Zeng JH, Yu SH, Liu XM, Qian YT (2001) Shape control and characterization of transition metal diselenides MSe2(M=Ni, Co, Fe) prepared by a solvothermal-reduction process. Chem Mater 13:848–85310.1021/cm0005945 ↗
40. Yang CC, Wan CC, Wang YY (2004) Synthesis of Ag/Pd nanoparticles via reactive micelles as templates and its application to electroless copper deposition. J Colloid Interf Sci 279:433–43910.1016/j.jcis.2004.06.098 ↗
41. Zhong ZY, Yin YD, Gates B, Xia YN (2000) Preparation of mesoscale hollow spheres of TiO2 and SnO2 by templating against crystalline arrays of polystyrene beads. Adv Mater 12:206–20910.1002/(SICI)1521-4095(200002)12:3<206::AID-ADMA206>3.0.CO;2-5 ↗