Surface oxygen vacancies induced peroxidase-like activity for W18O49 nanospheres and their application in degradation of methylene blue
Source abstract
Abstract
In this paper, the W18O49 nanospheres (W18O49 NSs) with diameter about 100 nm have been found to exhibit intrinsic peroxidase-like activity, which can catalytically oxidize 3,3′,5,5′-tetramethylbenzidine (TMB) by H2O2 to produce a color reaction. Different from the catalytic behavior of the Fe3O4 particles, the possible catalysis mechanism was notably dependent on the surface oxygen vacancies (SOVs) abundant in W18O49 NSs, which served as important catalytic sites. Moreover, due to the speciality with high surface area (136.13 m2 g−1) and negative potential (− 54.8 mV), the obtained W18O49 NSs could be used as efficient peroxidase mimetic to remove the dye pollutant methylene blue (MB) in the assistance of H2O2. And the degradation efficiency of MB could be achieved above 91% with 50 μg mL−1 W18O49 NSs.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Nanomaterials in Catalysis · Electrochemical sensors and biosensors · Nanocluster Synthesis and Applications
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