Construction of CoS2-N-C sheets anchored on 3D graphene network for lithium storage performances
Source abstract
Abstract
The construction of transition metal sulfides integrated into three-dimensional graphene network (3DGN) is a greatly attractive strategy for energy conversion and storage. Metal–organic framework (MOF) as template-derived CoS2 with N-doped carbon coating (CoS2-N-C) sheets (~ 510 nm) anchored on 3DGN (CoS2-N-C/3DGN) was designed and synthesized via a solution immersion reaction combined with a carbonization–sulfidation treatment. The formed ultra-small CoS2 nanoparticles are uniformly diffused and encapsulated in the N-rich carbon matrix, grown on 3DGN to obtain a self-supporting structure. The resulting CoS2-N-C/3DGN composites were evaluated as binder-free anode materials of lithium-ion batteries, delivering a high reversible gravimetric capacity of 409.5 mA h g−1 after 100 cycles as well as great rate capability of 124 mA h g−1 at 1600 mA g−1. The enhanced electrochemical behaviors should be attributed to the synergistic interaction between CoS2-N-C with high electrochemical activities and 3DGN with high conductivity and macroscopically porous structure. This work provides new ideas to rational design of other metal sulfides applied on 3DGN for high-performance energy storage devices.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (53)
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