journal article·2013-01Open access

Strong quantum confinement effects in SnS nanocrystals produced by ultrasound-assisted method

Yashar Azizian-Kalandaragh, Ali Khodayari, Zaiping Zeng, Christos S. Garoufalis, Sotirios Baskoutas, Lionel Cervera Gontard

Journal of Nanoparticle Research· Volume 15· Issue 1

Abstract

Nanocrystalline SnS powder has been prepared using tin chloride (SnCl2) as a tin ion source and sodium sulfide (Na2S) as a sulfur ion source with the help of ultrasound irradiation at room temperature. The as-synthesized SnS nanoparticles were quantitatively analyzed and characterized in terms of their morphological, structural and optical properties. The detailed structural and optical properties confirmed the orthorhombic SnS structure and a strongly blue shifted direct band gap (1.74 eV), for synthesized nanoparticles. The measured band gap energy of SnS nanoparticles is in a fairly good agreement with the results of theoretical calculations of exciton energy based on the potential morphing method (PMM) in the Hartree Fock approximation
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (63)

Show source-provided references
1. Alivisatos AP (1996) Perspectives on the physical chemistry of semiconductor nanocrystals. J Phys Chem 100:13226–1323910.1021/jp9535506 ↗
2. Azizian-Kalandaragh Y, Khodayari A (2010a) Ultrasound-assisted preparation of CdSe nanocrystals in the presence of Polyvinyl alcohol as a capping agent. Mater Sci Semicond Process 13:225–23010.1016/j.mssp.2010.10.018 ↗
3. Azizian-Kalandaragh Y, Khodayari A (2010b) Aqueous synthesis and characterization of nearly monodispersed ZnS nanocrystals. Phys Status Solidi A 207(9):2144–214810.1002/pssa.200925484 ↗
4. Azizian-Kalandaragh Y, Khodayari A, Behboudnia M (2009) Ultrasound-assisted synthesis of ZnO semiconductor nanostructures. Mater Sci Semicond Process 12:142–14510.1016/j.mssp.2009.09.006 ↗
5. Bashkirov SA, Gremenok VF, Ivanov VA (2011) Physical properties of SnS thin films fabricated by hot wall deposition. Fizika i Tekhnika Poluprovodnikov 45:765–769
6. Baskoutas S (2005a) Excitons and charged excitons in InAs nanorods. Chem Phys Lett 404:107–11110.1016/j.cplett.2005.01.075 ↗
7. Baskoutas S (2005b) Novel formulation of the Hartree–Fock approximation: effective band gap calculation of InAs nanorods. Phys Lett A 341:303–30710.1016/j.physleta.2005.04.088 ↗
8. Baskoutas S, Terzis AF (2006) Size-dependent band gap of colloidal quantum dots. J Appl Phys 99:01370810.1063/1.2158502 ↗
9. Baskoutas S, Poulopoulos P, Karoutsos V, Angelakeris M, Flevaris NK (2006a) Strong quantum confinement effects in thin zinc selenide films. Chem Phys Lett 417:461–46410.1016/j.cplett.2005.10.068 ↗
10. Baskoutas S, Terzis AF, Schommers W (2006b) Size-Dependent exciton energy of narrow band gap colloidal quantum dots in the finite depth square-well effective mass approximation. J Comp Theor Nanosci 3:269–27110.1166/jctn.2006.01010.1166/jctn.2006.3008 ↗
11. Bhattacharyya S, Gedanken A (2008) A template-free, sonochemical route to porous ZnO nano-disks. Microporous Mesoporous Mater 110:553–55910.1016/j.micromeso.2007.06.053 ↗
12. Biswas S, Kar S, Chaudhuri S (2007) Thioglycolic acid (TGA) assisted hydrothermal synthesis of SnS nanorods and nanosheets. Appl Surf Sci 253:9259–926610.1016/j.apsusc.2007.05.053 ↗
13. Chandrasekhar HR, Humphreys RG, Zwick U, Cardona M (1977) Infrared and Raman spectra of the IV-VI compounds SnS and SnSe. Phys Rev B 15:2177–218310.1103/PhysRevB.15.2177 ↗
14. Chazali A, Zainal Z, Hussein MZ, Kassim A (1998) Cathodic electrodeposition of SnS in the presence of EDTA in aqueous media. Sol Energy Mater Sol Cells 55:237–24910.1016/S0927-0248(98)00106-8 ↗
15. Chen D, Shen G, Tang K, Lei S, Zheng H, Qian Y (2004) Microwave-assisted polyol synthesis of nanoscale SnSx (x = 1, 2) flakes. J Cryst Growth 260:469–47410.1016/j.jcrysgro.2003.09.009 ↗
16. El-Nahass MM, Zeyada HM, Aziz MS, El-Ghamaz NA (2002) Optical properties of thermally evaporated SnS thin films. Opt Mater 20:159–17010.1016/S0925-3467(02)00030-7 ↗
17. Engelken RD, McCloud HE, Lee C, Slayton M, Ghoreishi H (1987) Low temperature chemical precipitation and vapor deposition of Snx S thin films. J Electrochem Soc 134:2696–270710.1149/1.2100274 ↗
18. Ghosh B, Das M, Banerjee P, Das S (2008) Fabrication and optical properties of SnS thin films by SILAR method. Appl Surf Sci 254:6436–644010.1016/j.apsusc.2008.04.008 ↗
19. Goharshadi EK, Ding Y, Jorabchi MN, Nancarrow P (2009) Ultrasound-assisted green synthesis of nanocrystalline ZnO in the ionic liquid [hmim][NTf2]. Ultraso Sonochem 16:120–12310.1016/j.ultsonch.2008.05.017 ↗
20. Gontard LC, Ozkaya D, Dunin-Borkowski R (2011) A simple algorithm for measuring particle size distributions on an uneven background from TEM images. Ultramicroscopy 111:101–10610.1016/j.ultramic.2010.10.011 ↗
21. Gou XL, Chen J, Shen PW (2005) Synthesis, characterization and application of SnSx (x = 1, 2) nanoparticles. Mater Chem Phys 93:557–56610.1016/j.matchemphys.2005.04.008 ↗
22. Greiner W (1989) Quantum mechanics: an introduction. Springer, Berlin
23. Guinier A (1963) X-Ray diffraction. In: Crystals, imperfect crystals, and amorphous bodies, Freeman, Sanfrancisco10.1063/1.3051547 ↗
24. Hanken H (1956) Nuovo Cim 3:123010.1007/BF02785005 ↗
25. Henglein A (1989) Small-particle research: physicochemical properties of extremely small colloidal metal and semiconductor particles. Chem Rev 89:1861–187310.1021/cr00098a010 ↗
26. Johson JB, Jones H, Latham BS, Parker JD, Engelken RD, Barber C (1999) Optimization of photoconductivity in vacuum-evaporated tin sulfide thin films. Semicond Sci Technol 14:501–50710.1088/0268-1242/14/6/303 ↗
27. Li Q, Ding Y, Wu H, Liu X, Qian Y (2002) Fabrication of layered nanocrystallites SnS and β-SnS2 via a mild solution route. Mater Res Bull 37:925–93210.1016/S0025-5408(02)00705-5 ↗
28. Liu Y, Xu Y, Li JP, Zhang B, Wu D, Sun YH (2006) Synthesis of CdSxSe1-x nanorods via a solvothermal route. Mater Res Bull 41:99–10910.1016/j.materresbull.2005.07.027 ↗
29. Liu H, Liu Y, Wang Z, He P (2010) Facile synthesis of monodisperse, size-tunable SnS nanoparticles potentially for solar cell energy conversion. Nanotechnology 21:10570710.1088/0957-4484/21/10/105707 ↗
30. Mahendia S, Tomar AK, Chahal RP, Goyal P, Kumar S (2011) Optical and structural properties of poly(vinyl alcohol) films embedded with citrate-stabilized gold nanoparticles. J. Phys. D 44:20510510.1088/0022-3727/44/20/205105 ↗
31. Nanda KK, Kruis FE, Fissan H (2004) Effective mass approximation for two extreme semiconductors: band gap of PbS and CuBr nanoparticles. J Appl Phys 95:5035–504310.1063/1.1691184 ↗
32. Ning J, Men K, Xiao G, Wang L, Dai Q, Zou B, Liu B, Zou G (2010) Facile synthesis of IV–VI SnS nanocrystals with shape and size control: nanoparticles, nanoflowers and amorphous nanosheets. Nanoscale 2:1699–170310.1039/c0nr00052c ↗
33. Nozaki H, Onoda M, Dekita M, Kosuda K, Wada T (2005) Variation of lattice dimensions in epitaxial SnS films on MgO(001). J Solid State Chem 178:245–25210.1016/j.jssc.2004.11.031 ↗
34. Ögüt S, Chelikowsky JR, Louie SG (1997) Quantum confinement and optical gaps in Si nanocrystals. Phys Rev Lett 79:1770–177310.1103/PhysRevLett.79.1770 ↗
35. Ortiz A, Alonso JC, Garcia M, Toriz J (1996) Tin sulphide films deposited by plasma-enhanced chemical vapour deposition. Semicond Sci Technol 11:243–24710.1088/0268-1242/11/2/017 ↗
36. Panda SK, Gorai S, Chaudhuri S (2006) Shape selective solvothermal synthesis of SnS: role of ethylenediamine–water solvent system. Mater Sci Eng B 129:265–26910.1016/j.mseb.2005.12.014 ↗
37. Parenteau M, Carlone C (1990) Influence of temperature and pressure on the electronic transitions in SnS and SnSe semiconductors. Phys Rev B 41:5227–523410.1103/PhysRevB.41.5227 ↗
38. Paul GS, Agarwal P (2007). Structural and stability studies of SnS nanoflakes synthesized by solvothermal process for solar photovoltaic applications. IEEE Conference Proceedings, pp. 884–886
39. Paul GS, Gogoi P, Agarwal P (2008) Structural and stability studies of CdS and SnS nanostructures synthesized by various routes. J Non-Cryst Solids 354:2195–219910.1016/j.jnoncrysol.2007.09.012 ↗
40. Pellegrini G, Mattei G, Mazzoldi P (2005) Finite depth square well model: applicability and limitations. J Appl Phys 97:073706–07371310.1063/1.1868875 ↗
41. Poulopoulos P, Baskoutas S, Pappas SD, Garoufalis CS, Droulias SA, Zamani A, Kapaklis V (2011) Intense quantum confinement effects in Cu2O thin films. J Phys Chem C 115:14839–1484310.1021/jp203145n ↗
42. Price LS, Parkin IP, Field MN, Hardy AME, Clark RJH, Hibbert TG, Molloy KC (2000) Atmospheric pressure chemical vapour deposition of tin(II) sulfide films on glass substrates from Bun3SnO2CCF3 with hydrogen sulfide. J Mater Chem 10:527–53010.1039/a907939d ↗
43. Qian XF, Zhang XM, Wang C, Wang WZ, Xie Y, Qian YT (1999) Solvent–thermal preparation of nanocrystalline tin chalcogenide. J Phys Chem Solids 60:415–41710.1016/S0022-3697(98)00229-7 ↗
44. Rama Krishna MV, Friesner RA (1991) Quantum confinement effects in semiconductor clusters. J Chem Phys 95:8309–832210.1063/1.461258 ↗
45. Reddy KTR, Reddy PP (2002) Structural studies on SnS films grown by a two-stage process. Mater Lett 56:108–11110.1016/S0167-577X(02)00427-5 ↗
46. Reddy NK, Reddy KTR (2006) Optical behaviour of sprayed tin sulphide thin films. Mat Res Bull 41:414–42210.1016/j.materresbull.2005.08.001 ↗
47. Reddy NK, Reddy KTR, Fisher G, Best R, Dutta PK (1999) The structural behaviour of layers of SnS grown by spray pyrolysis. J Phys D 32:988–99010.1088/0022-3727/32/9/307 ↗
48. Rieth M, Schommers W, Baskoutas S (2002) Exact numerical solution of Schrödinger’s equation for a particle in an interaction potential of general shape. Int J Mod Phys B 16:408110.1142/S0217979202014802 ↗
49. Rudel H (2003) Case study: bioavailability of tin and tin compounds. Ecotoxicol Environ Saf 56:180–18910.1016/S0147-6513(03)00061-7 ↗
50. Suslick KS (1988) Ultrasound: its chemical, physical, and biological effects. VCH, New York
51. Suslick KS (1990) Sonochemistry. Science 247:1439–144510.1126/science.247.4949.1439 ↗
52. Suslick K, Doktycz S, Flint E (1990) On the origin of sonoluminescence and sonochemistry. Ultrasonics 28:280–29010.1016/0041-624X(90)90033-K ↗
53. Takeuchi K, Ichimura M, Arai E, Yamazaki Y (2003) SnS thin films fabricated by pulsed and normal electrochemical deposition. Sol Energy Mater Sol Cells 75:427–43210.1016/S0927-0248(02)00192-7 ↗
54. Tanusevski A (2003) Optical and photoelectric properties of SnS thin films prepared by chemical bath deposition. Semicond Sci Technol 18:50110.1088/0268-1242/18/6/318 ↗
55. Thangaraju B, Kaliannan P (2000) Spray pyrolytic deposition and characterization of SnS and SnS2 thin films. J Phys D 33:1054–105910.1088/0022-3727/33/9/304 ↗
56. Trindade T, O’Brien P, Pickett NL (2001) Nanocrystalline semiconductors: synthesis, properties, and perspectives. Chem Mater 13:3843–385810.1021/cm000843p ↗
57. Vidal J, Lany S, d’Avezac M, Zunger A, Zakutayev A, Francis J, Tate J (2012) Band-structure, optical properties, and defect physics of the photovoltaic semiconductor SnS. Appl Phys Lett 100:032104–03210710.1063/1.3675880 ↗
58. Wang Y, Herron N (1990) Quantum size effects on the exciton energy of CdS clusters. Phys Rev B 42:7253–725510.1103/PhysRevB.42.7253 ↗
59. Wang H, Zhang JR, Zhao XN, Xu S, Zhu JJ (2002) Preparation of copper monosulfide and nickel monosulfide nanoparticles by sonochemical method. Mater Lett 55:253–25810.1016/S0167-577X(01)00656-5 ↗
60. Winship KA (1998) Toxicity of tin and its compounds. Adverse Drug React Acute Poisoning Rev 7:19–38
61. Yue GH, Peng DL, Yan PX, Wang LS, Wang W, Luo XH (2009) Structure and optical properties of SnS thin film prepared by pulse electrodeposition. J Alloy Compd 468:254–25710.1016/j.jallcom.2008.01.047 ↗
62. Zhao Y, Zhang Z, Dang H, Liu W (2004) Synthesis of tin sulfide nanoparticles by a modified solution dispersion method. Mater Sci Eng B 113:175–17810.1016/j.mseb.2004.08.003 ↗
63. Zhu L, Meng J, Cao X (2008) Sonochemical synthesis of monodispersed KY3F10:eu3+ nanospheres with bimodal size distribution. Mater Lett 62:3007–300910.1016/j.matlet.2008.01.096 ↗