journal article·2024-06

Development of a novel treatment strategy for the removal of cadmium from wastewater samples using poly(vinyl alcohol)-based magnetic hydrogel beads

Nazime Ebrar Karlıdağ, Tuğçe Göver, Elif Öztürk Er, Gamze Dalgıç Bozyiğit, Fatma Turak, Sezgin Bakırdere

Journal of Nanoparticle Research· Volume 26· Issue 6
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Abstract

This study proposed a treatment strategy based on the application of poly(vinyl alcohol)-based magnetic hydrogel (PVA-MH) beads for the adsorptive removal of cadmium from synthetic domestic wastewater. The hydrogels were prepared through a facile and rapid synthesis procedure and used to remove cadmium ions from domestic wastewater. The influential parameters of adsorption process were studied by varying the type and volume of buffer solution, mass of adsorbent, and shaking period. The optimum parameters of the adsorption process were found as 1.0 mL of pH 8.0 buffer solution, 100 mg of PVA-MH beads, and 30 min orbital shaking. The process of adsorption equilibrium was clarified by the three-parameter Sips model, and outcomes indicated that this model, with an R2 value of 0.9876, fitted the experimental data effectively. Moreover, sorption kinetic results are well described by the pseudo-second-order kinetic model. The findings indicated that both monolayer adsorption and multi-site interactions governed the adsorption of cadmium onto the hydrogel surface and the swelling characteristics of PVA-MH beads had a low influence on the adsorption mechanism.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Extraction and Separation Processes

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References (61)

Show source-provided references
1. Al-Emam E, Soenen H, Caen J, Janssens K (2020) Characterization of polyvinyl alcohol-borax/agarose (PVA-B/AG) double network hydrogel utilized for the cleaning of works of art. Heritage Science 8(1):106. https://doi.org/10.1186/s40494-020-00447-310.1186/s40494-020-00447-3 ↗
2. Al-Rashdi B, Somerfield C, Hilal N (2011) Heavy metals removal using adsorption and nanofiltration techniques. Sep Purif Rev 40(3):209–25910.1080/15422119.2011.558165 ↗
3. An F-Q, Wu R-Y, Li M, Hu T-P, Gao J-F, Yuan Z-G (2017) Adsorption of heavy metal ions by iminodiacetic acid functionalized D301 resin: kinetics, isotherms and thermodynamics. React Funct Polym 118:42–50. https://doi.org/10.1016/j.reactfunctpolym.2017.07.00510.1016/j.reactfunctpolym.2017.07.005 ↗
4. Asy-Syifa N, Waresindo WX, Edikresnha D, Suciati T, Khairurrijal K (2022) The study of the swelling degree of the PVA hydrogel with varying concentrations of PVA. J Phys: Conf Ser 2243(1):12053
5. Atia AA, Donia AM, ELwakeel KZ (2005) Adsorption behaviour of non-transition metal ions on a synthetic chelating resin bearing iminoacetate functions. Sep Purif Technol 43(1):43–48. https://doi.org/10.1016/j.seppur.2004.09.01210.1016/j.seppur.2004.09.012 ↗
6. Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4(4):361–37710.1016/j.arabjc.2010.07.019 ↗
7. Benettayeb A, Morsli A, Elwakeel KZ, Hamza MF, Guibal E (2021) Recovery of heavy metal ions using magnetic glycine-modified chitosan—application to aqueous solutions and tailing leachate. Appl Sci 11(18):8377. https://doi.org/10.3390/app1118837710.3390/app11188377 ↗
8. Burakov AE, Galunin EV, Burakova IV, Kucherova AE, Agarwal S, Tkachev AG, Gupta VK (2018) Adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: a review. Ecotoxicol Environ Saf 148:702–71210.1016/j.ecoenv.2017.11.034 ↗
9. Chai WS, Cheun JY, Kumar PS, Mubashir M, Majeed Z, Banat F, Ho S-H, Show PL (2021) A review on conventional and novel materials towards heavy metal adsorption in wastewater treatment application. J Clean Prod 296:12658910.1016/j.jclepro.2021.126589 ↗
10. Chen X, Hossain MF, Duan C, Lu J, Tsang YF, Islam MS, Zhou Y (2022) Isotherm models for adsorption of heavy metals from water - a review. In Chemosphere 307:135545. https://doi.org/10.1016/j.chemosphere.2022.135545. (Elsevier Ltd)10.1016/j.chemosphere.2022.135545 ↗
11. de Oliveira da Mota I, de Castro JA, de GóesCasqueira R, de Oliveira Junior AG (2015) Study of electroflotation method for treatment of wastewater from washing soil contaminated by heavy metals. J Mater Res Technol 4(2):109–11310.1016/j.jmrt.2014.11.004 ↗
12. El-Sheikh AH, Qawariq RF, Abdelghani JI (2019) Adsorption and magnetic solid-phase extraction of NSAIDs from pharmaceutical wastewater using magnetic carbon nanotubes: effect of sorbent dimensions, magnetite loading and competitive adsorption study. Environ Technol Innov 16:10049610.1016/j.eti.2019.100496 ↗
13. Elgarahy AM, Eloffy MG, Guibal E, Alghamdi HM, Elwakeel KZ (2023) Use of biopolymers in wastewater treatment: a brief review of current trends and prospects. Chinese J Chem Eng 64:29210.1016/j.cjche.2023.05.018 ↗
14. Elgueta E, Sánchez J, Dax D, Xu C, Willför S, Rivas BL, González M (2016) Functionalized galactoglucomannan-based hydrogels for the removal of metal cations from aqueous solutions. J Appl Polym Sci 133(41):1–8. https://doi.org/10.1002/app.4409310.1002/app.44093 ↗
15. Elwakeel KZ, El-Bindary AA, Kouta EY (2017) Retention of copper, cadmium and lead from water by Na-Y-Zeolite confined in methyl methacrylate shell. J Environ Chem Eng 5(4):3698–3710. https://doi.org/10.1016/j.jece.2017.06.04910.1016/j.jece.2017.06.049 ↗
16. Elwakeel KZ, Ahmed MM, Akhdhar A, Alghamdi HM, Sulaiman MGM, Hamza MF, Khan ZA (2023) Effect of the magnetic core in alginate/gum composite on adsorption of divalent copper, cadmium, and lead ions in the aqueous system. Int J Biol Macromol 253:126884. https://doi.org/10.1016/j.ijbiomac.2023.12688410.1016/j.ijbiomac.2023.126884 ↗
17. Elwakeel KZ, Hamza MF, Guibal E (2021) Effect of agitation mode (mechanical, ultrasound and microwave) on uranium sorption using amine-and dithizone-functionalized magnetic chitosan hybrid materials. Chem Eng J 411:12855310.1016/j.cej.2021.128553 ↗
18. Gu S, Kang X, Wang L, Lichtfouse E, Wang C (2019) Clay mineral adsorbents for heavy metal removal from wastewater: a review. Environ Chem Lett 17:629–65410.1007/s10311-018-0813-9 ↗
19. Guo X, Ge J, Yang C, Wu R, Dang Z, Liu S (2015) Sorption behavior of tylosin and sulfamethazine on humic acid: kinetic and thermodynamic studies. RSC Adv 5(72):58865–5887210.1039/C5RA08684A ↗
20. Gurreri L, Tamburini A, Cipollina A, Micale G (2020) Electrodialysis applications in wastewater treatment for environmental protection and resources recovery: a systematic review on progress and perspectives. Membranes 10(7):14610.3390/membranes10070146 ↗
21. Hamzenejad Taghlidabad R, Sepehr E, Khodaverdiloo H, Samadi A, Rasouli-Sadaghiani MH (2020) Characterization of cadmium adsorption on two cost-effective biochars for water treatment. Arab J Geosci 13(12):448. https://doi.org/10.1007/s12517-020-05477-610.1007/s12517-020-05477-6 ↗
22. Hasan I, Ahamd R (2019) A facile synthesis of poly (methyl methacrylate) grafted alginate@Cys-bentonite copolymer hybrid nanocomposite for sequestration of heavy metals. Groundw Sustain Dev 8:82–92. https://doi.org/10.1016/j.gsd.2018.09.00310.1016/j.gsd.2018.09.003 ↗
23. Huang Y, Wang D, Liu W, Zheng L, Wang Y, Liu X, Fan M, Gong Z (2020) Rapid screening of rhodamine B in food by hydrogel solid-phase extraction coupled with direct fluorescence detection. Food Chem 316:126378. https://doi.org/10.1016/j.foodchem.2020.12637810.1016/j.foodchem.2020.126378 ↗
24. Hui B, Zhang Y, Ye L (2015) Structure of PVA/gelatin hydrogel beads and adsorption mechanism for advanced Pb(II) removal. J Ind Eng Chem 21:868–876. https://doi.org/10.1016/j.jiec.2014.04.02510.1016/j.jiec.2014.04.025 ↗
25. Imyim A, Thanacharuphamorn C, Saithongdee A, Unob F, Ruangpornvisuti V (2016) Simultaneous removal of Ag (I), Cd (II), Cr (III), Ni (II), Pb (II), and Zn (II) from wastewater using humic acid-coated aminopropyl silica gel. Desalin Water Treat 57(37):17411–1742010.1080/19443994.2015.1085445 ↗
26. Kaji M (2012) Role of experts and public participation in pollution control: the case of Itai-itai disease in Japan1. Ethics Sci Environ Polit 12(2):99–11110.3354/esep00126 ↗
27. Karlıdağ NE, Demirel R, Serbest H, Turak F, Bakırdere S (2023) Determination of cobalt in chamomile tea samples at trace levels by flame atomic absorption spectrophotometry after poly (vinyl alcohol)-magnetic hydrogel based dispersive solid phase extraction. Anal Methods 15(1):56–6210.1039/D2AY01493A ↗
28. Kavand M, Eslami P, Razeh L (2020) The adsorption of cadmium and lead ions from the synthesis wastewater with the activated carbon: optimization of the single and binary systems. J Water Process Eng 34:10115110.1016/j.jwpe.2020.101151 ↗
29. Kumar M, Kushwaha A, Goswami L, Singh AK, Sikandar M (2021) A review on advances and mechanism for the phycoremediation of cadmium contaminated wastewater. Clean Eng Technol 5:10028810.1016/j.clet.2021.100288 ↗
30. Kundu D, Mondal SK, Banerjee T (2019) Development of β-cyclodextrin-cellulose/hemicellulose-based hydrogels for the removal of Cd(II) and Ni(II): synthesis, kinetics, and adsorption aspects. J Chem Eng Data 64(6):2601–2617. https://doi.org/10.1021/acs.jced.9b0008810.1021/acs.jced.9b00088 ↗
31. Kwikima MM, Mateso S, Chebude Y (2021) Potentials of agricultural wastes as the ultimate alternative adsorbent for cadmium removal from wastewater. A review Scientific African 13:e0093410.1016/j.sciaf.2021.e00934 ↗
32. Luo Q, Ren T, Lei Z, Huang Y, Huang Y, Xu D, Wan C, Guo X, Wu Y (2022) Non-toxic chitosan-based hydrogel with strong adsorption and sensitive detection abilities for tetracycline. Chem Eng J 427:131738. https://doi.org/10.1016/j.cej.2021.13173810.1016/j.cej.2021.131738 ↗
33. Ma J, Liu Y, Ali O, Wei Y, Zhang S, Zhang Y, Cai T, Liu C, Luo S (2018) Fast adsorption of heavy metal ions by waste cotton fabrics based double network hydrogel and influencing factors insight. J Hazard Mater 344:1034–104210.1016/j.jhazmat.2017.11.041 ↗
34. Mahmoudian N, Zamani A, Fashi A, Richter P, Abdolmohammad-Zadeh H (2023) Ultra-trace determination of cadmium in water and food samples by a thin-film microextraction using a supported liquid membrane combined with smartphone-based colorimetric detection. Food Chem 421:13619310.1016/j.foodchem.2023.136193 ↗
35. Maltepe E, Öztürk Er E, Bakırdere S (2020) Chitosan magnetic hydrogel based ligandless magnetic solid phase extraction for the accurate and sensitive determination of thallium by slotted-quartz tube flame atomic absorption spectrophotometry with matrix matching calibration strategy. Microchem J 158:105231. https://doi.org/10.1016/j.microc.2020.10523110.1016/j.microc.2020.105231 ↗
36. Manfrin J, Gonçalves Junior AC, Schwantes D, Zimmermann J, Conradi Junior E (2021) Effective Cd2+ removal from water using novel micro-mesoporous activated carbons obtained from tobacco: CCD approach, optimization, kinetic, and isotherm studies. J Environ Health Sci Eng 19(2):1851–1874. https://doi.org/10.1007/s40201-021-00740-810.1007/s40201-021-00740-8 ↗
37. Mashhadikhan S, Amooghin AE, Sanaeepur H, Shirazi MMA (2022) A critical review on cadmium recovery from wastewater towards environmental sustainability. Desalination 535:11581510.1016/j.desal.2022.115815 ↗
38. Mok CF, Ching YC, Muhamad F, Abu Osman NA, Hai ND, Che Hassan CR (2020) Adsorption of dyes using poly(vinyl alcohol) (PVA) and PVA-based polymer composite adsorbents: a review. J Polym Environ 28(3):775–793. https://doi.org/10.1007/s10924-020-01656-410.1007/s10924-020-01656-4 ↗
39. Park CM, Han J, Chu KH, Al-Hamadani YAJ, Her N, Heo J, Yoon Y (2017) Influence of solution pH, ionic strength, and humic acid on cadmium adsorption onto activated biochar: experiment and modeling. J Ind Eng Chem 48:186–19310.1016/j.jiec.2016.12.038 ↗
40. Pellenz L, de Oliveira CRS, da Silva Júnior AH, da Silva LJS, da Silva L, de Souza AAU, de Ulson SMAG, Borba AG, da Silva FHA (2023) A comprehensive guide for characterization of adsorbent materials. Sep Purif Technol 305:12243510.1016/j.seppur.2022.122435 ↗
41. Petrinic I, Korenak J, Povodnik D, Hélix-Nielsen C (2015) A feasibility study of ultrafiltration/reverse osmosis (UF/RO)-based wastewater treatment and reuse in the metal finishing industry. J Clean Prod 101:292–30010.1016/j.jclepro.2015.04.022 ↗
42. Porter JF, McKay G, Choy KH (1999) The prediction of sorption from a binary mixture of acidic dyes using single- and mixed-isotherm variants of the ideal adsorbed solute theory. Chem Eng Sci 54(24):5863–5885. https://doi.org/10.1016/S0009-2509(99)00178-510.1016/S0009-2509(99)00178-5 ↗
43. Qayoom A, Kazmi SA, Ali SN (2017) Equilibrium modelling for adsorption of aqueous Cd (II) onto turmeric: linear versus nonlinear regression analysis. Moroccan J Chem 5(2):2–5
44. Rahimzadeh MR, Rahimzadeh MR, Kazemi S, Moghadamnia A (2017) Cadmium toxicity and treatment: an update. Caspian J Intern Med 8(3):135
45. Renu NA, Agarwal M, Singh K (2017) Methodologies for removal of heavy metal ions from wastewater: an overview. Interdiscip Environ Rev 18(2):124–14210.1504/IER.2017.087915 ↗
46. Salam OEA, Reiad NA, ElShafei MM (2011) A study of the removal characteristics of heavy metals from wastewater by low-cost adsorbents. J Adv Res 2(4):297–30310.1016/j.jare.2011.01.008 ↗
47. Şen NE, Şenol ZM (2023) Effective removal of Allura red food dye from water using cross-linked chitosan-diatomite composite beads. Int J Biol Macromol 253:126632. https://doi.org/10.1016/j.ijbiomac.2023.12663210.1016/j.ijbiomac.2023.126632 ↗
48. Shahat A, Kubra KT, Salman MS, Hasan MN, Hasan MM (2021) Novel solid-state sensor material for efficient cadmium (II) detection and capturing from wastewater. Microchem J 164:10596710.1016/j.microc.2021.105967 ↗
49. Sreńscek-Nazzal J, Narkiewicz U, Morawski AW, Wróbel RJ, Michalkiewicz B (2015) Comparison of optimized isotherm models and error functions for carbon dioxide adsorption on activated carbon. J Chem Eng Data 60(11):3148–3158. https://doi.org/10.1021/acs.jced.5b0029410.1021/acs.jced.5b00294 ↗
50. Sulaymon AH, Mohammed TJ, Al-Najar J (2012) Equilibrium and kinetics studies of adsorption of heavy metals onto activated carbon. Can J Chem Eng Technol 3(4):86
51. Taktak F, Gökçe S (2024) Ultrasound-assisted synthesis of biodegradable graphene oxide-based hydrogel nanocomposites for highly efficient and cost-effective removal of methyl orange from aqueous media. Journal of Water Process Engineering 58:104837. https://doi.org/10.1016/j.jwpe.2024.10483710.1016/j.jwpe.2024.104837 ↗
52. Turan NB, Erkan HS, Chormey DS, Cağlak A, Bakirdere S, Engin GO (2020) Feasibility studies on the effect of natural plant compounds on sludge characteristics in a batch-type aerobic reactor and N-butyryl-L homoserine lactone. Anal Lett 53(15):2431–244410.1080/00032719.2020.1745222 ↗
53. Ugulu I (2015) Determination of heavy metal accumulation in plant samples by spectrometric techniques in Turkey. Appl Spectrosc Rev 50(2):113–15110.1080/05704928.2014.935981 ↗
54. Wang FP, Li GF, Zhou QQ, Yang CX, Wang QZ (2016) Removal of metal ions from aqueous solution with β-cyclodextrin-based hydrogels. Mater Express 6(5):394–402. https://doi.org/10.1166/mex.2016.132910.1166/mex.2016.1329 ↗
55. Wu J, Wang T, Wang J, Zhang Y, Pan W-P (2021) A novel modified method for the efficient removal of Pb and Cd from wastewater by biochar: enhanced the ion exchange and precipitation capacity. Sci Total Environ 754:14215010.1016/j.scitotenv.2020.142150 ↗
56. Wu N, Li Z (2013) Synthesis and characterization of poly(HEA/MALA) hydrogel and its application in removal of heavy metal ions from water. Chem Eng J 215–216:894–902. https://doi.org/10.1016/j.cej.2012.11.08410.1016/j.cej.2012.11.084 ↗
57. Yan L, Wang W, Li X, Duan J, Jing C (2016) Evaluating adsorption media for simultaneous removal of arsenate and cadmium from metallurgical wastewater. J Environ Chem Eng 4(3):2795–280110.1016/j.jece.2016.05.027 ↗
58. Yin X, Ke T, Zhu H, Xu P, Wang H (2023) Efficient removal of heavy metals from aqueous solution using licorice residue-based hydrogel adsorbent. Gels 9(7):55910.3390/gels9070559 ↗
59. Zeng H, Hu Z, Peng C, Deng L, Liu S (2021) Effective adsorption and sensitive detection of Cr(VI) by chitosan/cellulose nanocrystals grafted with carbon dots composite hydrogel. Polymers 13(21):3788. https://doi.org/10.3390/polym1321378810.3390/polym13213788 ↗
60. Zhang Y, Duan X (2020) Chemical precipitation of heavy metals from wastewater by using the synthetical magnesium hydroxy carbonate. Water Sci Technol 81(6):1130–113610.2166/wst.2020.208 ↗
61. Zhu Q, Li Z (2015) Hydrogel-supported nanosized hydrous manganese dioxide: synthesis, characterization, and adsorption behavior study for Pb2+, Cu2+, Cd2+ and Ni2+ removal from water. Chem Eng J 281:69–80. https://doi.org/10.1016/j.cej.2015.06.06810.1016/j.cej.2015.06.068 ↗