journal article·2015-02

Evolution of the localized surface plasmon resonance and electron confinement effect with the film thickness in ultrathin Au films

X. D. Li, T. P. Chen, Y. Liu, K. C. Leong

Journal of Nanoparticle Research· Volume 17· Issue 2
Publisher page

Abstract

Localized surface plasmon resonance (LSPR) and electron confinement effects on the interband transitions and free-electron absorption in ultrathin Au films with the film thicknesses of about 1–12 nm are investigated. A significant evolution of the LSPR, interband transition energies, plasma energy, and conductivity with the film thickness is observed. The evolution is attributed to the changes in the size, shape, and spacing of the self-assembled gold nanoparticles (Au NPs) with the sizes from several nanometers to 110 nm as well as the aggregation of the Au NPs in the Au films.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Plasmonic and Surface Plasmon Research · nanoparticles nucleation surface interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (24)

Show source-provided references
1. Azzam RMA, Bashara NM (1977) Ellipsometry and polarized light. North-Holland, New York
2. Balamurugan B, Maruyama T (2005) Evidence of an enhanced interband absorption in Au nanoparticles: size-dependent electronic structure and optical properties. Appl Phys Lett 87:143105–143107. doi: 10.1063/1.207783410.1063/1.2077834 ↗
3. Fujiwara H, Kondo M (2005) Effects of carrier concentration on the dielectric function of ZnO:Ga and In2O3:Sn studied by spectroscopic ellipsometry: analysis of free-carrier and band-edge absorption. Phys Rev B 71:75101–75109. doi: 10.1103/PhysRevB.71.07510910.1103/PhysRevB.71.075101 ↗
4. Hohenester U, Krenn J (2005) Surface plasmon resonances of single and coupled metallic nanoparticles: a boundary integral method approach. Phys Rev B 72:195429–195437. doi: 10.1103/PhysRevB.72.19542910.1103/PhysRevB.72.195429 ↗
5. Irani GB, Huen T, Wooten F (1972) Optical properties of gold and α-phase gold-aluminum alloys. Phys Rev B 6:2904–2909. doi: 10.1103/PhysRevB.6.290410.1103/PhysRevB.6.2904 ↗
6. Jałochowski M, Strozak M, Zdyb R (2002) Anomalous optical absorption in ultrathin Pb films. Phys Rev B 66:205417–205421. doi: 10.1103/PhysRevB.66.20541710.1103/PhysRevB.66.205417 ↗
7. Kawata S (2013) Plasmonics: future outlook. Jpn J Appl Phys 52:010001. doi: 10.7567/JJAP.52.01000110.7567/JJAP.52.010001 ↗
8. Kelly KL, Coronado E, Zhao LL, Schatz GC (2002) The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment. J Phys Chem B 107:668–677. doi: 10.1021/jp026731y10.1021/jp026731y ↗
9. Kreibig U, CV Fragstein (1969) The limitation of electron mean free path in small silver particles. Z Physik 224:307–323. doi: 10.1007/BF0139305910.1007/BF01393059 ↗
10. Kreibig U, Vollmer M (1995) Optical properties of metal clusters. Springer, New York10.1007/978-3-662-09109-8 ↗
11. Lasser R, Smith NV (1981) Interband optical transitions in gold in the photon energy range 2–25 eV. Solid State Commun 37:507–509. doi: 10.1016/0038-1098(81)90488-910.1016/0038-1098(81)90488-9 ↗
12. Li XD, Chen TP, Liu Y, Leong KC (2014) Influence of localized surface plasmon resonance and free electrons on the optical properties of ultrathin Au films: a study of the aggregation effect. Opt Express 22:5124–5132. doi: 10.1364/OE.22.00512410.1364/OE.22.005124 ↗
13. Link S, El-Sayed MA (2003) Optical properties and ultrafast dynamics of metallic nanocrystals. Annu Rev Phys Chem 54:331–366. doi: 10.1146/annurev.physchem.54.011002.10375910.1146/annurev.physchem.54.011002.103759 ↗
14. Nordlander P, Oubre C, Prodan E, Li K, Stockman MI (2004) Plasmon hybridization in nanoparticle dimers. Nano Lett 4:899–903. doi: 10.1021/nl049681c10.1021/nl049681c ↗
15. Oates TWH, Mücklich A (2005) Evolution of plasmon resonances during plasma deposition of silver nanoparticles. Nanotechnology 16:2606–2611. doi: 10.1088/0957-4484/16/11/02310.1088/0957-4484/16/11/023 ↗
16. Rakic AD, Djurisic AB, Elazar JM, Majewski ML (1998) Optical properties of metallic films for vertical-cavity optoelectronic devices. Appl Opt 37:5271–5283. doi: 10.1364/AO.37.00527110.1364/AO.37.005271 ↗
17. Romaniello P, de Boeij PL (2005) The role of relativity in the optical response of gold within the time-dependent current-density-functional theory. J Chem Phys 122:164303–164306. doi: 10.1063/1.188498510.1063/1.1884985 ↗
18. Schaaff TG et al (1997) Isolation of smaller nanocrystal Au molecules: robust quantum effects in optical spectra. J Phys Chem B 101:7885–7891. doi: 10.1021/jp971438x10.1021/jp971438x ↗
19. Schneider CA, Rasband WS, Eliceiri KW (2012) NIH image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675. doi: 10.1038/nmeth.208910.1038/nmeth.2089 ↗
20. Slepička P, Kolská Z, Náhlík J, Hnatowicz V, Švorčík V (2009) Properties of Au nanolayers on polyethyleneterephthalate and polytetrafluoroethylene. Surf Interface Anal 41:741–745. doi: 10.1002/sia.308210.1002/sia.3082 ↗
21. Tamaru H, Kuwata H, Miyazaki HT, Miyano K (2002) Resonant light scattering from individual Ag nanoparticles and particle pairs. Appl Phys Lett 80:1826–1828. doi: 10.1063/1.146107210.1063/1.1461072 ↗
22. Trivedi N, Ashcroft NW (1988) Quantum size effects in transport properties of metallic films. Phys Rev B 38:12298–12309. doi: 10.1103/PhysRevB.38.1229810.1103/PhysRevB.38.12298 ↗
23. Willets KA, Van Duyne RP (2007) Localized surface plasmon resonance spectroscopy and sensing. Annu Rev Phys Chem 58:267–297. doi: 10.1146/annurev.physchem.58.032806.10460710.1146/annurev.physchem.58.032806.104607 ↗
24. Yong Y, Shigemasha M, Masayuki N, Jianlin S, Weiming H (2006) One-dimensional self-assembly of gold nanoparticles for tunable surface plasmon resonance properties. Nanotechnology 17:2821–2827. doi: 10.1088/0957-4484/17/11/01510.1088/0957-4484/17/11/015 ↗