journal article·2013-09

RETRACTED ARTICLE: Cu2ZnSnSe4 quantum dots with controllable size and quantum confinement effect

Kai Zong, SiHeng Lu, Hao Wang, YuXiu Sun, JingBing Liu, Hui Yan

Journal of Nanoparticle Research· Volume 15· Issue 9
This record is marked as retracted by the source. Review the publisher’s notice before using its findings.
Publisher page

Abstract

Cu2ZnSnSe4 quantum dots (QDs) with controllable sizes have been synthesized via a hot-injection method. The diameters of the QDs range from 3.2 to 10.1 nm with the tunable band gap from 1.27 to 1.54 eV by adjusting the reaction temperatures from 180 to 240 °C. Structural and Raman scattering data confirm that Cu2ZnSnSe4 is obtained without other secondary phases. The band gaps of the QDs with diameters less than 4.6 nm show an obvious blue shift to higher energy due to quantum confinement effect. It indicates that the Cu2ZnSnSe4 QDs can be a potential candidate for quantum-dot-sensitized solar cells in the future.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Altosaar M, Raudoja J, Timmo K, Danilson M, Grossberg M, Krustok J, Mellikov E (2008) Cu2Zn1–xCdx Sn(Se1−ySy)4 solid solutions as absorber materials for solar cells. Physica Status Solidi (a) 205:167–17010.1002/pssa.200776839 ↗
2. Bang JH, Kamat PV (2011) CdSe quantum dot–fullerene hybrid nanocomposite for solar energy conversion: electron transfer and photoelectrochemistry. ACS Nano 5:9421–942710.1021/nn204350w ↗
3. Cao YB, Xiao YJ, Jung JY, Um HD, Jee SW, Choi HM, Bang JH, Lee JH (2013) Highly electrocatalytic Cu2ZnSn(S1−xSex)4 counter electrodes for quantum-dot-sensitized solar cells. ACS Appl Mater Interfaces 5:479–48410.1021/am302522c ↗
4. Debnath R, Tang J, Barkhouse DA, Wang XH, Pattantyus-Abraham AG, Brzozowski L, Levina L, Sargent EH (2010) Ambient-processed colloidal quantum dot solar cells via individual pre-encapsulation of nanoparticles. J Am Chem Soc 132:5952–595310.1021/ja1013695 ↗
5. Diguna LJ, Shen Q, Kobayashi J, Toyoda T (2007) High efficiency of CdSe quantum-dot-sensitized TiO2 inverse opal solar cells. Appl Phys Lett 91:02311610.1063/1.2757130 ↗
6. Franzl T, Klar TA, Schietinger S, Rogach AL, Feldmann J (2004) Exciton recycling in graded gap nanocrystal structures. Nano Lett 4:1599–160310.1021/nl049322h ↗
7. Grossberg M, Krustok J, Timmo K, Altosaar M (2009) Radiative recombination in Cu2ZnSnSe4 monograins studied by photoluminescence spectroscopy. Thin Solid Films 517:2489–249210.1016/j.tsf.2008.11.024 ↗
8. Guo Q, Ford GM, Yang WC, Walker BC, Stach EA, Hillhouse HW, Agrawal R (2010) Fabrication of 7.2 % efficient CZTSSe solar cells using CZTS nanocrystals. J Am Chem Soc 132:17384–1738610.1021/ja108427b ↗
9. Kamat PV (2008) Quantum dot solar cells. Semiconductor nanocrystals as light harvesters. J Phys Chem C 112:18737–1875310.1021/jp806791s ↗
10. Kamat PV (2012) Boosting the efficiency of quantum dot sensitized solar cells through modulation of interfacial charge transfer. Acc Chem Res 45:1906–191510.1021/ar200315d ↗
11. Khare A, Wills AW, Ammerman LM, Norrisz DJ, Aydil ES (2011) Size control and quantum confinement in Cu2ZnSnS4 nanocrystals. Chem Commun 47:11721–1172310.1039/c1cc14687d ↗
12. Lee YL, Lo YS (2009) Highly efficient quantum-dot-sensitized solar cell based on Co-sensitization of CdS/CdSe. Adv Funct Mater 19:604–60910.1002/adfm.200800940 ↗
13. Lee HJ, Chen P, Moon SJ, Sauvage F, Sivula K, Bessho T, Gamelin DR, Comte P, Zakeeruddin SM, Seok SI, Grätzel M, Nazeeruddin MK (2009a) Regenerative PbS and CdS quantum dot sensitized solar cells with a cobalt complex as hole mediator. Langmuir 25:7602–760810.1021/la900247r ↗
14. Lee HJ, Wang M, Chen P, Gamelin DR, Zakeeruddin SM, Grätzel M, Nazeeruddin MK (2009b) Efficient CdSe Quantum dot-sensitized solar cells prepared by an improved successive ionic layer adsorption and reaction process. Nano Lett 9:4221–422710.1021/nl902438d ↗
15. Liu WC, Guo BL, Wu XS, Zhang FM, Mak CL, Wong KH (2013) Facile hydrothermal synthesis of hydrotropic Cu2ZnSnS4 nanocrystal quantum dots: band-gap engineering and phonon confinement effect. J Mater Chem A 1:3182–318610.1039/c3ta00357d ↗
16. Luther JM, Gao JB, Lloyd MT, Semonin OE, Beard MC, Nozik AJ (2010) Stability assessment on a 3% bilayer PbS/ZnO quantum dot heterojunction solar cell. Adv Mater 22:3704–370710.1002/adma.201001148 ↗
17. Nozik AJ (2005) Exciton multiplication and relaxation dynamics in quantum dots: applications to ultrahigh-efficiency solar photon conversion. Inorg Chem 44:6893–689910.1021/ic0508425 ↗
18. Pedro VG, Xu XQ, Seró IM, Bisquert J (2010) Modeling high-efficiency quantum dot sensitized solar cells. ACS Nano 4:5783–579010.1021/nn101534y ↗
19. Persson C (2011) Electronic and optical properties of Cu2ZnSnS4 and Cu2ZnSnSe4. J Appl Phys 107:05371010.1063/1.3318468 ↗
20. Riha SC, Parkinson BA, Prieto AL (2009) Solution-based synthesis and characterization of Cu2ZnSnS4 nanocrystals. J Am Chem Soc 131:12054–1205510.1021/ja9044168 ↗
21. Riha SC, Fredrick SJ, Sambur JB, Liu Y, Prieto AL, Parkinson BA (2011) Photoelectrochemical characterization of nanocrystalline thin-film Cu2ZnSnS4 photocathodes. ACS Appl Mater Interfaces 3:58–6610.1021/am1008584 ↗
22. Steinhagen C, Panthani MG, Akhavan V, Goodfellow B, Koo B, Korgel BA (2009) Synthesis of Cu2ZnSnS4 nanocrystals for use in low-cost photovoltaics. J Am Chem Soc 131:12554–1255510.1021/ja905922j ↗
23. Tisdale WA, Williams KJ, Timp BA, Norris DJ, Aydil ES, Zhu XY (2010) Hot-electron transfer from semiconductor nanocrystals. Science 328:1543–154710.1126/science.1185509 ↗
24. Todorov TK, Reuter KB, Mitzi DB (2010) High-efficiency solar cell with earth-abundant liquid-processed absorber. Adv Mater 22:E156–E15910.1002/adma.200904155 ↗
25. Xu CY, Zhang PX, Yan L (2001) Blue shift of Raman peak from coated TiO2 nanoparticles. J Raman Spectrosc 32:862–86510.1002/jrs.773 ↗
26. Xu J, Yang X, Yang QD, Wong TL, Lee CS (2012) Cu2ZnSnS4 hierarchical microspheres as an effective counter electrode material for quantum dot sensitized solar cells. J Phys Chem C 116:19718–1972310.1021/jp306628m ↗
27. Yin Y, Alivisatos AP (2005) Colloidal nanocrystal synthesis and the organic–inorganic interface. Nature 437:664–67010.1038/nature04165 ↗