journal article·2011-06

Fabrication of silver nanoparticles in a continuous flow, low temperature microwave-assisted polyol process

Grzegorz Dzido, Andrzej B. Jarzębski

Journal of Nanoparticle Research· Volume 13· Issue 6
Publisher page

Abstract

The performed experiments showed that continuous microwave-assisted polyol synthesis at about 70 °C is a viable process to give silver nanoparticles with a narrow size distribution in bulk amounts. The increase of silver precursor concentration in reaction system from 0.0097 to 0.0389 M resulted in the formation of fine nanoparticles 5–10 nm in size, in addition to the larger ones 30–100 nm, and that changed the pattern of particle size distribution from monomodal to bimodal. The effect of specific process variables was found to be the same in the continuous process as in batch operation. An aqueous glycerol solution was found suitable for use as both solvent and reducing agent.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nanoparticles: synthesis and applications · Nanomaterials for catalytic reactions · Microwave-Assisted Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (31)

Show source-provided references
1. Bhattacharyya S, Gedanken A (2008) Microwave-assisted insertion of silver nanoparticles into 3-D mesoporous zinc oxide nanocomposites and nanorods. J Phys Chem C 112:659–665. doi: 10.1021/jp076025310.1021/jp0760253 ↗
2. Bonnemann H, Botha SS, Bladergroen B, Linkov VM (2005) Monodisperse copper- and silver-nanocolloids suitable for heat-conductive fluids. Appl Organomet Chem 19:768–773. doi: 10.1002/aoc.88910.1002/aoc.889 ↗
3. Buongiorno J, Venerus DC, Dzido G, Jarzebski AB et al (2009) A benchmark study on the thermal conductivity of nanofluids. J Appl Phys 106:094312. doi: 10.1063/1.324533010.1063/1.3245330 ↗
4. Cho T, Baek I, Lee J, Park S (2005) Preparation of nanofluid containing suspended silver particles for enhancing fluid thermal conductivity of fluids. J Ind Eng Chem 11(3):400–406
5. Dzido G, Chmiel-Kurowska K, Gierczycki A, Jarzębski AB (2008) Convective heat transfer in Ag– and Cu–ethylene glycol nanofluids. NSTI Nanotechnology Conference, Boston, 2008. Tech Proc 1:778–781
6. Filippo E, Serra A, Manno D (2009) Poly(vinyl alcohol) capped silver nanoparticles as localized surface plasmon resonance-based hydrogen peroxide sensor. Sens Actuators B 138:625–630. doi: 10.1016/j.snb.2009.02.05610.1016/j.snb.2009.02.056 ↗
7. Gao F, Lu Q, Komarneni S (2005) Interface reaction for the self-assembly of silver nanocrystals under microwave-assisted solvothermal conditions. Chem Mater 17:856–860. doi: 10.1021/cm048663t10.1021/cm048663t ↗
8. Glasnov TN, Kappe CO (2007) Microwave-assisted synthesis under continuous-flow conditions. Macromol Rapid Commun 28:395–410. doi: 10.1002/marc.20060066510.1002/marc.200600665 ↗
9. Groisman Y, Gedenken A (2008) Continuous flow, circulating microwave system and its application in nanoparticle fabrication and biodiesel synthesis. J Phys Chem C 112:8802–8808. doi: 10.1021/jp801409t10.1021/jp801409t ↗
10. Jiang H, Moon K, Zhang Z, Pothukuchi S, Wong CP (2006) Variable frequency microwave synthesis of silver nanoparticles. J Nanopart Res 8:117–124. doi: 10.1007/s11051-005-7522-610.1007/s11051-005-7522-6 ↗
11. Khaydarov RA, Khaydarov RR, Gapurova O, Estrin Y, Scheper T (2009) Electrochemical method for the synthesis of silver nanoparticles. J Nanopart Res 11:1193–1200. doi: 10.1007/s11051-008-9513-x10.1007/s11051-008-9513-x ↗
12. Komarneni S, Pidugu R, Li QH, Roy R (1995) Microwave-hydrothermal processing of metal powders. J Mater Res 10:1687–169210.1557/JMR.1995.1687 ↗
13. Kundu S, Wang K, Liang H (2009) Size-controlled synthesis and self-assembly of silver nanoparticles within a minute using microwave irradiation. J Phys Chem C 113:134–141. doi: 10.1021/jp808292s10.1021/jp808292s ↗
14. Li D, Komarneni S (2006) Microwave-assisted polyol process for synthesis of Ni nanoparticles. J Am Ceram Soc 89:1510–1517. doi: 10.1111/j1551-2916.200610.1111/j.1551-2916.2006.00925.x ↗
15. Loginov AV, Gorbunova VV, Boitsova TB (2002) Photochemical synthesis and properties of colloidal copper, silver and gold adsorbed on quartz. J Nanopart Res 4:193–205. doi: 10.1023/A:101996602159810.1023/A:1019966021598 ↗
16. Manoth M, Manzoor K, Patra MK, Pandey P, Vadera SR, Kumar N (2009) Dendrigraft polymer-based synthesis of silver nanoparticles showing bright blue fluorescence. Mat Res Bull 44:714–717. doi: 10.1016/j.materresbull.2008.06.03310.1016/j.materresbull.2008.06.033 ↗
17. Martinez-Castanon GA, Ninio-Martinez N, Martinez-Gutierrez F, Martinez-Mendoza JR, Ruiz F (2008) Synthesis and antibacterial activity of silver nanoparticles with different sizes. J Nanopart Res 10:1343–1348. doi: 10.1007/s11051-008-9428-610.1007/s11051-008-9428-6 ↗
18. Mourdikoudis S, Simeonidis K, Tsiaoussis I, Dendrinou-Samara C, Angelakeris M, Kalogriou O (2009) Impact of synthesis parameters on structural and magnetic characteristics of Co-based nanoparticles. J Nanopart Res 11:1477–1484. doi: 10.1007/s11051-008-9428-610.1007/s11051-008-9567-9 ↗
19. Pastoriza-Santos I, Liz-Marzan LM (2002) Formation of PVP-protected metal nanoparticles in DMF. Langmuir 18:2888–2894. doi: 10.1021/la015578g10.1021/la015578g ↗
20. Petit Ch, Lixonf P, Pileni MP (1993) In situ synthesis of silver nanocluster in AOT reverse micelles. J Phys Chem 97:12974–12983. doi: 10.1021/j100151a05410.1021/j100151a054 ↗
21. Rai M, Yadav A, Gade A (2009) Silver nanoparticles as a new generation of antimicrobials. Biotechnol Adv 27:76–83. doi: 10.1016/j.biotechadv.2008.09.00210.1016/j.biotechadv.2008.09.002 ↗
22. Stadler A, Yousefi BH, Dallinger D, Walla P, Eycken E, Kaval N, Kappe CO (2003) Scalability of microwave–assisted organic synthesis. From single- mode to multimode parallel batch reactors. Org Proc Res Dev 7:707–716. doi: 10.1021/op034075+10.1021/op034075+ ↗
23. Starowicz M, Stypuła B, Banaś J (2006) Electrochemical synthesis of silver nanoparticles. Electrochem Commun 8:227–230. doi: 10.1016/j.elecom.2005.11.01810.1016/j.elecom.2005.11.018 ↗
24. Sun Y, Xia Y (2002) Large-scale synthesis of uniform silver nanowires through a soft, self-ending, polyol process. Adv Mater 14(11):833–83710.1002/1521-4095(20020605)14:11<833::AID-ADMA833>3.0.CO;2-K ↗
25. Tsuji M, Hashimoto M, Nishizawa Y, Kubokawa M, Tsuji T (2005) Microwave-assisted synthesis of metallic nanostructures in solution. Chem Eur J 11:440–452. doi: 10.1002/chem.20040041710.1002/chem.200400417 ↗
26. Tu W, Liu H (2000) Continuous synthesis of colloidal metal nanoclusters by microwave irradiation. Chem Mater 12:564–567. doi: 10.1021/cm990637l10.1021/cm990637l ↗
27. Wu Ch, Zeng T (2005) Size-tunable synthesis of metallic nanoparticles in a continuous and steady-flow reactor. Chem Mater 19(2):123–125. doi: 10.1021/cm062344f
28. Xie Y, Ye R, Liu H (2006) Synthesis of silver nanoparticles in reverse micelles stabilized by natural biosurfactant. Colloids Surf A Physicochem Eng Aspects 279:175–17810.1016/j.colsurfa.2005.12.056 ↗
29. Zhang J, Chen P, Sun Ch, Hu X (2004) Sonochemical synthesis of colloidal silver catalysts for reduction of complexing silver in DTR system. Appl Catal A 266:49–54. doi: 10.1016/j.apcata.2004.01.02510.1016/j.apcata.2004.01.025 ↗
30. Zhang W, Qiao X, Chen J (2008) Formation of silver nanoparticles in SDS inverse microemulsions. Mat Chem Phys 109:411–416. doi: 10.1016/j.matchemphys.2007.12.00910.1016/j.matchemphys.2007.12.009 ↗
31. Zhua H, Zhang C, Yin Y (2004) Rapid synthesis of copper nanoparticles by sodium hypophosphite reduction in ethylene glycol under microwave irradiation. J Crystal Growth 270:722–728. doi: 10.1016/j.jcrysgro.2004.07.00810.1016/j.jcrysgro.2004.07.008 ↗