Recent advances in the development of nanocomposites for effective removal of pesticides from aqueous stream
Source abstract
Abstract
Pesticides play a significant key role in the agriculture sector. In India, there is a sharp increase in pesticides consumption in recent years, leading to severe implications. Due to the rapid use of pesticides, there is residue in the food, which leads to poor effects on human health. Furthermore, the discharge of various pesticides into water bodies from the industries and agricultural activities leads to environmental concerns. Because of their toxicity, persistent nature, and bioaccumulation potential, it is essential to remove pesticides from water. Nanoparticles are tiny particles whose size ranges from 1 to 100 nm. Nanomaterials have a large surface area, a large number of active sites, and high reactivity. Therefore, nanotechnology is a fast, efficient, and economical process. Nanotechnology plays an influential role in the removal of various pesticides from water and wastewater. In recent years, various nanomaterials, such as TiO2, ZVI, Zn, and rGO (reduced graphene oxide), CNTs (carbon nanotubes), and polymer-supported nanomaterials are widely used for the removal of pesticides from water. In this review, detailed information about various pesticides and their removal with the help of nanocomposites has been discussed.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Graphene and Nanomaterials Applications · Adsorption and biosorption for pollutant removal · Nanoparticles: synthesis and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Abdelhaleem A, Chu W (2019) Insights into peroxymonosulfate activation for carbofuran degradation under visible LED via a double-component photocatalyst of Fe (III) impregnated N-doped TiO2. Chemosphere 237:124487. https://doi.org/10.1016/j.chemosphere.2019.12448710.1016/j.chemosphere.2019.124487 ↗
2. Abd El-Aziz, AR, Al-Othman MR, Mahmoud MA (2018) Degradation of DDT by gold nanoparticles synthesised using Lawsonia inermis for environmental safety. Biotechnology & Biotechnological Equipment 1–9. https://doi.org/10.1080/13102818.2018.150205110.1080/13102818.2018.1502051 ↗
3. Ahmadifard T, Heydari R, Tarrahi MJ, Khorramabadi GS (2019) Photocatalytic degradation of diazinon in aqueous solutions using immobilized MgO nanoparticles on concrete. Int J Chem React Eng 20180154. https://doi.org/10.11515/ijcre-2018-15410.11515/ijcre-2018-154 ↗
4. Ali I, ALOthman ZA, Al-Warthan A (2016) Sorption, kinetics and thermodynamics studies of atrazine herbicide removal from water using iron nano-composite material. Int J Environ Sci Technol 13:733–74210.1007/s13762-015-0919-6 ↗
5. Asgari G, Seidmohammadi A, Esrafili A, Noori Sepehr M, Jafarinia M (2020) The catalytic ozonation of diazinon using nano-MgO@CNT@Gr as a new heterogenous catalyst: the optimization of effective factors by response surface methodology. RSC Advances 10:7718–773110.1039/C9RA10095D ↗
6. Agency for toxic substances and disease registry, U.S. Department of Health and Human Services. Toxicologic profile for alpha-, beta, gamma- and delta-hexachlorocyclohenxane. August 2005
7. Alkayal NS, Hussein MA (2019) Photocatalytic degradation of atrazine under visible light using novel Ag@Mg4Ta2O9 nanocomposites. Scientific Reports 9:7470. https://doi.org/10.1038/s41598-019-43915-y10.1038/s41598-019-43915-y ↗
8. Arienzo M, Masuccio AA, Ferrara L (2013) Evaluation of sediment contamination by heavy metals, organochlorinated pesticides, and polyaromatic hydrocarbons in the Berre coastal lagoon (Southeast France). Arch Environ Contam Toxicol 65:396–40610.1007/s00244-013-9915-3 ↗
9. Aragay G, Pino F, Merkoçi A (2012) Nanomaterials for sensing and destroying pesticides. Chem Rev 112(10):5317–5338. https://doi.org/10.1021/cr300020c10.1021/cr300020c ↗
10. Atwan AA, Elmehasseb IM, Talha N, El‐Kemary M (2020) Parameters affecting carbofuran photocatalytic degradation in water using ZnO nanoparticles. J Chinese Chem Soc 1–1010.1002/jccs.201900532 ↗
11. "A valuable reputation (n.d.) Tyrone Hayes said that a chemical was harmful, its maker pursued him" by Rachel Aviv, The New Yorker, 10 February 2014
12. Bandala ER, Gelover S, Leal MT, Arancibia-Bulnes C, Jimenez A, Estrada CA (2002) Solar photocatalytic degradation of aldrin. Catal Today 76:189–19910.1016/S0920-5861(02)00218-3 ↗
13. "Basic information about pesticide ingredients". US Environmental Protection Agency. Apr 2, 2018. Retrieved Dec 1, 2018
14. Beard J (2006) DDT and human health. Sci Total Environ 355:78–8910.1016/j.scitotenv.2005.02.022 ↗
15. Bhoj Y, Pandey G, Bhoj A, Tharmavaram M, Rawtani D (2021) Recent advancement in practices related to desalination by means of nanotechnology. Chem Phys Impact 2:10002510.1016/j.chphi.2021.100025 ↗
16. Blodgett DJ (2006) Organophosphate and carbamate insecticides. Small animal toxicology, 2nd ed.; Peterson ME Talcott PA Eds. Elsevier Saunders, Saint Louis, pp 941–95310.1016/B0-72-160639-3/50069-1 ↗
17. Bonner MR, Coble J, Blair A, Freeman LEB, Hoppin JA, Sandler DA, Alavanja MCR (2007b) Malathion exposure and the incidence of cancer in the agricultural health study. Am J Epidemiol 166(9):1023–103410.1093/aje/kwm182 ↗
18. Bonner MR, Coble J, Blair A et al (2007) Malathion exposure and the incidence of cancer in the agricultural health study. Am J Epidemiol 166(9):1023–103410.1093/aje/kwm182 ↗
19. Bonner MR, Coble J, Blair A et al (2007a) Malathion exposure and the incidence of cancer in the agricultural health study. Am J Epidemiol 166(9):1023–103410.1093/aje/kwm182 ↗
20. Boussahel R, Harik D, Mammar M, Lamara-Mohamed S (2007) Degradation of obsolete DDT by Fenton oxidation with zero-valent iron. Desalination 206:369–37210.1016/j.desal.2006.04.059 ↗
21. Canevari TC, Prado TM, Cincotto FH, Machado SAS (2016) Immobilization of ruthenium phthalocyanine on silica-coated multi-wall partially oriented carbon nanotubes: electrochemical detection of fenitrothion pesticide. Mater Res Bull 76:41–4710.1016/j.materresbull.2015.12.007 ↗
22. California Department of Pesticide Regulation (2008) What are the potential health effects of pesticides? Community guide to recognizing and reporting pesticide problems. Sacramento, CA. Pages 27–29
23. Chemical review: atrazine (2015) Australian pesticides and veterinary medicines authority. 2014–05–28. Retrieved 2015–02–11. https://apvma.gov.au/node/12371
24. Chen GC, Shan XQ, Zhou YQ, Shen XE, Huang HL, Khan SU (2009) Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes. J Hazard Mater 169:912–918. https://doi.org/10.1016/j.jhazmat.2009.04.03410.1016/j.jhazmat.2009.04.034 ↗
25. Chen L, Hosseini M, Fakhri A, Fazelian N, Nasr SM, Nobakht N (2019) Synthesis and characterization of Cr2S3–Bi2O3 nanocomposites: photocatalytic, quenching, repeatability, and antibacterial performances. J Mater Sci Mater Electron 30:13067–13075. https://doi.org/10.1007/s10854-019-01668-410.1007/s10854-019-01668-4 ↗
26. Chen H, Yang S, Yu K, Ju Y, Sun C (2011) Effective photocatalytic degradation of atrazine over titania-coated carbon nanotubes (CNTs) coupled with microwave energy. J Phys Chem A 115:3034–304110.1021/jp109948n ↗
27. Cheney MA, Fiorillo R, Criddle RS (1997) Herbicide and estrogen effects on the metabolic activity of Elliptio complanata measured by calorespirometry. Comp Biochem Physiol C Pharmacol Toxicol Endocrinol 118(2):159–16410.1016/S0742-8413(97)00102-3 ↗
28. Ci Y Wang S Zhang X Fang Z Ma A Huang Z (2018) Chemical warfare agents’ degradation on Fe–Cu codoped TiO2 nanoparticles. Appl Physics A 124(11). https://doi.org/10.1007/s00339-018-2209-x10.1007/s00339-018-2209-x ↗
29. Choi M, Lee IS, Jung RH (2016) Rapid determination of organochlorine pesticides in fish using selective pressurized liquid extraction and gas chromatography-mass spectrometry. Food Chem 205:1–810.1016/j.foodchem.2016.02.156 ↗
30. Comber S, Gardner M (1999) An assessment of trends in European environmental data for mercury and chlorinated organic compounds in water and biota. Sci Total Environ 244:193–20110.1016/S0048-9697(99)00388-5 ↗
31. Cone Marla (2005) EPA takes pest killer diazinon off the shelves. Los Angeles Times. Retrieved 2 Jul 2020
32. Cortes DR, Hites RA (2000) Detection of statistically significant trends in atmospheric concentrations of semivolatile compounds. Environ Sci Technol 34:2826–282910.1021/es990466l ↗
33. Cornell University (n.d.) Pesticides in the environment archived 2009–06–05 at the Wayback Machine. Pesticide fact sheets and tutorial, . Pesticide Safety Education Program. Retrieved on 2007–10–11
34. Das K, Majhi D, Bariki R, Mishra BG (2020) SnS2 /Bi4Ti3O12 Heterostructure material: a UV-visible light active direct Z-scheme photocatalyst for aqueous phase degradation of diazinon. ChemistrySelect 5(4):1567–157710.1002/slct.201904532 ↗
35. Dewhurst, Patrick (2011) Alarm over new pet poison. Cyprus Mail. Archived from the original on May 28, 2011
36. Donaldson D Kiely T Grube A Pesticide's industry sales and usage 1998–1999 market estimates. US Environmental Protection Agency; Washington (DC): Report No. EPA-733-R-02-OOI
37. Duarte AALS, Amorim MTSP (2020) Performance assessment of micropollutants removal from water using advanced oxidation processes Wseas Transactions on environment and development., volume 16. https://doi.org/10.37394/232015.2020.16.710.37394/232015.2020.16.7 ↗
38. Economic benefits of pest management (2002) R. Peshin, encyclopedia of pest management, pages 224–227, Pub Marcel Dekker
39. Ebrahimi R, Maleki A, Rezaee R, Daraei H, Safari M, McKay G, … Jafari A (2020) Synthesis and application of Fe-Doped TiO2 nanoparticles for photodegradation of 2,4-D from aqueous solution. Arab J Sci Eng. https://doi.org/10.1007/s13369-020-05071-810.1007/s13369-020-05071-8 ↗
40. Edwards D (2006) Reregistration eligibility decision for malathion (PDF). US Environmental Protection Agency - Prevention, Pesticides and Toxic Substances
41. Ejobi F, Kanja LW, Kyule MN, Muller P, Kruger J, Latigo AAR (1996) Organochlorine pesticide residues in mother’s milk in Uganda. Bull Environ Contam Toxicol 56:873–88810.1007/s001289900127 ↗
42. Elliott DW, Lien HL, Zhang WX (2009) Degradation of lindane by zero-valent iron nanoparticles. J Environ Eng 135:317–32410.1061/(ASCE)0733-9372(2009)135:5(317) ↗
43. "EPA bans carbofuran pesticide residues on food". Environmental News Service. May 11, 2009. Retrieved June 5, 2009
44. Forget G Goodman T de Villiers A (1990) Impact of pesticide use on health in developing countries, Proceedings of a symposium held in Ottawa, Canada, 17–20 September 1990. Ottawa: Int Dev Res Centre
45. Fouad DM, Mohamed MB (2012) Comparative study of the photocatalytic activity of semiconductor nanostructures and their hybrid metal nanocomposites on the photodegradation of malathion. J Nanomater 2012:1–810.1155/2012/524123 ↗
46. Fouad DM, El-Said WA, Mohamed MB (2015) Spectroscopic characterization of magnetic Fe3O4@Au core shell nanoparticles. Spectrochim Acta Part A Mol Biomol Spectrosc 140:392–39710.1016/j.saa.2014.12.097 ↗
47. Four Corners By Janine Cohen (2013) Four corners investigation finds dangerous dioxins in widely used herbicide 24D". Abc.net.au. Retrieved 2014–05–03
48. Galloway TS, Depledge MH (2001) Immunotoxicity in invertebrates: measurement and ecotoxicological relevance. Ecotoxicology 10(1):5–2310.1023/A:1008939520263 ↗
49. Gar Alalm M, Ookawara S, Fukushi D, Sato A, Tawfik A (2016) Improved WO3 photocatalytic efficiency using ZrO2 and Ru for the degradation of carbofuran and ampicillin. J Hazard Mater 302:225–23110.1016/j.jhazmat.2015.10.002 ↗
50. Gautam SK, Suresh S (2007) Studies on dechlorination of DDT (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane) using magnesium/palladium bimetallic system. J Hazard Mater 139:146–15310.1016/j.jhazmat.2006.06.017 ↗
51. Gillion, RJ; Barbash, JE; Crawford, GG; Hamilton, PA; Martin, JD; Nakagaki, N; Nowell, LH; Scott, JC; Stackelberg, PE; Thelin, GP; Wolock, DM (2007–02–15) [2006]. "1. Overview of findings and implications". Pesticides in the Nation's Streams and Ground Water, 1992–2001 (Report). The quality of our nation’s waters. Reston, VA: US Geological Survey. p. 4. Circular 129110.3133/cir1291 ↗
52. González AE, Asomoza M, Solís S et al (2020) Enhanced photocatalytic degradation of the herbicide 2,4-dichlorophenoxyacetic acid by Pt/TiO2–SiO2 nanocomposites. Reac Kinet Mech Cat 131:489–503. https://doi.org/10.1007/s11144-020-01865-x10.1007/s11144-020-01865-x ↗
53. Grobler R (2019) As many as 1 000 dogs poisoned per week in SA. News24. Archived from the original on August 4, 2019. Retrieved November 12, 2019
54. Gupta SM, Tripathi M (2011) A review of TiO2 nanoparticles. Chin Sci Bull 56:163910.1007/s11434-011-4476-1 ↗
55. Gunnell D, Eddleston M, Phillips MR et al (2007) The global distribution of fatal pesticide self-poisoning: systematic review. BMC Public Health 7(1):35710.1186/1471-2458-7-357 ↗
56. Hong SH, Shim WJ, Han GM, Ha SY, Jang M, Rani M, Hong S, Yeo GY (2014) Levels and profiles of persistent organic pollutants in resident and migratory birds from an urbanized coastal region of South Korea. Sci Total Environ 470–471:1463–147010.1016/j.scitotenv.2013.07.089 ↗
57. Hossaini H, Moussavi G, Farrokhi M (2014) The investigation of the LED-activated FeFNS-TiO2 nanocatalyst for photocatalytic degradation and mineralization of organophosphate pesticides in water. Water Res 59:130–144. https://doi.org/10.1016/j.watres.2014.04.00910.1016/j.watres.2014.04.009 ↗
58. "Ingredients used in pesticide products 2,4-D (2014) EPA. 2014–09–22. www2.epa.gov. Retrieved November 6, 2014
59. Israel B (2012) Common insecticide may harm boys’ brains more than girls’. Sci Am. https://www.scientificamerican.com/article/common-insecticide-may-harm-boys-brains-more-than-girls/
60. Jeyaratnam J, de Alwis Seneviratne RS, Copplestone JF (1982) Survey of pesticide poisoning in Sri Lanka. Bull World Health Organ 60(4):615–619
61. Jonidi-Jafari A, Shirzad-Siboni M, Yang JK, Naimi-Joubani M, Farrokhi M (2015) J Taiwan Inst Chem Eng 50:100–10710.1016/j.jtice.2014.12.020 ↗
62. Joo SH, Zhao D (2008) Destruction of lindane and atrazine using stabilized iron nanoparticles under aerobic and anaerobic conditions: effects of catalyst and stabilizer. Chemosphere 70:418–42510.1016/j.chemosphere.2007.06.070 ↗
63. Jo W-K, Natarajan TS (2015) Influence of TiO2 morphology on the photocatalytic efficiency of direct Z-scheme g-C3N4/TiO2 photocatalysts for isoniazid degradation. Chem Eng J 281:549–56510.1016/j.cej.2015.06.120 ↗
64. Kamrin MA (1997) Pesticide profiles: toxicity, environmental impact, and fate. Lewis Publishers, New York
65. Kadam AN, Dhabbe RS, Kokate MR, Gaikwad YB, Garadkar KM (2014) Preparation of N doped TiO2 via microwave-assisted method and its photocatalytic activity for degradation of malathion. Spectrochim Acta Part A Mol Biomol Spectrosc 133:669–67610.1016/j.saa.2014.06.020 ↗
66. Kafilzadeh F (2015) Assessment of organochlorine pesticide residues in water, sediments and fish from Lake Tashk. Iran Arch Life Sci 9:107–111
67. Kalidhasan S, Ben-Sasson M, Dror I, Carmieli R, Schuster EM, Berkowitz B (2016) Oxidation of aqueous organic pollutants using a stable copper nanoparticle suspension. Can J Chem Eng 95(2):343–352. https://doi.org/10.1002/cjce.2265210.1002/cjce.22652 ↗
68. Kamarudin NS, Jusoh R, Sukor NF, Jalil AA, Setiabudi HD (2020) Intensified photocatalytic degradation of 2, 4–dicholorophenoxyacetic acid using size-controlled silver nanoparticles: effect of pre-synthesis extraction. Adv Powder Technol 31(8):3381–339410.1016/j.apt.2020.06.023 ↗
69. Kannan K, Tanabe S, Ramesh A, Subramanian A, Tatsukawa R (1992) Persistent organochlorine residues in foodstuffs from India and their implications on human dietary exposure. J Agric Food Chem 40:518–52410.1021/jf00015a032 ↗
70. Kang S, Wang G, Wang Z, Cai W (2019) Monodispersed zerovalent iron nanoparticles decorated carbon submicrospheres for enhanced removal of DDT from aqueous solutions. ChemistrySelect 4(41):12134–12142. https://doi.org/10.1002/slct.20190283710.1002/slct.201902837 ↗
71. Khatri N, Tyagi S, Rawtani D (2016) Removal of basic dyes auramine yellow and auramine O by halloysite nanotubes. Int J Environ Waste Manage 17(1):44. https://doi.org/10.1504/ijewm.2016.07642710.1504/ijewm.2016.076427 ↗
72. Kellogg RL, Nehring R, Grube A, Goss DW, and Plotkin S (2000) Environmental indicators of pesticide leaching and runoff from farm fields Archived June 18, 2002, at the Wayback Machine. United States Department of Agriculture Natural Resources Conservation Service. Retrieved on 2007–10–03
73. Kgoetlana CM, Malinga SP, Dlamini LN (2020) Photocatalytic degradation of chlorpyrifos with Mn-WO3/SnS2 heterostructure. Catalysts 10(6):699. https://doi.org/10.3390/catal1006069910.3390/catal10060699 ↗
74. Khoiriah K, Safni S, Syukri S, Gunlazuardi J (2020) The operational parameters effect on photocatalytic degradation of diazinon using carbon and nitrogen modified TiO2. Rasayan J Chem 13(3):1919–1925. https://doi.org/10.31788/RJC.2020.133574310.31788/RJC.2020.1335743 ↗
75. Koushik D, Sen Gupta S, Maliyekkal SM, Pradeep T (2016) Rapid dehalogenation of pesticides and organics at the interface of reduced graphene oxide-silver nanocomposite. J Hazard Materials 308:192–198. https://doi.org/10.1016/j.jhazmat.2016.01.00410.1016/j.jhazmat.2016.01.004 ↗
76. Kurakalva RM (2016) In situ remediation of aldrin via activated persulfate oxidation. Geo-Chicago. https://doi.org/10.1061/9780784480168.03110.1061/9780784480168.031 ↗
77. Kusvuran E, Erbatur O (2004) Degradation of aldrin in adsorbed system using advanced oxidation processes: comparison of the treatment methods. J Hazard Mater 106B:115–12510.1016/j.jhazmat.2003.10.004 ↗
78. Li W, Li Y, Zhang D, Lan Y, Guo J (2020) CuO-Co3O4@CeO2as a heterogeneous catalyst for efficient degradation of 2,4-dichlorophenoxyacetic acid by peroxymonosulfate. J Hazard Mater 381:12120910.1016/j.jhazmat.2019.121209 ↗
79. Li FB, Li XM, Zhou SG, Zhuang L, Cao F, Huang DY, Xu W, Liu TX, C.H, (2010) FengEnhanced reductive dechlorination of DDT in an anaerobic system of dissimilatory iron-reducing bacteria and iron oxide Environ. Pollut 158:1733–174010.1016/j.envpol.2009.11.020 ↗
80. Lia Z, Wang Y, Ni Y, Kokot S (2014) Unmodified silver nanoparticles for rapid analysis of the organophosphorus pesticide, dipterex, often found in different waters. Sens Actuator B 193:205–21110.1016/j.snb.2013.11.096 ↗
81. Lin C, Lin KS (2007) Photocatalytic oxidation of toxic organohalides with TiO2/UV: the effects of humic substances and organic mixtures. Chemosphere 66:1872–187710.1016/j.chemosphere.2006.08.027 ↗
82. "Listing of POPs in the Stockholm convention" (n.d.) Stockholm Convention
83. Lorenz, Eric S (2009) Potential health effects of pesticides (PDF). Ag communications and marketing: 1–8. Archived from the original (PDF) on 2013–08–11. Retrieved February 2014
84. Longnecker PM, Rogan WJ, Lucier G (1997) The human health effects of DDT (dichlorodiphenyltrichloroethane) and PCBs (polychlorinated biphenyls) and an overview of organochlorines in public health. Annu Rev Public Health 18:211–24410.1146/annurev.publhealth.18.1.211 ↗
85. Lopez-Ayala S, Rincon ME, Quiroz-Alfaro MA, Bandala ER, MendezRojas MA, Castaño VM (2015) Nanocrystalline titania doped by metal precursors in the photocatalytic degradation of 2,4-D sodium salt. J Photochem Photobiol A: Chem 311:166–17510.1016/j.jphotochem.2015.06.019 ↗
86. Macholz RM, Kujwa M (1985) Recent state of lindane metabolism (Part III). Residue Rev 94:119–141
87. Majhi D, Das K, Mishra A, Dhiman R, Mishra BG (2020) One pot synthesis of CdS/BiOBr/Bi2O2CO3: a novel ternary double z-scheme heterostructure photocatalyst for efficient degradation of atrazine. Appl Catal B: Environ 260:11822210.1016/j.apcatb.2019.118222 ↗
88. Manga Raju I, Siva Rao T, Divya Lakshmi KV, Ravi Chandra M, Swathi Padmaja J, Divya G (2019) Poly 3-Thenoic acid sensitized, copper doped anatase/brookite TiO2 nanohybrids for enhanced photocatalytic degradation of an organophosphorus pesticide. J Environ Chem Eng 7:103211. https://doi.org/10.1016/j.jece.2019.10321110.1016/j.jece.2019.103211 ↗
89. Mathur SC (1999) Future of Indian pesticides industry in next millennium. Pestic Inf 24:9–23
90. Malato S, Blanco J, Fernandez-Alba AR, Agüera A (2000) Solar photocatalytic mineralization of commercial pesticides: acrinathrin. Chemosphere 40:403–40910.1016/S0045-6535(99)00267-2 ↗
91. Maya-Treviño ML, Guzmán-Mar JL, Hinojosa-Reyes L, Ramos-Delgado NA, Maldonado MI, Hernández-Ramírez A (2014) Ceram Int 40(6):8701–870810.1016/j.ceramint.2014.01.088 ↗
92. McMurray TA, Dunlop PSM, Byrne JA (2006) The photocatalytic degradation of atrazine on nanoparticulate TiO2 films. J Photochem Photobiol A Chem 182:43–5110.1016/j.jphotochem.2006.01.010 ↗
93. Merci S, Saljooqi A, Shamspur T, Mostafavi A (2020) Investigation of photocatalytic chlorpyrifos degradation by a new silica mesoporous material immobilized by WS2 and Fe3O4 nanoparticles: application of response surface methodology. Appl Org Chem (2020):e5343. https://doi.org/10.1002/aoc.534310.1002/aoc.5343 ↗
94. Mn C (2001) Nanoparticles. Proteins and nucleic acid biotechnology meets material science. Angew Chem Int Ed Eng 40:4128–415810.1002/1521-3773(20011119)40:22<4128::AID-ANIE4128>3.0.CO;2-S ↗
95. Mirmasoomi SR, Ghazi MM, Galedari M (2016) Sep Purif Technol 175:18–21
96. Mkhalid IA (2016) Ceram Int 42:15975–1598010.1016/j.ceramint.2016.07.100 ↗
97. Mew EJ, Padmanathan P, Konradsen F et al (2017) The global burden of fatal self-poisoning with pesticides 2006–15: systematic review. J Affect Disord 219:93–10410.1016/j.jad.2017.05.002 ↗
98. Moon HB, Kim HS, Choi M, Choi HG (2009) Human health risk of polychlorinated biphenyls and organochlorine pesticides resulting from seafood consumption in South Korea, 2005–2007. Food Chem Toxicol 47:1819–182510.1016/j.fct.2009.04.028 ↗
99. Moon HB, Lee DH, Lee YS, Choi M, Choi HG, Kannan K (2012) Polybrominated diphenyl ethers, polychlorinated biphenyls, and organochlorine pesticides in adipose tissues of Korean women. Arch Environ Contam Toxicol 62:176–18410.1007/s00244-011-9679-6 ↗
100. Mitchell HW (1965) Pesticides and other agricultural chemicals as a public health problem. Am J Public Health Nations Health 55(Suppl 7):10–1510.2105/AJPH.55.Suppl_7.10 ↗