journal article·2017-10

High-efficiency preparation of oil-dispersible MoS2 nanosheets with superior anti-wear property in ultralow concentration

Hongxing Wu, Blake Johnson, Liping Wang, Guangneng Dong, Shuncheng Yang, Junfeng Zhang

Journal of Nanoparticle Research· Volume 19· Issue 10
Publisher page

Abstract

Molybdenum disulfide (MoS2) nanosheets are a promising lubricant additive for enhanced engine efficiency in cars. However, high-cost production methods and poor dispersion have limited their application in industry. In this study, the ball milling process is demonstrated as a low-cost and high-efficient method for fabrication of oil-dispersible MoS2 nanosheet, and the ball milling parameters are optimized. Moreover, the lubrication effectiveness of ball-milled MoS2 nanosheet was also evaluated. Results indicated that well-dispersed MoS2 nanosheets with a size of 250 nm can be manufactured with optimized surfactants of zinc dialkyldithiphosphates (ZDDP) and polyisobutylene succinimide (PIBS) after being ball milled for 36 h. Tribological results revealed that a friction coefficient of white oil with 0.25% MoS2 nanosheets reached 0.075, much lower than that of lubricant without nanosheets (0.16). The wear scar radius of 0.015% MoS2 nanosheets was similar with that of Hertz contact, and the wear scar radius reduction reached 20% compared with that of 1% ZDDP. In addition, EDS and XPS results indicated the formation of a MoS2 and FeS tribofilm on the wear surface.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Lubricants and Their Additives · Tribology and Wear Analysis · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Ali MKA, Xianjun H, Elagouz A, Essa F, Abdelkareem MA (2016) Minimizing of the boundary friction coefficient in automotive engines using Al2O3 and TiO2 nanoparticles. J Nanopart Res 18(12):37710.1007/s11051-016-3679-4 ↗
2. Berman D, Erdemir A, Sumant AV (2013) Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54:454–45910.1016/j.carbon.2012.11.061 ↗
3. Çelik O, Ay N, Göncü Y (2013) Effect of nano hexagonal boron nitride lubricant additives on the friction and wear properties of AISI 4140 steel. Part Sci Technol 31(5):501–50610.1080/02726351.2013.779336 ↗
4. Chen Z, Liu X, Liu Y, Gunsel S, Luo J (2015) Ultrathin MoS2 nanosheets with superior extreme pressure property as boundary lubricants. Sci Rep 5:1286910.1038/srep12869 ↗
5. Chiñas-Castillo F, Spikes H (2003) Mechanism of action of colloidal solid dispersions. J Tribol 125(3):552–55710.1115/1.1537752 ↗
6. Gao C, Wang Y, Hu D, Pan Z, Xiang L (2013) Tribological properties of magnetite nanoparticles with various morphologies as lubricating additives. J Nanopart Res 15(3):150210.1007/s11051-013-1502-z ↗
7. Gulzar M, Masjuki H, Kalam M, Varman M, Zulkifli N, Mufti R, Zahid R (2016) Tribological performance of nanoparticles as lubricating oil additives. J Nanopart Res 18(8):22310.1007/s11051-016-3537-4 ↗
8. Holmberg K, Andersson P, Erdemir A (2012) Global energy consumption due to friction in passenger cars. Tribol Int 47:221–23410.1016/j.triboint.2011.11.022 ↗
9. Holmberg K, Andersson P, Nylund N-O, Mäkelä K, Erdemir A (2014) Global energy consumption due to friction in trucks and buses. Tribol Int 78:94–11410.1016/j.triboint.2014.05.004 ↗
10. Kogovšek J, Kalin M (2014) Various MoS2-, WS2-and C-based micro-and nanoparticles in boundary lubrication. Tribol Lett 53(3):585–59710.1007/s11249-014-0296-1 ↗
11. Li S, Bhushan B (2016) Lubrication performance and mechanisms of Mg/Al-, Zn/Al-, and Zn/Mg/Al-layered double hydroxide nanoparticles as lubricant additives. Appl Surf Sci 378:308–31910.1016/j.apsusc.2016.03.220 ↗
12. Li W, Zheng S, Cao B, Ma S (2011) Friction and wear properties of ZrO2/SiO2 composite nanoparticles. J Nanopart Res 13(5):2129–213710.1007/s11051-010-9970-x ↗
13. Li LH, Glushenkov AM, Hait SK, Hodgson P, Chen Y (2014) High-efficient production of boron nitride nanosheets via an optimized ball milling process for lubrication in oil. Sci Rep 4:728810.1038/srep07288 ↗
14. Nallasamy P, Saravanakumar N, Nagendran S, Suriya E, Yashwant D (2014) Tribological investigations on MoS2-based nanolubricant for machine tool slideways. Proc Inst Mech Eng Part J: J Eng Tribol 1350650114556394
15. Rabaso P, Ville F, Dassenoy F, Diaby M, Afanasiev P, Cavoret J, . . . Le Mogne T (2014a) Boundary lubrication: Influence of the size and structure of inorganic fullerene-like MoS 2 nanoparticles on friction and wear reduction. Wear 320: 161–17810.1016/j.wear.2014.09.001 ↗
16. Rabaso P, Dassenoy F, Ville F, Diaby M, Vacher B, Le Mogne T, . . . Cavoret J (2014b) An investigation on the reduced ability of IF-MoS2 nanoparticles to reduce friction and wear in the presence of dispersants. Tribol Lett 55(3): 503–51610.1007/s11249-014-0381-5 ↗
17. Rapoport L, Fleischer N, Tenne R (2005) Applications of WS 2 (MoS 2) inorganic nanotubes and fullerene-like nanoparticles for solid lubrication and for structural nanocomposites. J Mater Chem 15(18):1782–178810.1039/b417488g ↗
18. Rudenko P, Bandyopadhyay A (2013) Talc as friction reducing additive to lubricating oil. Appl Surf Sci 276:383–38910.1016/j.apsusc.2013.03.102 ↗
19. Sgroi M, Gili F, Mangherini D, Lahouij I, Dassenoy F, Garcia I, . . . Kraft G (2015) Friction reduction benefits in valve-train system using IF-MoS2 added engine oil. Tribol Trans 58(2): 207–21410.1080/10402004.2014.960540 ↗
20. Shi Y, Wang Y, Wong J I, Tan A Y S, Hsu C-L, Li L-J, . . . Yang H Y (2013a) Self-assembly of hierarchical MoSx/CNT nanocomposites (2<×<3): towards high performance anode materials for lithium ion batteries. Sci Rep 310.1038/srep02169 ↗
21. Shi Y, Huang J-K, Jin L, Hsu Y-T, Yu SF, Li L-J, Yang HY (2013b) Selective decoration of Au nanoparticles on monolayer MoS2 single crystals. Sci Rep 3:183910.1038/srep01839 ↗
22. Tannous J, de Bouchet BM, Le-Mogne T, Charles P, Martin J (2007) Contribution of gas phase lubrication in understanding tribochemistry of organosulphur compounds. Tribol Mater Surf Interf 1(2):98–10410.1179/175158407X231321 ↗
23. Tannous J, Dassenoy F, Lahouij I, Le Mogne T, Vacher B, Bruhács A, Tremel W (2011) Understanding the tribochemical mechanisms of IF-MoS2 nanoparticles under boundary lubrication. Tribol Lett 41(1):55–6410.1007/s11249-010-9678-1 ↗
24. Verma A, Jiang W, Abu Safe HH, Brown WD, Malshe AP (2008) Tribological behavior of deagglomerated active inorganic nanoparticles for advanced lubrication. Tribol Trans 51(5):673–67810.1080/10402000801947691 ↗
25. Wan Q, Jin Y, Sun P, Ding Y (2014) Rheological and tribological behaviour of lubricating oils containing platelet MoS2 nanoparticles. J Nanopart Res 16(5):238610.1007/s11051-014-2386-2 ↗
26. Wu H, Ho J K, Dong G, Zhang D (2014) Friction reduction of pre-phosphating nanofilm on bearing steel by tricresyl phosphate pretreatment in boundary lubrication. Proc Inst Mech Eng Part J: J Eng Tribol 1350650114544200
27. Wu H, Qin L, Zeng Q, Dong G (2015) Understanding the physical adsorption action mechanism of MoS2 nanoparticles in boundary lubrication with different Polyisobutyleneamine Succinimide (PIBS) concentrations. Tribol Lett 60(2):1–12
28. Wu H, Wang L, Dong G, Yang S, Zhang J, Zhou B, Tang Z (2016) Lubrication effectiveness investigation on the friendly capped MoS2 nanoparticles. Lubrication Science10.1002/ls.1360 ↗
29. Zhang ZJ, Zhang J, Xue QJ (1994) Synthesis and characterization of a molybdenum disulfide nanocluster. J Phys Chem 98(49):12973–1297710.1021/j100100a027 ↗
30. Zhang W, Demydov D, Jahan MP, Mistry K, Erdemir A, Malshe AP (2012) Fundamental understanding of the tribological and thermal behavior of Ag–MoS 2 nanoparticle-based multi-component lubricating system. Wear 288:9–1610.1016/j.wear.2012.03.003 ↗
31. Zhang W L, Cao Y, Tian P, Guo F, Tian Y, Zheng W, . . . Liu J (2016) Soluble, exfoliated two-dimensional nanosheets as excellent aqueous lubricants. ACS Applied Materials & Interfaces10.1021/acsami.6b09752 ↗
32. Zhao Y, Zhang Z, Dang H (2004) Fabrication and tribological properties of Pb nanoparticles. J Nanopart Res 6(1):47–5110.1023/B:NANO.0000023223.79545.af ↗
33. Zhou J, Yang J, Zhang Z, Liu W, Xue Q (1999) Study on the structure and tribological properties of surface-modified Cu nanoparticles. Mater Res Bull 34(9):1361–136710.1016/S0025-5408(99)00150-6 ↗