journal article·2011-08

Titanium dioxide doped with transition metals (M x Ti1−x O2, M: Ni, Co): synthesis and characterization for its potential application as photoanode

K. Esquivel, Ma. G. García J., F. J. Rodríguez, M. Vega González, L. Escobar-Alarcón, Luis Ortiz-Frade, Luis A. Godínez

Journal of Nanoparticle Research· Volume 13· Issue 8
Publisher page

Abstract

This study presents the synthesis of TiO2 doped with different amounts of Co and Ni, starting from a simple metallic titanium powder. A successful electrophoretic deposition of these materials on ITO electrodes was achieved for its potential application as photoanodes. EDX, diffuse reflectance UV–Vis spectroscopy, and XRD measurements gave information on the chemical composition of the material and the location of the Ni or Co within the crystal structure of TiO2. Raman spectroscopy suggests that for a higher content of doping metal above a defined percentage, the formation of metal oxide is promoted. A preliminary study of photoelectrocatalytic orange dye degradation shows higher color removal efficiency as compared to the commercial TiO2 material.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Ananpattarachai J, Kajitvichyanukul P, Seraphin S (2009) Visible light absorption ability and photocatalytic oxidation activity of various interstitial N-doped TiO2 prepared from different nitrogen dopants. J Hazard Mater doi: 10.1016/j.jhazmat.2009.02.03610.1016/j.jhazmat.2009.02.036 ↗
2. Baea S, Shimb E, Yoonc J, Joo H (2008) Enzymatic hydrogen production by light-sensitized anodized tubular TiO2 photoanode. Solar Energy Mater Solar Cells 92:402–40910.1016/j.solmat.2007.09.019 ↗
3. Barakat MA, Schaeffer H, Hayes G, Ismat SS (2004) Photocatalytic degradation of 2-chlorophenol by Co-doped TiO2 nanoparticles. Appl Catal B 57:23–3010.1016/j.apcatb.2004.10.001 ↗
4. Barakat MA, Hayes G, Ismat SS (2005) Effect of cobalt doping on the phase transformation of TiO2 nanoparticles. J Nanosci Nanotechnol 10:1–7
5. Bengtsson N, Castellote M, Lopez-Muñoz MJ, Cerro L (2009) Preparation of Co-doped TiO2 for photocatalytic degradation of NO x in air under visible light. J Adv Oxid Technol 12(1):55–64
6. Castro AL, Nunes MR, Carvalho MD, Ferreira LP, Jumas JC, Costa FM, Florencio MH (2009) Doped titanium dioxide nanocrystalline powders with high photocatalytic activity. J Solid State Chem. doi: 10.1016/j.jssc.2009.04.02010.1016/j.jssc.2009.04.020 ↗
7. Chen J, Yao M, Wang X (2008) Investigation of transition metal ion doping behaviours on TiO2 nanoparticles. J Nanopart Res 10:163–17110.1007/s11051-007-9237-3 ↗
8. Chen L-C, Ho Y-C, Guo W-S, Huang C-M, Pan T-C (2009) Enhanced visible light-induced photoelectrocatalytic degradation of phenol by carbon nanotube-doped TiO2 electrodes. Electrochim Acta 54:3884–389110.1016/j.electacta.2009.02.001 ↗
9. Chu D, Yuan X, Qin G, Xu M, Zheng P, Lu J, Zha L (2008) Efficient carbon-doped nanostructured TiO2 (anatase) film for photoelectrochemical solar cells. J Nanopart Res 10:357–36310.1007/s11051-007-9241-7 ↗
10. Djerdj I, Tonejc AM, Tonejc A (2006) Structural refinement of nanocrystalline TiO2 samples. Electron Crystallogr 497–50110.1007/1-4020-3920-4_32 ↗
11. Elsellami L, Vocanson F, Dappozze F, Puzenat E, Païsse O, Houas A, Guillard C (2010) Kinetic of adsorption and of photocatalytic degradation of phenylalanine effect of pH and light intensity. Appl Catal A 380:142–14810.1016/j.apcata.2010.03.054 ↗
12. Eshaghi A, Mozaffarinia R, Pakshir M, Eshaghi A (2011) Photocatalytic properties of TiO2 sol–gel modified nanocomposite films. Ceram Int 37:327–33110.1016/j.ceramint.2010.09.008 ↗
13. Esquivel K, Arriaga LG, Rodríguez FJ, Martínez L, Godínez LA (2009) Development of a TiO2 modified optical fiber electrode and its incorporation into a photoelectrochemical reactor for wastewater treatment. Water Res 43:3593–360310.1016/j.watres.2009.05.035 ↗
14. Facchin G, Carturan G, Campostrini R, Gialanella S, Lutterotti L, Armelao L, Marcí G, Palmisano L, Sclafani A (2000) Sol-gel synthesis and characterisation of TiO2-anatase powders containing nanometric platinum particles employed as catalysts for 4-nitrophenol photodegradation. J Sol-Gel Sci Technol 18:29–5910.1023/A:1008737612606 ↗
15. Garzella C, Bontempi E, Depero LE, Vomiero A, Della Mea G, Sberveglieri G (2003) Novel selective ethanol sensors: W/TiO2 thin films by sol–gel spin-coating. Sens Actuators B 93:495–50210.1016/S0925-4005(03)00192-8 ↗
16. Glaspell G, Manivannan A (2005) Sol–gel synthesis and magnetic studies of titanium dioxide doped with 10% M (M = Fe, Mn and Ni). J Clust Sci 16(4):501–51310.1007/s10876-005-0023-z ↗
17. Gonçalves G, Lenzi MK, Santos OAA, Jorge LMM (2006) Preparation and characterization of nickel based catalysts on silica, alumina and titania obtained by sol–gel method. J Non-Cryst Solids 352:3697–370410.1016/j.jnoncrysol.2006.02.120 ↗
18. Hadjiev VG, Iliev MN, Vergilov IV (1988) The Raman spectra of Co3O4. J Phys C 21:L199–L20110.1088/0022-3719/21/7/007 ↗
19. Han F, Subba Rao KV, Srinivasan M, Dharmarajan R, Naidu R (2009) Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: a review. Appl Catal A 359:25–4010.1016/j.apcata.2009.02.043 ↗
20. Janczarek M, Kisch H, Hupka J (2007) Photoelectrochemical characterization of nitrogen-modified TiO2. Physicochem Probl Miner Process 41:159–166
21. Khaleel A, Al-Nayli A (2008) Supported and mixed oxide catalysts based on iron and titanium for the oxidative decomposition of chlorobenzene. Appl Catal B 80:176–18410.1016/j.apcatb.2007.11.027 ↗
22. Khan R, Kim T-J (2009) Preparation and application of visible-light-responsive Ni-doped and SnO2-coupled TiO2 nanocomposite photocatalysts. J Hazard Mater 163:1179–118410.1016/j.jhazmat.2008.07.078 ↗
23. Kim HR, Choi KY, Shul Y-G (2007) Preparation of TiO2/SiO2 hollow spheres and their activity in methylene blue photodecomposition. Korean J Chem Eng 24(4):596–59910.1007/s11814-007-0009-7 ↗
24. Kim DH, Choi D-K, Kim S-J, Lee KS (2008) The effect of phase type on photocatalytic activity in transition metal doped TiO2 nanoparticles. Catal Commun 9:654–65710.1016/j.catcom.2007.07.017 ↗
25. Kisand V, Joost U, Reedo V, Pärna R, Tätte T, Shulga J, Saar A, Matisen L, Kikas A, Kink I (2010) Influence of the heating temperature on the properties of nickel doped TiO2 films prepared by sol–gel method. Appl Surf Sci 256:4538–454210.1016/j.apsusc.2010.02.043 ↗
26. Kudo A, Niishiro R, Iwase A, Kato H (2007) Effects of doping of metal cations on morphology, activity, and visible light response of photocatalysts. Chem Phys 339:104–11010.1016/j.chemphys.2007.07.024 ↗
27. Li X, Yue P-L, Kutal C (2003) Synthesis and photocatalytic oxidation properties of iron doped titanium dioxide nanosemiconductor particles. New J Chem 27:1264–126910.1039/b301998e ↗
28. Li W, Frenkel AI, Woicik JC, Ni C, Ismat SS (2005) Dopant location identification in Nd3+-doped TiO2 nanoparticles. Phys Rev B 72:155315-1–155315-6
29. Li J, Liu S, He Y, Wang J (2008) Adsorption and degradation of the cationic dyes over Co doped amorphous mesoporous titania–silica catalyst under UV and visible light irradiation. Microporous Mesoporous Mater 115:416–42510.1016/j.micromeso.2008.02.022 ↗
30. Manriquez J, Godínez LA (2007) Tuning the structural, electrical and optical properties of Ti(III)-doped nanocrystalline TiO2 films by electrophoretic deposition time. Thin Solid Films 515:3402–341310.1016/j.tsf.2006.09.055 ↗
31. Martín C, Solana G, Malet P, Rives V (2003) Nb2O5-supported WO3: a comparative study with WO3/Al2O3. Catal Today 78:365–37610.1016/S0920-5861(02)00301-2 ↗
32. Muruganadham M, Swaminathan M (2006) Nano-Ag particles doped TiO2 for efficient photodegradation of direct azo dyes. J Mol Catal A 258:124–13210.1016/j.molcata.2006.05.013 ↗
33. Pacheco F, González M, Medina A, Velumani S, Ascencio JA (2004) Structural analysis of cobalt titanate nanoparticles obtained by sol–gel process. Appl Phys A 78:531–53610.1007/s00339-003-2454-4 ↗
34. Peralta-Hernández JM, Meas-Vong Y, Rodríguez FJ, Chapman TW, Maldonado MI, Godínez LA (2008) Comparison of hydrogen peroxide-based processes for treating dye-containing wastewater: decolorization and destruction of Orange II azo dye in dilute water. Dyes Pigments 76:656–66210.1016/j.dyepig.2007.01.001 ↗
35. Piera E, Tejedor-Tejedor MI, Zorn ME, Anderson MA (2003) Relationship concerning the nature and concentration of Fe(III) species on the surface of TiO2 particles and photocatalytic activity of the catalyst. Appl Catal B 46:671–68510.1016/S0926-3373(03)00288-1 ↗
36. Raman Spectra Database of Minerals and Inorganic Materials (RASMIN) at RIO-DB of AIST ( http://www.aist.go.jp/RIODB/rasmin/E_index.htm )
37. Rauf MA, Ashraf SS (2009) Review: fundamental principles and application of heterogeneous photocatalytic degradation of dyes in solution. Chem Eng J 151:10–1810.1016/j.cej.2009.02.026 ↗
38. Rietveld HM (1969) A profile refinement method for nuclear and magnetic structures. J Appl Crystallogr 2:65–7110.1107/S0021889869006558 ↗
39. Selculi H, Zaltner W, Sene JJ, Bekbolet M, Anderson MA (2004) Photocatalytic and photoelectrocatalytic performance of 1% Pt doped TiO2 for the detoxification of water. J Appl Electrochem 34:653–65810.1023/B:JACH.0000021931.36151.54 ↗
40. Shieh Y-N, Chang Y-Y (2010) Influence of cobalt ion implantation on optical properties of titanium dioxide thin films. Thin Solid Films 518:7464–746710.1016/j.tsf.2010.05.025 ↗
41. Sobana SJ, Qiao L, Sun S, Wang G (2008) Photocatalytic degradation of Orange G on nitrogen-doped TiO2 catalysts under visible light and sunlight irradiation. J Hazard Mater 155:312–31910.1016/j.jhazmat.2007.11.062 ↗
42. Suriye K, Praserthdam P, Jongsomjit B (2007) Effect of surface sites of TiO2 support on the formation of cobalt-support compound in Co/TiO2 catalysts. Catal Commun 8:1772–178010.1016/j.catcom.2007.01.011 ↗
43. Tian B, Li C, Gu F, Jiang H (2009) Synergetic effects of nitrogen doping and Au loading on enhancing the visible-light photocatalytic activity of nano-TiO2. Catal Commun 10:925–92910.1016/j.catcom.2008.12.029 ↗
44. Tiana H, Maa J, Li K, Li J (2008) Photocatalytic degradation of methyl orange with W-doped TiO2 synthesized by a hydrothermal method. Mater Chem Phys 112:47–5110.1016/j.matchemphys.2008.05.005 ↗
45. Torres-Martínez LM, Juárez-Ramírez I, Del Ángel-Sánchez K, Garza-Tovar L, Cruz-López A, Del Ángel G (2008) Rietveld refinement of sol–gel Na2Ti6O13 and its photocatalytic performance on the degradation of methylene blue. J Sol-Gel Sci Technol 47:158–16410.1007/s10971-008-1790-4 ↗
46. Tryba B (2008) Immobilization of TiO2 and Fe–C–TiO2 photocatalysts on the cotton material for application in a flow photocatalytic reactor for decomposition of phenol in water. J Hazard Mater 151:623–62710.1016/j.jhazmat.2007.06.034 ↗
47. Xu W-X, Zhu S, Fu X-C, Chen Q (1999) The structure of TiO x thin film studied by Raman spectroscopy and XRD. Appl Surf Sci 148:253–26210.1016/S0169-4332(98)00589-3 ↗
48. Yang Q, Choi H, Al-Abed SR, Dionysiou DD (2009) Iron–cobalt mixed oxide nanocatalysts: heterogeneous peroxymonosulfate activation, cobalt leaching, and ferromagnetic properties for environmental applications. Appl Catal B 88:462–46910.1016/j.apcatb.2008.10.013 ↗
49. Yanga H, Ana T, Li G, Song W, Cooper WJ, Luo H, Guo X (2010) Photocatalytic degradation kinetics and mechanism of environmental pharmaceuticals in aqueous suspension of TiO2: a case of β blockers. J Hazard Mater 179:834–83910.1016/j.jhazmat.2010.03.079 ↗
50. Zhao H, Jiang D, Zhang S, Wen W (2007) Photoelectrocatalytic oxidation of organic compounds at nanoporous TiO2 electrodes in a thin-layer photoelectrochemical cell. J Catal 250:102–10910.1016/j.jcat.2007.05.013 ↗