journal article·2020-01

Nitrogen dozen carbon quantum dots as one dual function sensing platform for electrochemical and fluorescent detecting ascorbic acid

Xin Zhou, Qing Qu, Lin Wang, Lei Li, Shunling Li, Ke Xia

Journal of Nanoparticle Research· Volume 22· Issue 1
Publisher page

Abstract

A novel amine-modified carbon quantum dots (NH2-CQDs), which can act as a dual-detection probe for the ascorbic acid (AA) response, was synthesized. The product was obtained via facile and green hydrothermal carbonization of L-histidine. The high nitrogen to carbon ratio of L-histidine warrants a high nitrogen content of these CQDs, and thus to have more free electron pairs. This results in good electron transport capability. The NH2-CQDs with an average diameter of 3.67 ± 0.78 nm display blue fluorescence, with excitation/emission maxima at 340/420 nm, and a quantum yield of 15.9%. The fluorescence can be quenched by AA. Moreover, the NH2-CQDs can selectively detect AA with electrochemical detection. On the basis of the electrochemical and fluorescent properties of the NH2-CQDs, the electrochemistry method and fluorescence analysis for the detection of AA with a detection limit of 2.7 μM and 57 nM are developed. This finding may provide a dual-detection platform, which can be used as a potential candidate for more selective to detect AA in pharmaceuticals, clinics, and food industries.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon and Quantum Dots Applications · Electrochemical sensors and biosensors · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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