Nanoscale zinc-based metal-organic framework with high capacity for lithium-ion batteries
Source abstract
Abstract
Layered zinc-based metal-organic framework ([Zn(4,4′-bpy)(tfbdc)(H2O)2], Zn-LMOF) nanosheets were synthesized by a facile hydrothermal method (4,4′-bpy = 4,4′-bipyridine, H2tfbdc = tetrafluoroterephthalic acid). The materials were characterized by IR spectrum, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, transmission electron microscope (TEM), scanning electron microscope (SEM), and the Brunauer–Emmett–Teller (BET) surface. When the Zn-LMOF nanosheets with the thickness of about 24 ± 8 nm were used as an anode material of lithium-ion batteries, not only the Zn-LMOF electrode shows a high reversible capacity, retaining 623 mAh g−1 after 100 cycles at a current density of 50 mA g−1 but also exhibits an excellent cyclic stability and a higher rate performance.
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Research context
OpenAlex topics: Advancements in Battery Materials · Metal-Organic Frameworks: Synthesis and Applications · Extraction and Separation Processes
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