New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater
Source abstract
Abstract
The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m2/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Adsorption and biosorption for pollutant removal · Analytical chemistry methods development · Environmental remediation with nanomaterials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
Show source-provided references
1. Bangs LB (1984) Uniform latex particles. Seradyn Inc, Indianapolis, IN
2. Bayramoglu G, Arica MY (2011) Synthesis of Cr(VI)-imprinted poly(4-vinyl pyridine-co-hydroxyethyl methacrylate) particles: its adsorption propensity to Cr(VI). J Hazard Mater 187:213–22110.1016/j.jhazmat.2011.01.022 ↗
3. Biju VM, Gladis JM, Rao TP (2003) Ion imprinted polymer particles: synthesis, characterization and dysprosium ion uptake properties suitable for analytical applications. Anal Chim Acta 478:43–5110.1016/S0003-2670(02)01416-2 ↗
4. Birlik E, Ersöz A, Denizli A, Say R (2006) Preconcentration of copper using double-imprinted polymer via solid extraction. Anal Chim Acta 565:145–15110.1016/j.aca.2006.02.051 ↗
5. Birlik E, Ersöz A, Açıkkalp E, Denizli A, Say R (2007) Cr(III)-imprinted polymeric beads: sorption and preconcentration studies. J Hazard Mater 140:110–11610.1016/j.jhazmat.2006.06.141 ↗
6. Büyüktiryaki S, Say R, Denizli A, Ersöz A (2007) Mimicking receptor for methylmercury preconcentration based on ion-imprinting. Talanta 71:699–70510.1016/j.talanta.2006.05.026 ↗
7. Dai S, Burleigh MC, Shin Y, Morrow CC, Barnes CE, Xue Z (1999) Imprint coating: a novel synthesis of selective functionalized ordered mesoporous sorbents. Angew Chem Int Edit 38:1235–123910.1002/(SICI)1521-3773(19990503)38:9<1235::AID-ANIE1235>3.0.CO;2-X ↗
8. Dotto GL, Cadaval TRS, Pinto LAA (2012) Preparation of bionanoparticles derived from Spirulina platensis and its application for Cr(VI) removal from aqueous solutions. J Ind Eng Chem 18:1925–193010.1016/j.jiec.2012.05.005 ↗
9. Ferreira SLC, de Jesus DS, Cassella RJ, Costa ACS, de Carvalho MS, Santelli RE (1999) An on-line solid phase extraction system using polyurethane foam for the spectrophotometric determination of nickel in silicates and alloys. Anal Chim Acta 378:287–29210.1016/S0003-2670(98)00596-0 ↗
10. Gupta VK, Srivastava SK, Mohan D, Sharma S (1997) Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions. Water Res 17:517–522
11. Gupta VK, Shrivastava AK, Jain N (2001) Biosorption of chromium(VI) from aqueous solutions by green algae Spirogyra species. Water Res 35:4079–408510.1016/S0043-1354(01)00138-5 ↗
12. Gupta VK, Jain N, Varshney S (2007a) Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents. J Colloid Interf Sci 312:292–29610.1016/j.jcis.2007.03.054 ↗
13. Gupta VK, Ali I, Saini VK (2007b) Defluoridation of wastewaters using waste carbon slurry. Water Res 41:3307–331610.1016/j.watres.2007.04.029 ↗
14. Gupta VK, Mittal A, Malviya A, Mittal J (2009) Adsorption of carmoisine A from wastewater using waste materials-Bottom ash and deoiled soya. J Colloid Interf Sci 335:24–3310.1016/j.jcis.2009.03.056 ↗
15. Gupta VK, Rastogi A, Nayak A (2010) Biosorption of nickel onto treated alga (Oedogonium hatei): application of isotherm and kinetic models. J Colloid Interf Sci 342:533–53910.1016/j.jcis.2009.10.074 ↗
16. Gupta VK, Agarval S, Saleh TA (2011a) Chromium removal by combining the magnetic properties of iron oxide with adsorption properties of carbon nanotubes. Water Res 45:2207–221210.1016/j.watres.2011.01.012 ↗
17. Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A (2011b) A comparative investigation on adsorption performances of mesoporous activated carbon prepared form waste rubber tire and activated carbon for a hazardous azo dye-Acid Blue 113. J Hazard Mater 186:891–90110.1016/j.jhazmat.2010.11.091 ↗
18. Hasan S, Krishnaiah A, Ghosh TK, Viswanath DS, Boddu VM, Smith ED (2003) Adsorption of chromium(VI) on chitosan-coated perlite. Sep Sci Technol 38:3775–379310.1081/SS-120024229 ↗
19. Karabörk M, Ersöz A, Denizli A, Say R (2008) Polymer-clay nanocomposite iron traps based on intersurface ion-imprinting. Ind Eng Chem Res 47:2258–226410.1021/ie070885o ↗
20. Kaya IGB, Duranoglu D, Beker U, Senkal BF (2011) Development of polymeric and polymer-based hybrid adsorbents for chromium removal from aqueous solution, clean—soil. Air Water 39:980–98810.1002/clen.201000552 ↗
21. Khezami L, Capart R (2005) Removal of chromium(VI) from aqueous solution by activated carbons: kinetic and equilibrium studies. J Hazard Mater B123:223–23110.1016/j.jhazmat.2005.04.012 ↗
22. Kuchen W, Schram J (1988) Metal-ion selective exchange resins by matrix imprint with methacrylates. Angew Chem Int Edit 27:1695–169710.1002/anie.198816951 ↗
23. Kumar PA, Ray M, Chakraborty S (2007) Hexavalent chromium removal from wastewater using aniline formaldehyde condensate coated silica gel. J Hazard Mater 143:24–3210.1016/j.jhazmat.2006.08.067 ↗
24. Matheickal JT, Yu Q, Woodburn GM (1999) Biosorption of cadmium from aqueous solutions by prepared biomass of marine alga Durvillaea potatorum. Water Res 33:335–34210.1016/S0043-1354(98)00237-1 ↗
25. Mittal A, Gupta VK, Malviya A, Mittal J (2008) Process development for the batch and bulk removal and recovery of a hazardous, water-soluble azo dye (Metanil Yellow) by adsorption over waste materials (Bottom Ash and De-Oiled Soya) J. Hazard Mater 151:821–83210.1016/j.jhazmat.2007.06.059 ↗
26. Mittal A, Kaur D, Malviya A, Mittal J, Gupta VK (2009a) Adsorption studies on the removal of coloring agent phenol red from wastewater using waste materials as adsorbents. J Colloid Interf Sci 337:345–35410.1016/j.jcis.2009.05.016 ↗
27. Mittal A, Mittal J, Malviya A, Gupta VK (2009b) adsorptive removal of hazardous anionic dye “Congo red” from wastewater using waste materials and recovery by desorption. J Colloid Interf Sci 340:16–2610.1016/j.jcis.2009.08.019 ↗
28. Mittal A, Mittal J, Malviya A, Gupta VK (2010a) Removal and recovery of Chrysoidine Y from aqueous solutions by waste materials. J Colloid Interf Sci 344:497–50710.1016/j.jcis.2010.01.007 ↗
29. Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010b) Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. J Colloid Interf Sci 342:518–52710.1016/j.jcis.2009.10.046 ↗
30. Mittal A, Mittal J, Malviya A, Kaur D, Gupta VK (2010c) Adsorption of hazardous dye crystal violet from wastewater by waste materials. J Colloid Interf Sci 343:463–47310.1016/j.jcis.2009.11.060 ↗
31. Mohanty K, Jha M, Meikap BC, Biswas MN (2005) Removal of chromium(VI) from dilute aqueous solutions by activated carbon developed from Terminalia arjuna nuts activated with zinc chloride. Chem Eng Sci 60:3049–305910.1016/j.ces.2004.12.049 ↗
32. Perçin I, Karakoç V, Akgöl S, Aksöz E, Denizli A (2012) Poly(hydroxyethyl methacrylate) based magnetic nanoparticles for plasmid DN purification from Escherichia coli lysate. Mater Sci Eng C 32:1133–114010.1016/j.msec.2012.02.031 ↗
33. Rauf MA, Bukallah SB, Hamour FA, Nasir AS (2007) Adsorption of dyes from aqueous solutions onto sand and their kinetic behavior. Chem Eng J 137:238–24310.1016/j.cej.2007.04.025 ↗
34. Salih B, Say R, Denizli A, Genç Ö, Pişkin E (1998) Determination of inorganic and organic mercury compounds by capillary gas chromatography coupled with atomic absorption spectrometry after preconcentration on dithizoneanchored poly(ethylene glycol dimethacrylate–hydroxyethylmethacrylate) microbeads. Anal Chim Acta 371:177–18510.1016/S0003-2670(98)00354-7 ↗
35. Saxena R, Singh AK (1997) Pyrocatechol violet immobilized Amberlite XAD-2: synthesis and metal-ion uptake properties suitable for analytical applications. Anal Chim Acta 340:285–29010.1016/S0003-2670(96)00515-6 ↗
36. Say R, Şatıroğlu N, Pişkin E, Bektaş S, Genç Ö (1998) Dithiocarbamateincoporated monodisperse polystyrene microspheres as specific sorbents: adsorption of organomercury species. Anal Lett 31:511–52810.1080/00032719808001855 ↗
37. Say R, Garipcan B, Emir S, Patır S, Denizli A (2002a) Preparation of poly(hydroxyethyl methacrylate-co-methacrylamidohistidine) beads and its design as a affinity adsorbent for Cu(II) removal from aqueous solutions. Colloid Surf A 196:199–20710.1016/S0927-7757(01)00891-3 ↗
38. Say R, Tuncel A, Denizli A (2002b) Adsorption of Ni2+ from aqueous solutions by novel polyethyleneimine-attached poly(p-chloromethylstyrene) beads. J Appl Polym Sci 83:2467–247310.1002/app.10239 ↗
39. Say R, Birlik E, Ersöz A, Yılmaz F, Gedikbey T, Denizli A (2003a) Preconcentration of copper on ion-selective imprinted polymer microbeads. Anal Chim Acta 480:251–25810.1016/S0003-2670(02)01656-2 ↗
40. Say R, Emir S, Garipcan B, Patır S, Denizli A (2003b) Novel methacryloylamidophenylalanine functionalized porous chelating beads for adsorption of heavy metal ions. Adv Polym Technol 22:355–36410.1002/adv.10062 ↗
41. Scancar J, Milacic R (2002) A novel approach for speciation of airborne chromium by convective-interaction media fast-monolithic chromatography with electrothermal atomic-absorption spectrometric detection. Analyst 127:629–63310.1039/b200876a ↗
42. Snell FD, Snell CT (1959) Colorimetric methods of analysis, vol 2, 3rd edn. Van Nostrand Company, Canada
43. Uğuzdoğan E, Denkbaş EB, Kabasakal OS (2010) The use of polyethyleneglycolmethacrylate-co-vinylimidazole (PEGMA-co-VI) microspheres for the removal of nickel(II) and chromium(VI) ions. J Hazard Mater 177:119–12510.1016/j.jhazmat.2009.12.004 ↗
44. Uygun DA, Karagözler AA, Akgöl S, Denizli A (2009) Magnetic hydrophobic affinity nanobeads for lysozyme separation. Mater Sci Eng C 29:2165–217310.1016/j.msec.2009.04.018 ↗
45. Yong-Gang Z, Hao-Yu S, Sheng-Dong P, Mei-Qin H (2010) Synthesis, characterization and properties of ethylenediamine-functionalized Fe3O4 magnetic polymers for removal of Cr(VI) in wastewater. J Hazard Mater 182:295–30210.1016/j.jhazmat.2010.06.029 ↗