journal article·2012-03

Optical investigation of Tb3+-doped Y2O3 nanocrystals prepared by Pechini-type sol–gel process

M. Back, A. Massari, M. Boffelli, F. Gonella, P. Riello, D. Cristofori, R. Riccò, F. Enrichi

Journal of Nanoparticle Research· Volume 14· Issue 4
Publisher page

Abstract

We report an optical study of Tb3+-doped Y2O3 nanocrystals synthesized by Pechini-type sol–gel method. The particles are investigated in terms of size and morphology by means of X-ray diffraction and transmission electron microscopy analysis. It is shown how the simple Pechini method allows for the growth of monocrystalline nanoparticles with a volume-weighted average size of about 30 nm. The optical properties of Tb3+ in the host lattice are studied in terms of PL, PLE, and lifetimes. Moreover, a correlation between the type of decay curves, the emission and excitation bands' shapes, and the site location of the emitting Tb3+ in the host material Y2O3 is proposed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Optical properties and cooling technologies in crystalline materials · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (55)

Show source-provided references
1. Anh TK, Benalloul P, Barthou C, Giang LTK, Vu N, Minh LQ (2007) Luminescence, energy transfer and upconversion mechanisms of Y2O3 nanomaterials doped with Eu3+, Tb3+, Tm3+, Er3+ and Yb3+ ions. J Nanomater 2007(Article ID 48247):1–10. doi: 10.1155/2007/4824710.1155/2007/48247 ↗
2. Benedetti A, Polizzi S, Riello P, Battisti AD, Maldotti A (1991) X-ray diffraction characterization of iridium dioxide electrocatalysts. J Mater Chem 1(4):511–515. doi: 10.1039/JM991010051110.1039/jm9910100511 ↗
3. Bhargava RN, Chhabra V, Kulkarni B, Veliadis JV (1998) Transformation of deep impurities to shallow impurities by quantum confinement. Phys Status Solidi 210:621–629. doi: 10.1002/(SICI)1521-3951(199812)210:2<621::AID-PSSB621>3.0.CO;2-410.1002/(SICI)1521-3951(199812)210:2<621::AID-PSSB621>3.0.CO;2-4 ↗
4. Blasse G, Grabmaier BC (1994) Luminescent materials. Springer, Berlin10.1007/978-3-642-79017-1 ↗
5. Butler KH (1980) Fluorescent lamp phosphors. Pennsylvania State University Press, University Park
6. Chen XY, Zhuang HZ, Liu GK, Li S, Niedbala R (2003) Confinement on energy transfer between luminescent centers in nanocrystals. J Appl Phys 94:5559–5565. doi: 10.1063/1.161486510.1063/1.1614865 ↗
7. Cuif JP, Rohart E, Macadiere P, Bauregard C, Suda E, Pacaud B, Imanaka N, Masui T, Tamura S (2004) In: Adachi G, Imanaka N, Kang Z (eds) Binary rare earth oxides, chap 9. Kluwer, New York
8. Das GK, Tan TTY (2008) Rare-earth-doped and codoped Y2O3 nanomaterials as potential bioimaging probes. J Phys Chem C 12(30):11211–11217. doi: 10.1021/jp802076n10.1021/jp802076n ↗
9. Enrichi F (2008) Luminescent amine-functionalized or erbium-doped silica spheres for biological applications. Ann NY Acad Sci 1130(1):262–266. doi: 10.1196/annals.1430.03010.1196/annals.1430.030 ↗
10. Enrichi F, Trave E, Bersani M (2008) Acid synthesis of luminescent amine-functionalized or erbium-doped silica spheres for biological applications. J Fluoresc 18:507–511. doi: 10.1007/s10895-007-0292-z10.1007/s10895-007-0292-z ↗
11. Enrichi F, Riccò R, Meneghello A, Pierobon R, Cretaio E, Marinello F, Schiavuta P, Parma A, Riello P, Benedetti A (2010a) Investigation of luminescent dye-doped or rare-earth-doped monodisperse silica nanospheres for DNA microarray labelling. Opt Mater 32(12):1652–1658. doi: 10.1016/j.optmat.2010.04.02610.1016/j.optmat.2010.04.026 ↗
12. Enrichi F, Riccò R, Scopece P, Parma A, Mazaheri A, Riello P, Benedetti A (2010b) Comparison of Eu(NO3)3 and Eu(acac)3 precursors for doping luminescent silica nanoparticles. J Nanopart Res 12:1925–1931. doi: 10.1007/s110 51-009-9756-110.1007/s11051-009-9756-1 ↗
13. Falcomer D, Speghini A, Ibba G, Enzo S, Cannas C, Musinu A, Bettinelli M (2007) Morphology and luminescence of nanocrystalline Nb2O5 doped with Eu3+. J Nanomater 2007(Article ID 94975):1–5. doi: 10.1155/2007/9497510.1155/2007/94975 ↗
14. Flores-Gonzalez MA, Ledoux G, Roux S, Lebbou K, Perriat P, Tillement O (2005) Preparing nanometer scaled Tb-doped Y2O3 luminescent powders by the polyol method. J Solid State Chem 178:989–997. doi: 10.1016/j.jssc.2004.10.02910.1016/j.jssc.2004.10.029 ↗
15. Gwak JH, Park SH, Jang JE, Lee SJ, Jung JE, Kim JM (2000) Synthesis and modification of red oxide phosphors for low voltage excitation. J Vac Sci Technol B 18:1101–1105. doi: 10.1116/1.59133810.1116/1.591338 ↗
16. Huang S, Lou L (1990) Concentration dependence of sensitizer fluorescence intensity in energy transfer. Chin J Lumin 11(1):36–41. ISSN:1000-7032.0.1990-01-000
17. Jiang D, Chong CN (2008) Anti-counterfeiting using phosphor PUF. In: 2nd International conference on anti-counterfeiting, security and identification. ASID 2008, pp 59–6210.1109/IWASID.2008.4688338 ↗
18. Kakihana M, Yoshimura M (1999) Synthesis and characteristics of complex multicomponent oxides prepared by polymer complex method. Bull Chem Soc Jpn 72(7):1427–144310.1246/bcsj.72.1427 ↗
19. Kim GC, Park HL, Kim TW (2001) Emission color tuning from blue to green through cross-relaxation in heavily Tb3+-doped YAlO3. Mater Res Bull 36:1603–1608. doi: 10.1016/S0025-5408(01)00556-610.1016/S0025-5408(01)00556-6 ↗
20. Lakowicz JR (1999) Principle of fluorescence spectroscopy, 3rd edn. Kluwer Academic (Plenum Publisher), New York10.1007/978-1-4757-3061-6 ↗
21. Leavitt RP, Gruber JB, Chang NC, Morrison CA (1982) Optical spectra, energy levels, and crystal-field analysis of tripositive rare-earth ions in Y2O3. II. Non-Kramers ions in C 2 sites. J Chem Phys 76(10):4775–4788. doi: 10.1063/1.44279610.1063/1.442796 ↗
22. Li D, Lu SZ, Wang HY, Chen BJ, E SL, Zhang JH, Huang SH (2001) Concentration quenching of Tb3+ emissions in Y2O2S nanocrystals. Chin J Lumin 22(3):227–231. ISSN:1000-7032.0.2001-03-004
23. Lin J, Yu M, Lin CK, Liu XM (2007) Multiform oxide optical materials via the versatile Pechini-type sol–gel process: synthesis and characteristics. J Phys Chem C 111:5835–5845. doi: 10.1021/jp070062c10.1021/jp070062c ↗
24. Liu Z, Yu L, Wang Q, Tao Y, Yang H (2011) Effect of Eu,Tb codoping on the luminescent properties of Y2O3 nanorods. J Lumin 131:12–16. doi: 10.1016/j.jlumin.2010.08.01210.1016/j.jlumin.2010.08.012 ↗
25. Lü Q, Wu Y, Ding L, Zu G, Li A, Zhao Y, Cui H (2010) Visible upconversion luminescence of Tb3+ ions in Y2O3 nanoparticles induced by a near-infrared femtosecond laser. J Alloys Compd 496:488–493. doi: 10.1016/j.jallcom.2010.02.08510.1016/j.jallcom.2010.02.085 ↗
26. Mahalingam V, Mangiarini F, Vetrone F, Venkatramu V, Bettinelli M, Speghini A, Capobianco J (2008) Bright white upconversion emission from Tm3+/Yb3+/Er3+-doped Lu3Ga5O12 nanocrystals. J Phys Chem C 112(46):17745–17749. doi: 10.1021/jp807647910.1021/jp8076479 ↗
27. Martín-Rodríguez R, Valiente R, Polizzi S, Bettinelli M, Speghini A, Piccinelli F (2009) Upconversion luminescence in nanocrystals of Gd3Ga5O12 and Y3Al5O12 doped with Tb3+-Yb3+ and Eu3+-Yb3+. J Phys Chem C 113(28):12195–12200. doi: 10.1021/jp901711g10.1021/jp901711g ↗
28. Mehta A, Thundat T, Barnes MD, Chhabra V, Bhargava R, Bartko AP, Dickson RM (2003) Size-correlated spectroscopy and imaging of rare-earth-doped nanocrystals. Appl Opt 42:2132–2139. doi: 10.1364/AO.42.00213210.1364/AO.42.002132 ↗
29. Meng Q, Chen B, Xu W, Yang Y, Zhao X, Di W, Lu S, Wang X, Sun J, Cheng L, Yu T, Peng Y (2007) Size-dependent excitation spectra and energy transfer in Tb3+-doped Y2O3 nanocrystalline. J Appl Phys 102:093505-1. doi: 10.1063/1.2803502
30. Muenchausen RE, Jacobsohn LG, Bennett BL, McKigney EA, Smith JF, Valdez JA, Cooke DW (2007) Effects of Tb doping on the photoluminescence of Y2O3:Tb nanophosphors. J Lumin 126:838–842. doi: 10.1016/j.jlumin.2006.12.00410.1016/j.jlumin.2006.12.004 ↗
31. Nigara Y (1968) Measurement of the optical constants of yttrium oxide. Jpn J Appl Phys 7:404–408. doi: 10.1143/JJAP.7.40410.1143/JJAP.7.404 ↗
32. Ou-Yang FP, Tang B (2003) Study on energy trasfer of Y2O2S:Tb nanocrystals. Rare Met Mater Eng 32(7):522–525
33. Park JH, Back NG, Kwak MG, Jun BE, Choi BC, Moon BK, Jeong JH, Yi SS, Kim JB (2007) Synthesis and properties of luminescent Y2O3:Tb3+(5, 8, 12 wt.%) nanocrystals. Mater Sci Eng C 27:998–1001. doi: 10.1016/j.msec.2006.08.01210.1016/j.msec.2006.08.012 ↗
34. Parma A, Freris I, Riello P, Enrichi F, Cristofori D, Benedetti A (2010) Structural and photoluminescence properties of ZrO2:Eu3+ @ SiO2 nanophosphors as a function of annealing temperature. J Lumin 130(12):2429–2436. doi: 10.1016/j.jlumin.2010.08.00710.1016/j.jlumin.2010.08.007 ↗
35. Pechini MP (1967) Method of preparing lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor. US Patent, US 3330697
36. Riello P, Bucella S, Brunelli D, Fossa F, Benedetti A, Trave E, Mazzoldi P (2006a) Reduction of concentration-induced luminescence quenching in Eu3+-doped nanoparticles embedded in silica. Opt Mater 28(11):1261–1265. doi: 10.1016/j.optmat.2006.01.01910.1016/j.optmat.2006.01.019 ↗
37. Riello P, Bucella S, Cristofori D, Benedetti A, Polloni R, Trave E, Mazzoldi P (2006b) Effect of the microstructure on concentration quenching in heavily doped Tb2O3-ZrO2 nanoparticles embedded in silica. Chem Phys Lett 431:326–331. doi: 10.1016/j.cplett.2006.09.08310.1016/j.cplett.2006.09.083 ↗
38. Saengkerdsub S, Im HJ, Willis C, Dai S (2004) Pechini-type in-situ polymerizable complex (IPC) method applied to the synthesis of Y2O3:Ln (Ln = Ce or Eu) nanocrystallites. J Mater Chem 14:1207–1211. doi: 10.1039/b309606h10.1039/b309606h ↗
39. Silvestrini S, Riello P, Freris I, Cristofori D, Enrichi F, Benedetti A (2010) Structural and luminescence properties of europium(III)-doped zirconium carbonates and silica-supported Eu3+-doped zirconium carbonate nanoparticles. J Nanopart Res 12(3):993–1002. doi: 10.1007/s11051-009-9655-510.1007/s11051-009-9655-5 ↗
40. Song H, Wang J (2006) Dependence of photoluminescent properties of cubic Y2O3:Tb3+ nanocrystals on particle size and temperature. J Lumin 18:220–226. doi: 10.1016/j.jlumin.2005.08.01610.1016/j.jlumin.2005.08.016 ↗
41. Soo YL, Huang SW, Kao YH, Chhabra V, Kulkami B, Veliadis JVD, Bhargava RN (1999) Controlled agglomeration of Tb-doped Y2O3 nanocrystals studied by X-ray absorption fine structure, X-ray excited luminescence, and photoluminescence. Appl Phys Lett 75:2464–2466. doi: 10.1063/1.12504910.1063/1.125049 ↗
42. Sotiriou GA, Schneider M, Pratsinis SE (2011) Color-tunable nanophosphors by codoping flame-made Y2O3 with Tb and Eu. J Phys Chem C 115:1084–1089. doi: 10.1021/jp106137u10.1021/jp106137u ↗
43. Srikanth V, Sato A, Yoshimoto J, JH Kim TI (1994) Synthesis and crystal structure study of Y2O3 high-pressure polymorph. Cryst Res Technol 29(7):981–984. doi: 10.1002/crat.217029071210.1002/crat.2170290712 ↗
44. Tian Y, Qi XH, Wu XW, Hua RN, Chen BJ (2009) Luminescent properties of Y2(MoO4)3:Eu3+ red phosphors with flowerlike shape prepared via coprecipitation method. J Phys Chem C 113:10767–10772. doi: 10.1021/jp901053q10.1021/jp901053q ↗
45. Tomiki T, Tamashiro J, Tanahara Y, Yamada A, Fukutani H, Miyahara T, Kato H, Shin S, Ishigame M (1986) Optical spectra of Y2O3 single crystals in VUV. J Phys Soc Jpn 55:4543–4549. doi: 10.1143/JPSJ.55.454310.1143/JPSJ.55.4543 ↗
46. van Schaik W, Blasse G (1992) Influence of defects on the luminescence quantum yield of Y1.94Eu0.06O3. Chem Mater 4:410–415. doi: 10.1021/cm00020a03310.1021/cm00020a033 ↗
47. Wakefied G, Holland E, Dobson PJ, Hutchison TL (2001) Luminescence properties of nanocrystalline Y2O3:Eu. Adv Mater 13:1557–1560. doi: 10.1002/1521-4095(200110)13:20<1557::AID-ADMA1557>3.0.CO;2-W10.1002/1521-4095(200110)13:20<1557::AID-ADMA1557>3.0.CO;2-W ↗
48. Wang L, Shi L, Liao N, Jia H, Du P, Xi Z, Wang L, Jin D (2010) Photoluminescence properties of Y2O3:Tb3+ and YBO3:Tb3+ green phosphors synthesized by hydrothermal method. Mater Chem Phys 119:490–494. doi: 10.1016/j.matchemphys.2009.10.00210.1016/j.matchemphys.2009.10.002 ↗
49. Warren BE (1969) X-ray diffraction. Addison Wesley, Reading
50. Wei X, Zhao J, Zhang W, Li Y, Yin M (2010) Cooperative energy transfer in Eu3+, Yb3+ codoped Y2O3 phosphor. J Rare Earths 28:166–170. doi: 10.1016/S1002-0721(09)60073-910.1016/S1002-0721(09)60073-9 ↗
51. Wickersheim KA, Lafever RA (1961) Infrared transmittance of crystalline yttrium oxide and related compounds. J Opt Soc Am 51:1147–1148. doi: 10.1364/JOSA.51.00114710.1364/JOSA.51.001147 ↗
52. Wu YC, Garapon C, Bazzi R, Pillonnet A, Tillement O, Mugnier J (2007) Optical and fluorescent properties of Y2O3 solgel planar waveguides containing Tb3+ doped nanocrystals. Appl Phys A 87:697–704. doi: 10.1007/s00339-007-3894-z10.1007/s00339-007-3894-z ↗
53. Zhang JC, Wang YH, Zhang ZY, Wang DY, Cl ZP, Sun YK (2007) The concentration quenching characteristics of 5D3-7F j and 5D4-7F j (j = 0–6) transitions of Tb3+ in YBO3:Tb3+ phosphor. Chin Sci Bull 52(16):2297–2300. doi: 10.1007/s11434-007-0329-310.1007/s11434-007-0329-3 ↗
54. Zhang P, Navrotsky A, Guo B, Kennedy I, Clark AN, Lesher C, Liu Q (2008) Energetics of cubic and monoclinic yttrium oxide polymorphs: phase transitions, surface enthalpies, and stability at the nanoscale. J Phys Chem C 112:932–938. doi: 10.1021/jp710233710.1021/jp7102337 ↗
55. Zheng H, Gao D, Fu Z, Wang E, Lei Y, Tuan Y, Cui M (2011) Fluorescence enhancement of Ln3+ doped nanoparticles. J Lumin 131:423–428. doi: 10.1016/j.jlumin.2010.09.02610.1016/j.jlumin.2010.09.026 ↗