journal article·2011-11

Synthesis, characterization, and photocatalytic properties of core/shell mesoporous silica nanospheres supporting nanocrystalline titania

K. Cendrowski, X. Chen, B. Zielinska, R. J. Kalenczuk, M. H. Rümmeli, B. Büchner, R. Klingeler, E. Borowiak-Palen

Journal of Nanoparticle Research· Volume 13· Issue 11
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Abstract

The facile bulk synthesis of silica nanospheres makes them an attractive support for the transport of chemical compounds such as nanocrystalline titanium dioxide. In this contribution we present a promising route for the synthesis of mesoporous silica nanospheres (m-SiO2) with diameter in range 200 nm, which are ideal supports for nanocrystalline titanium dioxide (TiO2). The detailed microscopic and spectroscopic characterizations of core/shell structure (m-SiO2/TiO2) were conducted. Moreover, the photocatalytic potential of the nanostructures was investigated via phenol decomposition and hydrogen generation. A clear enhancement of photoactivity in both reactions as compared to commercial TiO2-Degussa P25 catalyst is detected.
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Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Catalytic Processes in Materials Science · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Bian SW, Ma Z, Zhang LS, Niu F, Song WG (2009) Silica nanotubes with mesoporous walls and various internal morphologies using hard/soft dual templates. Chem Comm 14:1261–126310.1039/b821196e ↗
2. Chen SL (1998) Preparation of monosize silica spheres and their crystalline stack. Physicochem Eng Asp 142:59–6310.1016/S0927-7757(98)00276-3 ↗
3. Chen HM, He JH, Tang HM, Yan CX (2008) Porous silica nanocapsules and nanospheres: dynamic self-assembly synthesis and application in controlled release. Chem Mater 20:5894–590010.1021/cm801411y ↗
4. Das DP, Parida KM, Mishra BK (2007) A study on the structural properties of mesoporous silica spheres. Mater Lett 61:3942–394510.1016/j.matlet.2006.12.084 ↗
5. Deng X, Yue Y, Gao Z (2002) Gas-phase photo-oxidation of organic compounds over nanosized TiO2 photocatalysts by various preparations. Appl Catal 39:135–14710.1016/S0926-3373(02)00080-2 ↗
6. Deng YH, Qi DW, Deng CH, Zhang XM, Zhao DY (2008) Superparamagnetic high-magnetization microspheres with an Fe3O4·SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins. J Am Chem Soc 130:28–2910.1021/ja0777584 ↗
7. Fei HL, Liu YP, Li YP, Sun PC, Yuan ZZ, Li BH, Ding DT, Chen TH (2007) Selective synthesis of borated meso-macroporous and mesoporous spherical TiO2 with high photocatalytic activity. Micropor Mesopor Mater 102:318–32410.1016/j.micromeso.2007.01.021 ↗
8. Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–3810.1038/238037a0 ↗
9. Jia BP, Gao L, Sun J (2007) Self-assembly of magnetite beads along multiwalled carbon nanotubes via a simple hydrothermal process. Carbon 45:1476–148110.1016/j.carbon.2007.03.025 ↗
10. Kingam KJ, Hemley RJ (1994) Raman spectroscopic study of microcrystalline silica. Am Miner 79:269–273
11. Kim W, Suh DJ, Park TJ, Hong IK (2007) Photocatalytic degradation of methanol on titiania and titania-silica aerogels prepared by non-alkoxide sol–gel route. Top Catal 44:499–50510.1007/s11244-006-0097-3 ↗
12. Le Y, Pu M, Chen J (2007) Theoretical and experimental studies on the silica hollow spheres. J Non-Cryst Solids 353:164–16910.1016/j.jnoncrysol.2006.09.036 ↗
13. Lee YG, Park JH, Oh C, Oh SG, Kim YC (2007) Preparation of highly monodispersed hybrid silica spheres using a one-step sol−gel reaction in aqueous solution. Langmuir 23:10875–1087810.1021/la702462b ↗
14. Li M, Hong Z, Fang Y, Huang F (2008) Synergistic effect of two surface complexes in enhancing visible-light photocatalytic activity of titanium dioxide. Mater Res Bull 43:2179–218610.1016/j.materresbull.2007.08.030 ↗
15. Lim SH, Phonthammachai N, Pramana SS, White TJ (2008) Robust gold-decorated silica−titania pebbles for low-temperature CO catalytic oxidation. Langmuir 24:6226–623110.1021/la703899j ↗
16. Long R, Dai Y, Huang B (2009) Structural and electronic properties of iodine-doped anatase and rutile TiO2. Comput Mater Sci 45:223–22810.1016/j.commatsci.2008.09.011 ↗
17. Muruganandham M, Swaminathan M (2006) Photocatalytic decolourisation and degradation of reactive orange 4 by TiO2-UV process. Dyes Pigmen 68:133–14210.1016/j.dyepig.2005.01.004 ↗
18. Park JH, Kim S, Bard AJ (2006) Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting. Nano Lett 6:24–2810.1021/nl051807y ↗
19. Park MVDZ, Annema W, Salvati A, Lesniak A, Elsaesser A, Barnes C, McKerr G, Howard CY, Lynch I, Dawson KA, Piersma AH, Jong WH (2009) In vitro developmental toxicity test detects inhibition of stem cell differentiation by silica nanoparticles. Toxicol Appl Pharmacol 240:108–11610.1016/j.taap.2009.07.019 ↗
20. Stober W, Fink A, Bohn EJ (1968) Controlled growth of monodisperse silica spheres in the micron size range. Colloid Interface Sci 26:62–6910.1016/0021-9797(68)90272-5 ↗
21. Tan LK, Kumar MK, An WW, Gao H (2010) Transparent, well-aligned TiO2 nanotube arrays with controllable dimensions on glass substrates for photocatalytic applications. Am Chem Soc Appl Mater Interfaces 2:498–50310.1021/am900726k ↗
22. Tian G, Dong L, Wei C, Huang J, He H, Shao J (2006) Investigation on microstructure and optical properties of titanium dioxide coatings annealed at various temperature. Opt Mater 28:1058–106310.1016/j.optmat.2005.06.007 ↗
23. Wan L, Li JF, Feng JY, Sunb W, Mao ZQ (2007) Anatase TiO2 films with 2.2 eV band gap prepared by micro-arc oxidation. Mater Sci Eng 139:216–22010.1016/j.mseb.2007.02.014 ↗
24. Yang LM, Wang Y, Luo GS, Dai YY (2008) Preparation and functionalization of mesoporous silica spheres as packing materials for HPLC. Particuology 6:143–14810.1016/j.partic.2008.03.006 ↗
25. Yu H, Yu J, Cheng B (2007) Photocatalytic activity of the calcined H-titanate nanowires for photocatalytic oxidation of acetone in air. Chemosphere 66:2050–205710.1016/j.chemosphere.2006.09.080 ↗
26. Zhang J, Post M, Veres T, Jakubek ZJ, Guan J, Wang DS, Normandin F, Deslandes Y, Simard B (2006) Laser-assisted synthesis of superparamagnetic Fe·Au core−shell nanoparticles. J Phys Chem 110:7122–712810.1021/jp0560967 ↗
27. Zhang H, Zhong X, Xu JJ, Chen HY (2008) Fe3O4/Polypyrrole/Au nanocomposites with core/shell/shell structure: synthesis, characterization, and their electrochemical properties. Langmuir 24:13748–1375210.1021/la8028935 ↗
28. Zhu YF, Fang Y, Kaskel S (2010) Folate-conjugated Fe3O4·SiO2 hollow mesoporous spheres for targeted anticancer drug delivery. J Phys Chem 114:16382–16388
29. Zielińska B, Borowiak-Palen E, Kalenczuk RJ (2011) Preparation, characterization and photocatalytic activity of metal-loaded NaNbO3. J Phys Chem Solids 72:117–12310.1016/j.jpcs.2010.11.007 ↗