Synthesis and microwave absorption properties of electromagnetic functionalized Fe3O4–polyaniline hollow sphere nanocomposites produced by electrostatic self-assembly
Source abstract
Abstract
Highly regulated Fe 3 O 4 –polyelectrolyte-modified polyaniline (Fe 3 O 4 –PE@PANI) hollow sphere nanocomposites were successfully synthesized using an electrostatic self-assembly approach. The morphology and structure of the Fe 3 O 4 –PE@PANI nanocomposites were characterized using field-emission scanning electron microscopy, transmission electron microscopy, Fourier-transform infrared spectroscopy, X-ray powder diffraction, thermogravimetric analysis, and X-ray photoelectron spectroscopy. The results showed that the as-prepared nanocomposites had well-defined sizes and shapes, and the average size is about 500 nm. The assembly process was investigated. Magnetization measurements showed that the saturation magnetization of the nanocomposites was 38.6 emu g −1 . It was also found that the Fe 3 O 4 –PE@PANI nanocomposites exhibited excellent reflection loss abilities and wide response bandwidths compared with those of PANI hollow spheres in the range 0.5–15 GHz. The Fe 3 O 4 –PE@PANI nanocomposites are, therefore, promising for microwave absorption applications.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Conducting polymers and applications · Electromagnetic wave absorption materials · Advanced Sensor and Energy Harvesting Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Baibarac M, Baltog I, Lefrant S, Mevellec JY, Chauvet O (2003) Polyaniline and carbon nanotubes based composites containing whole units and fragments of nanotubes. Chem Mater 15:4149–4156. doi: 10.1021/cm021287x10.1021/cm021287x ↗
2. Bajpai AK, Gupta R (2010) Synthesis and characterization of magnetite (Fe3O4)—Polyvinyl alcohol-based nanocomposites and study of superparamagnetism. Polym Compos 31:245–255. doi: 10.1002/pc.2079310.1002/pc.20793 ↗
3. Bidan G, Jarjayes O, Fruchart JM, Hannecart E (1994) New nanocomposites based on “tailor dressed” magnetic particles in a polypyrrole matrix. Adv Mater 6:152–155. doi: 10.1002/adma.1994006021310.1002/adma.19940060213 ↗
4. Caruso F, Lichtenfeld H, Giersig M, Mohwald H (1998) Electrostatic self-assembly of silica nanoparticle-polyelectrolyte multilayers on polystyrene latex particles. J Am Chem Soc 120:8523–8524. doi: 10.1021/ja981502410.1021/ja9815024 ↗
5. Cui CK, Du YC, Li TH, Zheng XY, Wang XH, Han XJ, Xu P (2012) Synthesis of electromagnetic functionalized Fe3O4 microspheres/polyaniline composites by two-step oxidative polymerization. J Phys Chem B 116:9523–9531. doi: 10.1021/jp302409910.1021/jp3024099 ↗
6. Deng J, Peng Y, He C, Long X, Li P, Chan ASC (2003) Magnetic and conducting Fe3O4–polypyrrole nanoparticles with core–shell structure. Polym Int 52:1182–1187. doi: 10.1002/pi.123710.1002/pi.1237 ↗
7. Fang FF, Liu YD, Choi JH, Seo YS (2011) Core–shell structured carbonyl iron microspheres prepared via dual-step functionality coatings and their magnetorheological response. Appl Mater Interfaces 3:3487–3495. doi: 10.1021/am200714p10.1021/am200714p ↗
8. Gao C, Li WW, Morimoto H, Nagaoka Y, Maekawa T (2006) Magnetic carbon nanotubes: synthesis by electrostatic self-assembly approach and application in biomanipulations. J Phys Chem B 110:7213–7220. doi: 10.1021/jp060247410.1021/jp0602474 ↗
9. Gomez-Romero P (2001) Hybrid organic-inorganic materials-in search of synergic activity. Adv Mater 13:163–174. doi: 10.1002/1521-4095(20010210.1002/1521-4095(200102)13:3<163::AID-ADMA163>3.0.CO;2-U ↗
10. Gu HB, Tadakamalla S, Zhang X, Huang YD, Jiang Y, Colorado HA, Luo ZP, Wei SY, Guo ZH (2013) Epoxy resin nanosuspensions and reinforced nanocomposites from polyaniline stabilized multiwalled carbon nanotubes. J Mater Chem C 1:729–743. doi: 10.1039/c2tc00379a10.1039/C2TC00379A ↗
11. Kang ET, Neoh KG, Tan KL (1998) A polymer with many interesting intrinsic redox states. Prog Polym Sci 23:277–324. doi: 10.1016/S0079-6700(97)00030-010.1016/S0079-6700(97)00030-0 ↗
12. Kawaguchi H (2000) Functional polymer microspheres. Prog Polym Sci 25:1171–1210. doi: 10.1016/S0079-6700(00)00024-110.1016/S0079-6700(00)00024-1 ↗
13. Kim JH, Fang FF, Choi HJ, Seo YS (2008) Magnetic composites of conducting polyaniline/nano-sized magnetite and their magnetorheology. Mater Lett 62:2897–2899. doi: 10.1016/j.matlet.2008.01.06710.1016/j.matlet.2008.01.067 ↗
14. Kong I, Ahmad SH, Abdullah MH, Hui D, Yusoff AN, Puryanti D (2010) Magnetic and microwave absorbing properties of magnetite–thermoplastic natural rubber nanocomposites. J Magn Magn Mater 322:3401–3409. doi: 10.1016/j.jmmm.2010.06.03610.1016/j.jmmm.2010.06.036 ↗
15. Lee HY, Rwei SP, Wang LY, Chen PH (2008) Preparation and characterization of core–shell polyaniline–polystyrene sulfonate@Fe3O4 nanoparticles. Mater Chem Phys 112:805–809. doi: 10.1016/j.matchemphys.2008.06.05010.1016/j.matchemphys.2008.06.050 ↗
16. Li YB, Chen G, Li QH, Qiu GZ, Liu XH (2011) Facile synthesis, magnetic and microwave absorption properties of Fe3O4/polypyrrole core/shell nanocomposites. J Alloys Compd 509:4104–4107. doi: 10.1016/j.jallcom.2010.12.10010.1016/j.jallcom.2010.12.100 ↗
17. Liu YD, Choi HJ (2012) Carbon nanotube-coated silicated soft magnetic carbonyl iron microspheres and their magnetorheology. J Appl Phys 111:07B502-1-07B502-3. doi: 10.1063/1.367060310.1063/1.3670603 ↗
18. MacDiarmid AG (2001) Synthetic metals: a novel role for organic polymers. Synth Met 125:11–22. doi: 10.1016/S0379-6779(01)00508-210.1016/S0379-6779(01)00508-2 ↗
19. Marchessault RH, Rioux P, Raymond L (1992) Magnetic cellulose fibers and paper: preparation, processing and properties. Polymer 33:4024–4028. doi: 10.1016/0032-3861(92)90600-210.1016/0032-3861(92)90600-2 ↗
20. Markovic MG, Matisons JG, Cervini R, Simon GP, Fredericks PM (2006) Synthesis of new polyaniline/nanotube composites using ultrasonically initiated emulsion polymerization. Chem Mater 18:6258–6265. doi: 10.1021/cm061344c10.1021/cm061344c ↗
21. Meier W (2000) Polymer nanocapsules. Chem Soc Rev 29:295–303. doi: 10.1039/A809106D10.1039/a809106d ↗
22. Pan LJ, Pu L, Shi Y, Sun T, Zhang R, Zheng YO (2006) Hydrothermal synthesis of polyaniline mesostructures. Adv Funct Mater 16:1279–1288. doi: 10.1002/adfm.20050054310.1002/adfm.200500543 ↗
23. Peyratout CS, Dahne L (2004) Tailor-made polyelectrolyte microcapsules: from multilayers to smart containers. Angew Chem Int Ed 43:3762–3783. doi: 10.1002/anie.20030056810.1002/anie.200300568 ↗
24. Shchukin DG, Sukhorukov GB (2004) Nanoparticle synthesis in engineered organic nanoscale reactors. Adv Mater 16:671–682. doi: 10.1002/adma.20030646610.1002/adma.200306466 ↗
25. Shen W, Shi MM, Wang M, Chen HZ (2010) A simple synthesis of Fe3O4 nanoclusters and their electromagnetic nanocomposites with polyaniline. Mater Chem Phys 122:588–594. doi: 10.1016/j.matchemphys.2010.03.05110.1016/j.matchemphys.2010.03.051 ↗
26. Umare SS, Shambharkar BH, Ningthoujam RS (2010) Synthesis and characterization of polyaniline–Fe3O4 nanocomposite: electricalconductivity, magnetic, electrochemical studies. Synth Met 160:1815–1821. doi: 10.1016/j.synthmet.2010.06.01510.1016/j.synthmet.2010.06.015 ↗
27. Wang GQ, Chen XD, Duan YP, Liu SH (2008) Electromagnetic properties of carbon black and barium titanate composite materials. J Alloys Compd 454:340–346. doi: 10.1016/j.jallcom.2006.12.07710.1016/j.jallcom.2006.12.077 ↗
28. Wei HG, Yan XG, Wu SJ, Luo ZP, Wei SY, Guo ZH (2012a) Electropolymerized polyaniline stabilized tungsten oxide nanocomposite films: electrochromic behavior and electrochemical energy storage. J Phys Chem C 116:25052–25064. doi: 10.1021/jp309077710.1021/jp3090777 ↗
29. Wei JJ, Zhao R, Zhan YQ, Meng FB, Yang XL, Xu MZ, Liu XB (2012b) One-step solvothermal syntheses and microwave electromagnetic properties of organic magnetic resin/Fe3O4 hybrid nanospheres. Appl Surf Sci 258:6705–6711. doi: 10.1016/j.apsusc.2012.03.01510.1016/j.apsusc.2012.03.015 ↗
30. Wei HG, Gu HB, Guo J, Wei SY, Guo ZH (2013) Electropolymerized polyaniline nanocomposites from multi-walled carbon nanotubes with tuned surface functionalities for electrochemical energy storage. J Electrochem Soc 160:G3038–G3045. doi: 10.1149/2.006307jes10.1149/2.006307jes ↗
31. Zhang LJ, Wan MX (2003) Polyaniline/TiO2 composite nanotubes. J Phys Chem B 107:6748–6753. doi: 10.1021/jp034130g10.1021/jp034130g ↗
32. Zhang D, Karki AB, Rutman D, Young DP, Wang A, Cocke D, Ho TH, Guo ZH (2009a) Electrospun polyacrylonitrile nanocomposite fibers reinforced with Fe3O4 nanoparticles: fabrication and property analysis. Polymer 50:4189–4198. doi: 10.1016/j.polymer.2009.06.06210.1016/j.polymer.2009.06.062 ↗
33. Zhang YS, Xu WH, Yao WT, Yu SH (2009b) Oxidation-reduction reaction driven approach for hydrothermal synthesis of polyaniline hollow spheres with controllable size and shell thickness. J Phys Chem C 113:8588–8594. doi: 10.1021/jp810491u10.1021/jp810491u ↗
34. Zhang YJ, Lin YW, Chang CC, Wu TM (2011) Conducting and magnetic behaviors of polyaniline coated multi-walled carbon nanotube composites containing monodispersed magnetite nanoparticles. Synth Met 161:937–942. doi: 10.1016/j.synthmet.2011.02.02610.1016/j.synthmet.2011.02.026 ↗
35. Zhang X, He QL, Gu HB, Wei SY, Guo ZH (2013) Polyaniline stabilized barium titanate nanoparticles reinforced epoxy nanocomposites with high dielectric permittivity and reduced flammability. J Mater Chem C 1:2886–2889. doi: 10.1039/C3TC30129J10.1039/c3tc30129j ↗
36. Zhou WC, Hu XJ, Bai XX, Zhou SY, Sun CH, Yan J, Chen P (2011) Synthesis and electromagnetic, microwave absorbing properties of Core–Shell Fe3O4-Poly(3, 4-ethylenedioxythiophene) microspheres. Appl Mater Interfaces 3:3839–3845. doi: 10.1021/am200481210.1021/am2004812 ↗
37. Zhu YF, Fu YQ, Natsuki T, Ni QQ (2013) Fabrication and microwave absorption properties of BaTiO3 nanotube/polyaniline hybrid nanomaterials. Polym Compos 34:265–273. doi: 10.1002/pc.2240910.1002/pc.22409 ↗