Synthesis, structural and conductivity characterization of alginic acid–Fe3O4 nanocomposite
Source abstract
Abstract
Alginic acid–Fe3O4 nanocomposite is synthesized by the precipitation of Fe3O4 in the presence of alginic acid (AA). Structural, surface, morphological, thermal and electrical transport properties of the nanocomposite were performed by XRD, FT-IR, TEM-SEM, TGA and conductivity measurements respectively. FT-IR analysis revealed that Fe3O4 NPs are strongly capped with AA and TGA analysis showed that nanocomposite have 80% of Fe3O4 content. TEM analysis of Fe3O4 NPs show an average particle size of 9.5 nm, and upon nanocomposite formation with AA these particles are observed to form aggregates of ~150 nm. The frequency-dependency of the AC conductivity show electrode polarization effect. Analysis of electrical modulus and dielectric permittivity functions suggest that ionic and polymer segmental motions are strongly coupled. DC electrical conductivity is strongly temperature dependent, and is classified into three regions over a limited temperature range of up to 100 °C.
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Research context
OpenAlex topics: Polymer Nanocomposite Synthesis and Irradiation · Polymer Nanocomposites and Properties · Conducting polymers and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
Show source-provided references
1. Almond DP, Vaines B (1999) The dielectric properties of random R–C networks as an explanation of the `universal’ power law dielectric response of solids. J Phys Condens Matter 11:9081–9093. doi: 10.1088/0953-8984/11/46/31010.1088/0953-8984/11/46/310 ↗
2. Audram RG, Huguenard AP (1981) Magnetic recording elements containing transparent recording layer. U.S. Patent 4302523: 6 pages
3. Bhatnagar SP, Rosensweig RE (1995) Introduction to the magnetic fluids bibliography. J Magn Magn Mater 149:19810.1016/0304-8853(95)00378-9 ↗
4. Bruce IJ, Taylor J, Todd M, Davies MJ, Borioni E, Sangregorio C, Sen T (2004) Synthesis, characterisation and application of silica-magnetite nanocomposites. J Magn Magn Mater 284:145–160. doi: 10.1016/j.jmmm.2004.06.03210.1016/j.jmmm.2004.06.032 ↗
5. Celik SU, Bozkurt A (2008) Preparation and proton conductivity of acid-doped 5-aminotetrazole functional poly(glycidyl methacrylate). Eur Polym J 44:213–218. doi: 10.1016/j.eurpolymj.2007.10.01010.1016/j.eurpolymj.2007.10.010 ↗
6. Cheong M, Zhitomirsky I (2008) Electrodeposition of alginic acid and composite films. Colloids Surf A 328:73–78. doi: 10.1016/j.colsurfa.2008.06.01910.1016/j.colsurfa.2008.06.019 ↗
7. Coey JMD, Berkowitz AE, Balcells LI, Putris FF, Parker FT (1998) Magnetoresistance of magnetite. Appl Phys Lett 72:734–73710.1063/1.120859 ↗
8. Cornell RM, Schwertmann U (1996) The iron oxides: structure, properties, reactions occurrence and uses. VCH, New York, p 28
9. Durmus Z, Kavas H, Toprak MS, Baykal A, Altınçekiç TG, Aslan A, Bozkurt A, Coşgun S (2009) l-lysine coated magnetite nanoparticles: synthesis, structural and conductivity characterization. J alloys Compd 484:371–376. doi: 10.1016/j.jallcom.2009.04.10310.1016/j.jallcom.2009.04.103 ↗
10. Gomez-Lopera S, Plaza R, Delgado AJ (2001) Synthesis and characterization of spherical magnetite/biodegradable polymer composite particles. J Colloid Interface Sci 240:40–47. doi: 10.1006/jcis.2001.757910.1006/jcis.2001.7579 ↗
11. Hongwei G, Keming X, Zhimou Y, Chang CK, Xu B (2005) Synthesis and cellular uptake of porphyrin decorated iron oxide nanoparticles—a potential candidate for bimodal anticancer therapy. Chem Commun 34:4270–4272. doi: 10.1039/b507779f
12. Huang RYM, Pal R, Moon GY (1999) Characteristics of sodium alginate membranes for the pervaporation dehydration of ethanol–water and isopropanol–water mixtures. J Membr Sci 160:101–11310.1016/S0376-7388(99)00071-X ↗
13. Jianqi H, Hong H, Lieping S, Gengbua G (2002) Comparison of calcium alginate film with collagen membrane for guided bone regeneration in mandibular defects in rabbits. J Oral Maxillofac Surg 60:1449–1454. doi: 10.1053/joms.2002.3610810.1053/joms.2002.36108 ↗
14. Juillerat-Jeanneret L, Schmitt F (2007) Chemical modification of therapeutic drugs or drug vector systems to achieve targeted therapy: looking for the grail. Res Rev 27:574–590. doi: 10.1002/med.2008610.1002/med.20086 ↗
15. Kavas H, Durmus Z, Baykal A, Aslan A, Bozkurt A, Toprak MS (2010) Synthesis and conductivity evaluation of PVTri–Fe3O4 nanocomposite. J Noncryst Solids 356:484–486. doi: 10.1016/j.jnoncrysol.2009.12.02210.1016/j.jnoncrysol.2009.12.022 ↗
16. Kim DK, Zhang Y, Kehr J, Klasson T, Bjelke B, Muhammed M (2001) Characterization and MRI studyof surfactant-coated superparamagnetic nanoparticles administered into the rat brain. J Magn Magn Mater 225:256–26110.1016/S0304-8853(00)01255-5 ↗
17. Koseoglu Y, Kavas H, Aktas B (2006) Surface effects on magnetic properties of superparamagnetic magnetite nanoparticles. Phys Stat Sol A 203(7):1595–1598. doi: 10.1002/pssa.20056310410.1002/pssa.200563104 ↗
18. Kreuter JJ (1991) Nanoparticle-based dmg delivery systems. J.Control Release 16:169–17610.1016/0168-3659(91)90040-K ↗
19. Leroux F, Gachon J, Besse J (2004) Biopolymer immobilization during the crystalline growth of layered double hydroxide. J Solid State Chem 177:245–250. doi: 10.1016/j.jssc.2003.08.01310.1016/j.jssc.2003.08.013 ↗
20. Li G, Jiang Y, Huang K, Ding P, Chen J (2008) Preparation and properties of magnetic Fe3O4–chitosan nanoparticles. J Alloys Compd 466:451–546. doi: 10.1016/j.jallcom.2007.11.10010.1016/j.jallcom.2007.11.100 ↗
21. Liang WJ, Bockrath M, Bozovic D, Hafner JH, Tinkham M, Park H (2001) Fabry-Perot interference in a nanotube electron waveguide. Nature 411:665–669. doi: 10.1038/3507951710.1038/35079517 ↗
22. Marchessault RH, Richard S, Rioux P (1992) In situ synthesis of ferrites in lignocellulosics. Carbohydr Res 224:133–13910.1016/0008-6215(92)84100-7 ↗
23. McMichael RD, Shull RD, Swartzendruber LJ, Bennett LH, Watson RE (1992) Magnetocaloric effect in superparamagnets. J Magn Magn Mater 111:29–3310.1016/0304-8853(92)91049-Y ↗
24. Mikhaylova M, Kim DK, Berry CC, Zagorodni A, Toprak MS, Curtis ASG, Muhammed MBSA (2004) Immobilization on amine-functionalized superparamagnetic iron oxide nanoparticles. Chem Mater 16:2344–2354. doi: 10.1021/cm034890410.1021/cm0348904 ↗
25. Mura CV, Becker MI, Orellana A, Wolff D (2002) Immunopurification of golgi vesicles by magnetic sorting. J Immunol Methods 260:263–27110.1016/S0022-1759(01)00546-4 ↗
26. Nyquist RA, Kagel RO (1971) Infrared spectra of inorganic compounds. Academic Press, New York10.1016/B978-0-12-523450-4.50005-5 ↗
27. Özkaya T (2008) Synthesis and magnetic characterization of magnetic nanoparticles. Master Thesis, Fatih University, Istanbul
28. Özkaya T, Toprak MS, Baykal A, Kavas H, Köseoğlu Y, Aktaş B (2009) Synthesis of Fe3O4 nanoparticles at 100°C and its magnetic characterization. J Alloys Compd 472:18–23. doi: 10.1016/j.jallcom.2008.04.10110.1016/j.jallcom.2008.04.101 ↗
29. Panteny S, Stevens R, Bowen CR (2005) The frequency dependent permittivity and AC conductivity of random electrical networks. Ferroelectric 319:199–208. doi: 10.1088/0953-8984/11/46/31010.1080/00150190590965884 ↗
30. Pielaszek R (2003) Analytical expression for diffraction line profile for polydispersive powders. In: Applied crystallography proceedings of the XIX Conference, Krakow, Poland, p 43
31. Pope NM, Alsop RC, Chang YA, Sonith AK (1994) Evaluation of magnetic alginate beads as a solid support for positive selection of CD34+ cells. J Biomed Mater Res 28:449–457. doi: 10.1002/jbm.82028040710.1002/jbm.820280407 ↗
32. Portet D, Denizot B, Rump E, Lejeune J, Jallet P (2001) Nonpolymeric coatings of ıron oxide colloids for biological use as magnetic resonance ımaging contrast agents. J Colloid Interface Sci 238:37–4210.1006/jcis.2001.7500 ↗
33. Pradhan DK, Choudhary RNP, Samantaray BK (2008) Studies of dielectric relaxation and AC conductivity behavior of plasticized polymer nanocomposite electrolytes. Int J Electrochem Sci 3:597–60810.1016/S1452-3981(23)15547-7 ↗
34. Roger J, Pons J, Massart R, Halbreich A, Bacri J (1999) Some biomedical applications of ferrofluids. J Eur Phys J Appl Phys 5:321–325. doi: 10.1051/epjap:199914410.1051/epjap:1999144 ↗
35. Rosensweig RE (1985) Ferrohydrodynamics. MIT Press, Cambridge
36. Si SF, Li CH, Wang X, Yu D, Peng Q, Li YD (2005) Magnetic monodisperse Fe3O4 nanoparticles. Cryst Growth Design 5:391–393. doi: 10.1021/cg049790510.1021/cg0497905 ↗
37. Soeya S, Hayakawa J, Takahashi H, Ito K, Yamamoto C, Kida A, Asano H, Matsui M (2002) Development of half-metallic ultrathin Fe3O4 films for spin-transport devices. Appl Phys Lett 80:823–829. doi: 10.1063/1.144699510.1063/1.1446995 ↗
38. Sun SH, Zeng H (2004) Size-controlled synthesis of magnetite nanoparticles. J Am Chem Soc 124:8204–8205. doi: 10.1021/ja026501x10.1021/ja026501x ↗
39. Suzuki Y, Nishimura Y, Tanihara M, Suzuki K, Nakamura T, Shimizu Y, Yamawaki Y, Kakimaru Y (1998) Evaluation of a novel alginate gel dressing: Cytotoxicity to fibroblasts in vitro and foreign-body reaction in pig skin in vivo. J Biomed Mater Res 39:317–32210.1002/(SICI)1097-4636(199802)39:2<317::AID-JBM20>3.0.CO;2-8 ↗
40. Suzuki K, Suzuki Y, Tanihara M, Ohnishi K, Hashimoto T, Endo K, Nishimura Y (2000) Reconstruction of rat peripheral nerve gap without sutures using freeze-dried alginate gel. J Biomed Mater Res 49:528–53310.1002/(SICI)1097-4636(20000315)49:4<528::AID-JBM11>3.0.CO;2-1 ↗
41. Tang NJ, Zhong W, Jiang HY, Wu XL, Liu W, Du YW (2004) Nanostructured magnetite (Fe3O4) thin films prepared by sol–gel method. J Magn Magn Mater 282:92–95. doi: 10.1016/j.jmmm.2004.04.02210.1016/j.jmmm.2004.04.022 ↗
42. Toprak MS, McKenna BJ, Waite H, Stucky GD (2007) Control of size and permeability of nanocomposite microspheres. Chem Mater 19(17):4263–4269. doi: 10.1021/cm071215b10.1021/cm071215b ↗
43. Torchilin VP (2000) Drug targeting. Eur J Pharm Sci 11:S81–S9110.1016/S0928-0987(00)00166-4 ↗
44. Wei S, Zhu Y, Zhang Y, Xu J (2007) Preparation and characterization of hyperbranched aromatic polyamides/Fe3O4 magnetic nanocomposite. React Funct Polym 66:1272–1277. doi: 10.1016/j.reactfunctpolym.2006.03.00810.1016/j.reactfunctpolym.2006.03.008 ↗
45. Wejrzanowski T, Pielaszek R, Opalińska A, Matysiak H, Lojkowski W, Kurzydlowski KJ (2006) Quantitative methods for nanopowders characterization. Appl Surf Sci 253:204–208. doi: 10.1016/j.apsusc.2006.05.08910.1016/j.apsusc.2006.05.089 ↗
46. Wunderbaldinger P, Josephson L, Weissleder R (2002) Tat peptide directs enhanced clearance and hepatic permeability of magnetic nanoparticles. Bioconjug Chem 13:264–268. doi: 10.1021/bc015563u10.1021/bc015563u ↗
47. Yapar E, Kayahan SK, Bozkurt A, Toppare L (2009) Immobilizing cholesterol oxidase in chitosan–alginic acid network. Carbohydr Polym 76:430–436. doi: 10.1016/j.carbpol.2008.11.00110.1016/j.carbpol.2008.11.001 ↗
48. Ziolo RF (1984) Developer composition containing superparamagnetic polymers. U.S. Patent 4474866, 4 pp