New nanocomposites containing metal nanoparticles, carbon nanotube and polymer
Source abstract
Abstract
Metal-carbon nanotube-graft-polymer (MCNT-g-P) nanocomposites were synthesized and characterized successfully. In this work, multiwall carbon nanotubes (MWCNT) were opened using HNO3/H2SO4 mixture and filled by metal nanoparticles such as silver nanoparticles through wet chemistry method. Then MWCNT containing metal nanoparticles were used as macroinitiator for ring opening polymerization of e-caprolactone and MCNT-g-P nanocomposites were obtained. Length of grafted polymer arms onto the MWCNT was controlled using MWCNT/e-caprolactone ratio. Structure and properties of nanocomposites were evaluated by TEM, DSC, TGA, and spectroscopy methods.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon Nanotubes in Composites · Graphene and Nanomaterials Applications · Polymer Nanocomposite Synthesis and Irradiation
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (75)
Show source-provided references
1. Ajayan PM (1999) Nanotubes from carbon. Chem Rev 99:1787–180010.1021/cr970102g ↗
2. Ajayan PM, Zhou OZ (2001) Applications of carbon nanotubes. Top Appl Phys 80:391–42510.1007/3-540-39947-X_14 ↗
3. Baibarac M, Baltog I, Lefrant S, Mevellec JY, Chauvet O (2003) Polyaniline and carbon nanotubes based composites containing whole units and fragments of nanotubes. Chem Mater 15:4149–415610.1021/cm021287x ↗
4. Baibarac M, Baltog I, Godon C, Lefrant S, Chauvet O (2004) Covalent functionalization of single-walled carbon nanotubes by aniline electrochemical polymerization. Carbon 42:3143–315210.1016/j.carbon.2004.07.030 ↗
5. Bahr JL, Yang J, Kosynkin DV, Bronikowski MJ, Smalley RE, Tour JM (2001) Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: a bucky paper electrode. J Am Chem Soc 123:6536–654210.1021/ja010462s ↗
6. Baughman RH, Zakhidov AA, de Heer WA (2002) Carbon nanotubes––the route toward applications. Science 297:787–79210.1126/science.1060928 ↗
7. Blake R, Gun’ko YK, Coleman J, Cadek M, Fonseca A, Nagy JB, Blau WJ, Generic A (2004) Organometallic approach toward ultra-strong carbon nanotube polymer composites. J Am Chem Soc 126:10226–1022710.1021/ja0474805 ↗
8. Cahill LS, Yao Z, Adronov A, Penner J, Moonoosawmy KR, Kruse P, Goward GR (2004) Polymer-functionalized carbon nanotubes investigated by solid-state nuclear magnetic resonance and scanning tunneling microscopy. J Phys Chem B 108:11412–1141810.1021/jp0491865 ↗
9. Cao L, Chen H-Z, Li H-Y, Zhou H-B, Sun J-Z, Zhang X-B, Wang M (2003) Fabrication of rare-earth biphthalocyanine encapsulated by carbon nanotubes using a capillary filling method. Chem Mater 15:3247–324910.1021/cm034326t ↗
10. Chen Q, Xu R, Yu D (2006) Multiwalled carbon nanotube/polybenzoxazine nanocomposites: preparation, characterization and properties. Polymer 47:7711–771910.1016/j.polymer.2006.08.058 ↗
11. Cochet M, Maser WK, Benito AM, Callejas MA, Martinez MT, Benoit JM, Schreiber J, Chauvet O (2001) Synthesis of a new polyaniline/nanotube composite: “in-situ” polymerisation and charge transfer through site-selective interaction. Chem Commun 1450–145110.1039/b104009j ↗
12. Coleman JN, Cadek M, Blake R, Nicolosi V, Ryan KP, Belton C, Fonseca A, Nagy JB, Gun’ko YK, Blau WJ (2004) High performance nanotube-reinforced plastics: understanding the mechanism of strength increase. Adv Funct Mater 14:791–79810.1002/adfm.200305200 ↗
13. Cullity BD, Stock SR (2001) Elements of x-ray diffraction. New Jersey
14. Dillon AC, Jones KM, Bekkedahl TA, Kiang CH, Bethune DS, Heben MJ (1997) Storage of hydrogen in single-walled carbon nanotubes. Nature 386:377–38010.1038/386377a0 ↗
15. Do Nascimento GM, Corio P, Novickis RW, Temperini MLA, Dresselhaus MS (2005) Synthesis and characterization of single-wall-carbon-nanotube-doped emeraldine salt and base polyaniline nanocomposites. J Polym Sci Part A 43:815–82210.1002/pola.20551 ↗
16. Dresselhaus M, Dresselhaus G, Avouris P (2001) Carbon nanotubes: synthesis, properties and applications. Springer-Verlag, Berlin10.1007/3-540-39947-X ↗
17. Dyke CA, Tour JM (2003a) Unbundled and highly functionalized carbon nanotubes from aqueous reactions. Nano Lett 3:1215–121810.1021/nl034537x ↗
18. Dyke CA, Tour JM (2003b) Solvent-free functionalization of carbon nanotubes. J Am Chem Soc 125:1156–115710.1021/ja0289806 ↗
19. Gao C, Jin YZ, Kong H, Whitby RLD, Acquah SFA, Chen GY, Qian H, Hartschuh A, Silva SRP, Henley S, Fearon P, Kroto HW, Walton DRM (2005) Polyurea-functionalized multiwalled carbon nanotubes: synthesis, morphology, and Raman spectroscopy. J Phys Chem B 109:11925–1193210.1021/jp051642h ↗
20. Gao C, Li W, Jin YZ, Kong H (2006) Facile and large-scale synthesis and characterization of carbon nanotube/silver nanocrystal nanohybrids. Nanotechnology 17:2882–289010.1088/0957-4484/17/12/010 ↗
21. Guldi DM, Rahman GNA, Ramey J, Marcaccio M, Paolucci D, Paolucci F, Qin S, Ford WT, Balbinot D, Jux N, Tagmatarchis N, Prato M (2004) Donor–acceptor nanoensembles of soluble carbon nanotubes. Chem Commun 2034–203510.1039/b406933a ↗
22. Guldi DM, Rahman GMA, Prato M, Jux N, Qin S, Ford W (2005) Single-wall carbon nanotubes as integrative building blocks for solar-energy conversion. Angew Chem Int Ed 44:2015–201810.1002/anie.200462416 ↗
23. Hadjiev VG, Mitchell CA, Arepalli S, Bahr JL, Tour JM, Krishnamoorti R (2005) Thermal mismatch strains in sidewall functionalized carbon nanotube/polystyrene nanocomposites. J Chem Phys 122:124708–12471410.1063/1.1874912 ↗
24. Hu H, Zhao B, Hamon MA, Kamaras K, Itkis ME, Haddon RC (2003) Sidewall functionalization of single-walled carbon nanotubes by addition of dichlorocarbene. J Am Chem Soc 125:14893–1490010.1021/ja0356737 ↗
25. Hudson JL, Casavant MJ, Tour JM (2004) Water-soluble, exfoliated, nonroping single-wall carbon nanotubes. J Am Chem Soc 126:11158–1115910.1021/ja0467061 ↗
26. Hwang GL, Shieh Y-T, Hwang KC (2004) Efficient load transfer to polymer-grafted multiwalled carbon nanotubes in polymer composites. Adv Funct Mater 14:487–49110.1002/adfm.200305382 ↗
27. Jia ZJ, Wang ZY, Xu C, Liang J, Wei BQ, Wu DH, Zhu SW (1999) Study on poly(methyl methacrylate)/carbon nanotube composites. Mater Sci Eng A271:395–400
28. Kamaras K, Itkis ME, Hu H, Zhao B, Haddon RC (2003) Covalent bond formation to a carbon nanotube metal. Science 301:1501–150310.1126/science.1088083 ↗
29. Kawasaki S, Komatsu K, Okino F, Touhara H, Kataura H (2004) Fluorination of open- and closed-end single-walled carbon nanotubes. Chem Phys 6:1769–1772
30. Kim BM, Qian S, Bau HH (2005) Filling carbon nanotubes with particles. Nano Lett 5:873–87810.1021/nl050278v ↗
31. Kong H, Gao C, Yan D (2004a) Functionalization of multiwalled carbon nanotubes by atom transfer radical polymerization and defunctionalization of the products. Macromolecules 37:4022–403010.1021/ma049694c ↗
32. Kong H, Gao C, Yan D (2004b) Controlled functionalization of multiwalled carbon nanotubes by in situ atom transfer radical polymerization. J Am Chem Soc 126:412–41310.1021/ja0380493 ↗
33. Kong H, Li W, Gao C, Yan D, Jin Y, Walton DRM, Kroto HW (2004c) Poly(N-isopropylacrylamide)-coated carbon nanotubes: temperature-sensitive molecular nanohybrids in water. Macromolecules 37:6683–668610.1021/ma048682o ↗
34. Kong H, Gao C, Yan D (2004d) Constructing amphiphilic polymer brushes on the convex surfaces of multi-walled carbon nanotubes by in situ atom transfer radical polymerization. J Mater Chem 14:1401–140510.1039/b401180e ↗
35. Kong H, Luo P, Gao C, Yan D (2005) Polyelectrolyte-functionalized multiwalled carbon nanotubes: preparation, characterization and layer-by-layer self-assembly. Polymer 46:2472–248510.1016/j.polymer.2005.01.037 ↗
36. Koshio A, Yudasaka M, Zhang M, Iijima S (2001) A simple way to chemically react single-wall carbon nanotubes with organic materials using ultrasonication. Nano Lett 1:361–363.10.1021/nl0155431 ↗
37. Kudin KN, Bettinger HF, Scuseria GE (2001) Fluorinated single-wall carbon nanotubes. Phys Rev B 63:045413–04542110.1103/PhysRevB.63.045413 ↗
38. Lee H, Yoon SW, Kim EJ, Park J (2007) In-situ growth of copper sulfide nanocrystals on multiwalled carbon nanotubes and their application as novel solar cell and amperometric glucose sensor materials. Nano Lett 7:778–78410.1021/nl0630539 ↗
39. Liu I-C, Huang H-M, Chang C-Y, Tsai H-C, Hsu C-H, Tsiang RC-C (2004a) Preparing a styrenic polymer composite containing well-dispersed carbon nanotubes: anionic polymerization of a nanotube-bound p-methylstyrene. Macromolecules 37:283–28710.1021/ma0304168 ↗
40. Liu Y, Tang J, Xin JH (2004b) Fabrication of nanowires with polymer shells using treated carbon nanotube bundles as macro-initiators. Chem Commun 2828–282910.1039/b412282h ↗
41. Liu Y, Yao Z, Adronov A (2005) Functionalization of single-walled carbon nanotubes with well-defined polymers by radical coupling. Macromolecules 38:1172–117910.1021/ma048273s ↗
42. Lu X, Chen Z (2005) Curved Pi-conjugation, aromaticity, and the related chemistry of small fullerenes (C60) and single-walled carbon nanotubes. Chem Rev 105:3643–369610.1021/cr030093d ↗
43. Mawhinney DB, Naumenko V, Kuznetsova A, Yates JT Jr, Liu J, Smalley RE (2000) Infrared spectral evidence for the etching of carbon nanotubes: ozone oxidation at 298 K. J Am Chem Soc 122:2383–238410.1021/ja994094s ↗
44. Murugesan S, Park T-J, Yang H, Mousa S, Linhardt RJ (2006) Blood compatible carbon nanotubes––nano-based neoproteoglycans. Langmuir 22:3461–346310.1021/la0534468 ↗
45. Nian J-N, Teng H (2006) Hydrothermal synthesis of single-crystalline anatase TiO2 nanorods with nanotubes as the precursor. J Phys Chem B 110:4193–419810.1021/jp0567321 ↗
46. Niu C, Sichel EK, Hoch R, Moy D, Tennet H (1997) High power electerochemical capacitors based on carbon nanotube. Appl Phys Lett 7:1480–148310.1063/1.118568 ↗
47. Park SJ, Cho MS, Lim ST, Choi HJ, Jhon MS (2003) Synthesis and dispersion characteristics of multi-walled carbon nanotube composites with poly(methyl methacrylate) prepared by in-situ bulk polymerization. Macromol Rapid Commun 24:1070–107310.1002/marc.200300089 ↗
48. Petrov P, Lou X, Pagnoulle C, Jerome C, Calberg C, Jerome R (2004) Functionalization of multi-walled carbon nanotubes by electrografting of polyacrylonitrile. Macromol Rapid Commun 25:987–99010.1002/marc.200400055 ↗
49. Qin S, Qin D, Ford WT, Resasco DE, Herrera JE (2004a) Functionalization of single-walled carbon nanotubes with polystyrene via grafting to and grafting from methods. Macromolecules 37:752–75710.1021/ma035214q ↗
50. Qin S, Qin D, Ford WT, Herrera JT, Resasco DE, Bachilo SM, Weisman RB (2004b) Solubilization and purification of single-wall carbon nanotubes in water by in situ radical polymerization of sodium 4-styrenesulfonate. Macromolecules 37:3965–396710.1021/ma049681z ↗
51. Qin S, Qin D, Ford WT, Herrera JT, Resasco DE (2004c) Grafting of poly(4-vinylpyridine) to single-walled carbon nanotubes and assembly of multilayer films. Macromolecules 37:9963–996710.1021/ma048692p ↗
52. Qin S, Qin D, Ford WT, Zhang Y, Kotov NA (2005) Covalent cross-linked polymer/single-wall carbon nanotube multilayer films. Chem Mater 17:2131–213510.1021/cm048239s ↗
53. Robertson N, McGowan CA (2003) A comparison of potential molecular wires as components for molecular electronics. Chem Soc Rev 32:96–10310.1039/b206919a ↗
54. Sainz R, Benito AM, Martinez MT, Galindo JF, Sotres J, Baro AM, Corraze B, Chauvet O, Maser WK (2005) Soluble self-aligned carbon nanotube/polyaniline composites. Adv Mater 17:278–28110.1002/adma.200400921 ↗
55. Shaffer MSP, Koziol K (2002) Polystyrene grafted multi-walled carbon nanotubes. Chem Commun 2074–207510.1039/b205806p ↗
56. Strano MS (2003) Probing chiral selective reactions using a revised Kataura Plot for the interpretation of single-walled carbon nanotube spectroscopy. J Am Chem Soc 125:16148–1615310.1021/ja036791x ↗
57. Sung JH, Kim HS, Jin H-J, Choi HJ, Chin I-J (2004) Nanofibrous membranes prepared by multiwalled carbon nanotube/poly(methyl methacrylate) composites. Macromolecules 37:9899–990210.1021/ma048355g ↗
58. Tans SJ, Verschueren ARM, Dekker C (1998) Room-temperature transistor based on a single carbon nanotube. Nature 393:49–5210.1038/29954 ↗
59. Tasis D, Tagmatarchis N, Bianco A, Prato M (2006) Chemistry of carbon nanotubes. Chem Rev 106:1105–113610.1021/cr050569o ↗
60. Tong X, Liu C, Cheng H-M, Zhao H, Yang F, Zhang X (2004) Surface modification of single-walled carbon nanotubes with polyethylene via in situ Ziegler-Natta polymerization. J Appl Polym Sci 92:3697–370010.1002/app.20306 ↗
61. Touhara H, Okino F (2000) Property control of carbon materials by fluorination. Carbon 38:241–26710.1016/S0008-6223(99)00140-2 ↗
62. Touhara H, Inahara J, Mizuno T, Yokoyama Y, Okanao S, Yanagiuch K, Mukopadhyay I, Kawasaki S, Okino F, Shirai H, Xu WH, Kyotani T, Tomita A (2002) Property control of new forms of carbon materials by fluorination. J Fluor Chem 114:181–18810.1016/S0022-1139(02)00026-X ↗
63. Tsang SC, Chen YK, Harris PJF, Green MLH (1994) A simple chemical method of opening and filling carbon nanotubes. Nature 372:159–16210.1038/372159a0 ↗
64. Viswanathan G, Chakrapani N, Yang H, Wei B, Chung H, Cho K, Ryu CY, Ajayan PM (2003) Single-step in situ synthesis of polymer-grafted single-wall nanotube composites. J Am Chem Soc 125:9258–925910.1021/ja0354418 ↗
65. Wu W, Zhang S, Li Y, Li J, Liu L, Qin Y, Guo Z-X, Dai L, Ye C, Zhu D (2003) PVK-modified single-walled carbon nanotubes with effective photoinduced electron transfer. Macromolecules 36:6286–628810.1021/ma034513c ↗
66. Xia H, Wang Q, Qiu G (2003) Polymer-encapsulated carbon nanotubes prepared through ultrasonically initiated in situ emulsion polymerization. Chem Mater 15:3879–388610.1021/cm0341890 ↗
67. Xu Y, Gao C, Kong H, Yan D, Jin YZ, Watts PCP (2004) Growing multihydroxyl hyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization. Macromolecules 37:8846–885310.1021/ma0484781 ↗
68. Yang Y, Wang X, Liu L, Xie X, Yang Z, Li RKY, Mai Y-W (2007) Structure and photoresponsive behaviors of multiwalled carbon nanotubes grafted by polyurethanes containing azobenzene side chains. J Phys Chem C 111:11231–1123910.1021/jp0728510 ↗
69. Yao Z, Braidy N, Botton GA, Adronov A (2003) Polymerization from the surface of single-walled carbon nanotubes––preparation and characterization of nanocomposites. J Am Chem Soc 125:16015–1602410.1021/ja037564y ↗
70. Yudanov NF, Okotrub AV, Shubin YV, Yudanova LI, Bulusheva LG, Chuvilin AL, Bonard JM (2002) Fluorination of arc-produced carbon material containing multiwall nanotubes. Chem Mater 14:1472–147610.1021/cm0103141 ↗
71. Yudasaka M, Zhang M, Jabs C, Iijima S (2001) Effect of an organic polymer in purification and cutting of single-wall carbon nanotubes. Appl Phys A 71:449–45110.1007/s003390000688 ↗
72. Zeng H, Gao C, Yan D (2006a) Poly(ε-caprolactone)-functionalized carbon nanotubes and their biodegradation properties. Adv Funct Mater 16:812–81810.1002/adfm.200500607 ↗
73. Zeng H, Gao C, Wang Y, Watts PCP, Kong H, Cui X, Yan D (2006b) In situ polymerization approach to multiwalled carbon nanotubes-reinforced nylon 1010 composites: Mechanical properties and crystallization behavior. Polymer 47:113–12210.1016/j.polymer.2005.11.009 ↗
74. Zengin H, Zhou W, Jin J, Czerw R, Smith DW Jr, Echegoyen L, Carroll DL, Foulger SH, Ballato J (2002) Carbon nanotube doped polyaniline. Adv Mater 14:1480–148310.1002/1521-4095(20021016)14:20<1480::AID-ADMA1480>3.0.CO;2-O ↗
75. Zhu J, Peng H, Rodriguez-Macias F, Margrave JL, Khabashesku VN, Imam AN, Lozano K, Barrera EV (2004) Reinforcing epoxy polymer composites through covalent integration of functionalized nanotubes. Adv Funct Mater 14:643–64810.1002/adfm.200305162 ↗