journal article·2009-10Open access

A novel approach to metal and metal oxide nanoparticle synthesis: the oil-in-water microemulsion reaction method

Margarita Sanchez-Dominguez, Magali Boutonnet, Conxita Solans

Journal of Nanoparticle Research· Volume 11· Issue 7

Abstract

A novel and straightforward approach, based on oil-in-water (o/w) microemulsions, was developed for the synthesis of inorganic nanoparticles at ambient conditions. It implies the use of organometallic precursors dissolved in nanometre-scale oil droplets of o/w microemulsions. Addition of reducing or oxidizing/precipitating agents results in the formation of metallic or metal oxide nanoparticles, respectively. Nonionic o/w microemulsion systems were chosen, and several key compositions were selected for nanoparticle synthesis at 25 °C. High Resolution Electron Microscopy revealed that small nanoparticles of metals (Pt, Pd and Rh) and nanocrystalline metal oxide (cerium (IV) oxide with cubic type crystalline structure confirmed by XRD), of less than 7 nm can be obtained in mild conditions.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Surfactants and Colloidal Systems · Gold and Silver Nanoparticles Synthesis and Applications · Coagulation and Flocculation Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (16)

Show source-provided references
1. Boutonnet M, Kizling J, Stenius P (1982) The preparation of monodisperse colloidal metal particles from microemulsions. Colloids Surf 5:209–225. doi: 10.1016/0166-6622(82)80079-610.1016/0166-6622(82)80079-6 ↗
2. Boutonnet M, Lödberg S, Svensson EE (2008) Recent developments in the application of nanoparticles prepared from w/o microemulsions in heterogeneous catalysis. Curr Opin Colloid Interface Sci 13:270–286. doi: 10.1016/j.cocis.2007.10.00110.1016/j.cocis.2007.10.001 ↗
3. Cavalli R, Caputo O, Marengo E, Pattarino F, Gasco MR (1998) The effect of the components of microemulsions on both size and crystalline structure of solid lipid nanoparticles (SLN) containing a series of model molecules. Pharmazie 53:392–396
4. Cushing BL, Kolesnichenko VL, O’Connor CJ (2004) Recent advances in the liquid-phase syntheses of inorganic nanoparticles. Chem Rev 104:3893–3946. doi: 10.1021/cr030027b10.1021/cr030027b ↗
5. Destrée C, Nagy JB (2006) Mechanism of formation of inorganic and organic nanoparticles from microemulsions. Adv Colloid Interface Sci 123–126:353–367. doi: 10.1016/j.cis.2006.05.02210.1016/j.cis.2006.05.022 ↗
6. Dörfler HD, Große A (1996) Applications of microemulsions with different compositions in detergents technique. Prog Colloid Polym Sci 101:113–115. doi: 10.1007/BFb011445310.1007/BFb0114453 ↗
7. Eastoe J, Hollamby MJ, Hudson L (2006) Recent advances in nanoparticle synthesis with reversed micelles. Adv Colloid Interface Sci 128–130:5–15. doi: 10.1016/j.cis.2006.11.00910.1016/j.cis.2006.11.009 ↗
8. Hentze HP, Kaler EW (2003) Polymerization of and within self-organized media. Curr Opin Colloid Interface Sci 8:164–178. doi: 10.1016/S1359-0294(03)00018-910.1016/S1359-0294(03)00018-9 ↗
9. Holmberg K (2003) Organic reactions in microemulsions. Curr Opin Colloid Interface Sci 8:187–196. doi: 10.1016/S1359-0294(03)00017-710.1016/S1359-0294(03)00017-7 ↗
10. Holmberg K (2004) Surfactant-templated nanomaterials synthesis. J Colloid Interface Sci 274:355–365. doi: 10.1016/j.jcis.2004.04.00610.1016/j.jcis.2004.04.006 ↗
11. Larsson KM, Adlercreutz P, Mattiasson B, Olsson U (1991) Enzyme catalysis in uni- and bi-continuous microemulsions: dependence of kinetics on substrate partitioning. J Chem Soc Faraday Trans 87:465–471. doi: 10.1039/ft991870046510.1039/ft9918700465 ↗
12. Lawrence MJ, Rees GD (2000) Microemulsion-based media as novel drug delivery systems. Adv Drug Deliv Rev 45:89–121. doi: 10.1016/S0169-409X(00)00103-410.1016/S0169-409X(00)00103-4 ↗
13. Lindman B, Friberg SE (1999) Microemulsions: a hystorical overview. In: Kumar P, Mittal KL (eds) Handbook of microemulsion science and technology. Marcel Dekker, New York, pp 1–12
14. López-Quintela MA, Tojo C, Blanco MC, Garcia-Rio L, Leis JR (2004) Microemulsion dynamics and reactions in microemulsions. Curr Opin Colloid Interface Sci 9:264–278. doi: 10.1016/j.cocis.2004.05.02910.1016/j.cocis.2004.05.029 ↗
15. Pileni MP (1997) Nanosized particles made in colloidal assemblies. Langmuir 13:3266–3276. doi: 10.1021/la960319q10.1021/la960319q ↗
16. Scholes FH, Hughes AE, Hardin SG, Lynch P, Miller PR (2007) Influence of hydrogen peroxide in the preparation of nanocrystalline ceria. Chem Mater 19:2321–2328. doi: 10.1021/cm063024z10.1021/cm063024z ↗