journal article·2009-02

Preparation of Fe3O4/polystyrene composite particles from monolayer oleic acid modified Fe3O4 nanoparticles via miniemulsion polymerization

Feng Yan, Jun Li, Jianjun Zhang, Fengqi Liu, Wensheng Yang

Journal of Nanoparticle Research· Volume 11· Issue 2
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Abstract

Fe3O4/polystyrene composite particles were prepared from oleic acid (OA) modified Fe3O4 nanoparticles via miniemulsion polymerization. It was concluded that the surface properties of OA modified magnetite nanoparticles have a great effect on preparation of the composite particles. When Fe3O4 nanoparticles coated by multilayer of OA was employed, there were large amounts of free polystyrene particles in the product. Fe3O4/polystyrene composite particles with defined structure and different magnetite content can be readily prepared from monolayer OA modified Fe3O4 nanoparticles. It was concluded that surface of the monolayer OA modified Fe3O4 nanoparticles is more hydrophobic than that of the multilayer coated ones, thus improving the dispersibility of the Fe3O4 nanoparticles in styrene monomer and allowing preparation of the Fe3O4/polystyrene composite particles with defined structure and controllable magnetite content.
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Research context

OpenAlex topics: Nanoparticle-Based Drug Delivery · Electrostatics and Colloid Interactions · Polymer Nanocomposites and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Antonietti M, Landfester K (2002) Polyreactions in miniemulsions. Prog Polym Sci 27(4):689–75710.1016/S0079-6700(01)00051-X ↗
2. Bucak S, Jones DA, Laibinis PE, Hatton TA (2003) Protein separations using colloidal magnetic nanoparticles. Biotechnol Prog 19(2):477–48410.1021/bp0200853 ↗
3. Csetneki I, Faix MK, Szilágyi A, Kovács AL, Németh Z, Zrinyi M (2004) Preparation of magnetic polystyrene latex via the miniemulsion polymerization technique. J Polym Sci Part: A Polym Chem 42(19):4802–480810.1002/pola.20300 ↗
4. De Palma R, Peeters S, Van Bael MJ, Van den Rul H, Bonroy K, Laureyn W, Mullens J, Borghs G, Maes G (2007) Silane ligand exchange to make hydrophobic superparamagnetic nanoparticles water dispersible. Chem Mater 19(7):1821–183110.1021/cm0628000 ↗
5. Deng Y, Wang L, Yang W, Fu S, Elaïssari A (2003) Preparation of magnetic polymeric particles via inverse microemulsion polymerization process. J Magn Magn Mater 257(1):69–7810.1016/S0304-8853(02)00987-3 ↗
6. Dubois LH, Zegarski BR, Nuzzo RG (1986) Spontaneous organization of carboxylic acid monolayer films in ultrahigh vacuum. Kinetic constraints to assembly via gas-phase adsorption. Langmuir 2(4):412–41710.1021/la00070a006 ↗
7. Fried T, Shemer G, Markovich G (2001) Ordered two-dimensional arrays of ferrite nanoparticles. Adv Mater 13(15):1158–116110.1002/1521-4095(200108)13:15<1158::AID-ADMA1158>3.0.CO;2-6 ↗
8. Frydman E, Cohen H, Maoz R, Sagiv J (1997) Monolayer damage in XPS measurements as evaluated by independent methods. Langmuir 13(19):50895–5010610.1021/la962058q ↗
9. Galindo-González C, de Vicente J, Ramos-Tjada MM, López- López MT, González-Caballero F, Durán JDG (2005) Preparation and sedimentation behavior in magnetic fields of magnetite-covered clay particles. Langmuir 21(10):4410–441910.1021/la047393q ↗
10. Gu H, Ho P-L, Tsang KWT, Wang L, Xu B (2003) Using biofunctional magnetic nanoparticles to capture vancomycin-resistant enterococci and other gram-positive bacteria at ultralow concentration. J Am Chem Soc 125(51):15702–1570310.1021/ja0359310 ↗
11. Gupta AK, Gupta M (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26(18):3995–402110.1016/j.biomaterials.2004.10.012 ↗
12. Jordan A, Scholz R, Wust P, Fähling H, Felix R (1999) Magnetic fluid hyperthermia (MFH): cancer treatment with AC magnetic field induced excitation of biocompatible superparamagnetic nanoparticles. J Magn Magn Mater 201(1–3):413–41910.1016/S0304-8853(99)00088-8 ↗
13. Korolev VV, Ramazanova AG, Blinov AV (2002) Adsorption of surfactants on superfine magnetite. Russ Chem Bull Int Ed 51(11):2044–204910.1023/A:1021655708965 ↗
14. Liu X, Guan Y, Ma Z, Liu H (2004) Surface modification and characterization of magnetic polymer nanospheres prepared by miniemulsion polymerization. Langmuir 20(23):10278–1028210.1021/la0491908 ↗
15. Lu S, Forcada J (2006) Preparation and characterization of magnetic polymeric composite particles by miniemulsion polymerization. J Polym Sci Part: A Polym Chem 44(13):4187–420310.1002/pola.21525 ↗
16. Lu Z, Wang G, Zhuang J, Yang W (2006) Effects of the concentration of tetramethylammonium hydroxide peptizer on the synthesis of Fe3O4/SiO2 core/shell nanoparticles. Colloids Surf A Physicochem Eng 278(1–3):140–14310.1016/j.colsurfa.2005.09.048 ↗
17. López-López MT, Durán JDG, Delgado AV, González-Caballero F (2005) Stability and magnetic characterization of oleate-covered magnetite ferrofluids in different nonpolar carriers. J Colloid Interface Sci 291(1):144–15110.1016/j.jcis.2005.04.099 ↗
18. Massart R (1981) Preparation of aqueous magnetic liquids in alkaline and acidic media. IEEE Trans Magn MAG-17(2):1247–124810.1109/TMAG.1981.1061188 ↗
19. Neuberger T, Schöpf B, Hofmann H, Hofmann M, Rechenberg BV (2005) Superparamagnetic nanoparticles for biomedical applications: Possibilities and limitations of a new drug delivery system. J Magn Magn Mater 293(2):483–49610.1016/j.jmmm.2005.01.064 ↗
20. Ramírez LP, Landfester K (2003) Magnetic polystyrene nanoparticles with a high magnetite content obtained by miniemulsion processes. Macromol Chem Phys 204(1):22–3110.1002/macp.200290052 ↗
21. Reimers J, Schork FJ (1996) Robust nucleation in polymer-stabilized miniemulsion polymerization. J Appl Polym Sci 59(12):1833–184110.1002/(SICI)1097-4628(19960321)59:12<1833::AID-APP4>3.0.CO;2-R ↗
22. Ren Y, Iimura KI, Kato T (2001) Structure of barium stearate films at the air/water interface investigated by polarization modulation infrared spectroscopy and π-alsotherms. Langmuir 17(9):2688–269310.1021/la000872e ↗
23. Sacanna S, Philipse AP (2006) Preparation and properties of monodisperse latex spheres with controlled magnetic moment for field-induced colloidal crystallization and (dipolar) chain formation. Langmuir 22(24):10209–1021610.1021/la0616505 ↗
24. Sahoo Y, Pizem H, Fried T, Golodnitsky D, Burstein L, Sukenik CN, Markovich G (2001) Alkyl phosphonate/phosphate coating on magnetite nanoparticles: a comparison with fatty acids. Langmuir 17(25):7907–791110.1021/la010703+ ↗
25. Shang H, Chang WS, Kan SH, Majetich SA, Lee GU (2006) Synthesis and characterization of paramagnetic microparticles through emulsion-templated free radical polymerization. Langmuir 22(6):2516–252210.1021/la052636f ↗
26. Shen L, Laibinis PE, Hatton TA (1999) Bilayer surfactant stabilized magnetic fluids: synthesis and interactions at interfaces. Langmuir 15(2):447–45310.1021/la9807661 ↗
27. Veiseh O, Sun C, Gunn J, Kohler N, Gabikian P, Lee D, Bhattarai N, Ellenbogen R, Sze R, Hallahan A, Olson J, Zhang MQ (2005) Optical and MRI multifunctional nanoprobe for targeting gliomas. Nano Lett 5(6):1003–100810.1021/nl0502569 ↗
28. Vestal CR, Zhang ZJ (2002) Atom transfer radical polymerization synthesis and magnetic characterization of MnFe2O4/Polystyrene core/shell nanoparticles. J Am Chem Soc 124(48):14312–1431310.1021/ja0274709 ↗
29. Wang Y, Teng X, Wang J-S, Yang H (2003) Solvent-free atom transfer radical polymerization in the synthesis of Fe2O3@polystyrene core-shell nanoparticles. Nano Lett 3(6):789–79310.1021/nl034211o ↗
30. Wang P-C, Chiu W-Y, Lee C-F, Young T-H (2004) Synthesis of iron oxide/poly(methyl methacrylate) composite latex particles: nucleation mechanism and morphology. J Polym Sci Part A: Polym Chem 42(22):5695–570510.1002/pola.20335 ↗
31. Willis AL, Turro NJ, O’Brien S (2005) Spectroscopic characterization of the surface of iron oxide nanocrystals. Chem Mater 17(24):5970–597510.1021/cm051370v ↗
32. Wu N, Fu L, Su M, Aslam M, Wong KC, Dravid VP (2004) Interaction of fatty acid monolayers with cobalt nanoparticles. Nano Lett 4(2):383–38610.1021/nl035139x ↗
33. Xu X, Friedman G, Humfeld KD, Majetich SA, Asher SA (2002) Synthesis and utilization of monodisperse superparamagnetic colloidal particles for magnetically controllable photonic crystals. Chem Mater 14(3):1249–125610.1021/cm010811h ↗
34. Xu C, Xu K, Gu H, Zheng R, Liu H, Zhang X, Guo Z, Xu B (2004) Dopamine as a robust anchor to immobilize functional molecules on the iron oxide shell of magnetic nanoparticles. J Am Chem Soc 126(32):9938–993910.1021/ja0464802 ↗
35. Yang C, Wang G, Lu Z, Sun J, Zhuang J, Yang W (2005) Effect of ultrasonic treatment on dispersibility of Fe3O4 nanoparticles and synthesis of multi-core Fe3O4/SiO2 core/shell nanoparticles. J Mater Chem 15(39):4252–425710.1039/b505018a ↗