Multiple magnetic characteristics in pure and Mn porphyrin-doped single-walled carbon nanotubes
Source abstract
Abstract
Magnetism of single-walled carbon nanotubes (SWCNT) is probed and an unexpected multiple magnetic behavior is observed. Paramagnetism, diamagnetism, and ferro(antiferro)magnetism in superparamagnetic form are present in 99.9 % pure samples. A paramagnetic component and a diamagnetic component, both present in the whole magnetic field range, add up to form a net diamagnetism, as expected. Moreover, antiferromagnetism is present. By contrast, a Mn(III)-porphyrin/SWCNT nanocomposite shows a different behavior. The SWCNT net diamagnetism vanishes, and spin-glass (spin-canted) behavior is observed. A de Almeida–Thouless line fit is used to verify the existence of the spin-glass state. Thermogravimetric analysis, along with electron spin resonance and energy dispersive spectrometry indicates that the amount of residual catalyst nanoparticles <1 % wt. left from the synthesis of SWCNT is unable to explain the magnetic behavior observed. Theoretical works are used to explain the phenomena.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Carbon Nanotubes in Composites · Graphene research and applications · Fullerene Chemistry and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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