Magnetic and dielectric properties of Mn0.2Ni0.8Fe2O4 nanoparticles synthesized by PEG-assisted hydrothermal method
Source abstract
Abstract
We present a systematic investigation on the structural and magnetic properties of Mn0.2Ni0.8Fe2O4 nanoparticles synthesized by a polyethylene glycol (PEG)-assisted hydrothermal route. XRD, FT-IR, TEM and VSM were used for the structural, morphological, dielectric properties and magnetic investigation of the products, respectively. Average crystallite size of product was estimated using Line profile fitting as 6 ± 1 nm and particle size as 6.5 ± 1.0 nm from TEM micrographs. Magnetization measurements have shown that the particles have a blocking temperature of 134 K. Magnetization and the coercive field of the sample increase by decreasing the temperature. The conductivity measurements reveal the semiconducting behaviour for the sample. Temperature-dependent dielectric properties: dielectric permittivity (e) and ac conductivity (σac) for the sample were studied as a function of applied frequency in the range from 1 Hz to 3 MHz. These studies indicated that the dielectric dispersion curve for the sample showed usual dielectric dispersion which can be explained on the basis of Koop’s theory, which is based on the Maxwell–Wagner model for the interfacial polarization of homogeneous double structure.
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Research context
OpenAlex topics: Magnetic Properties and Synthesis of Ferrites · Multiferroics and related materials · Magneto-Optical Properties and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Abdeen AM (1999) Dielectric behaviour in Ni–Zn ferrites. J Magn Magn Mater 192:121–129. doi: 10.1016/S0304-8853(98)00324-210.1016/S0304-8853(98)00324-2 ↗
2. Anantharaman MR, Sindhu S, Jagatheesan S, Malini KA, Kurian P (1999) Dielectric properties of rubber ferrite composites containing mixed ferrites. J Physics D: Appl Phys 32:180110.1088/0022-3727/32/15/307 ↗
3. Atif M, Hasanain SK, Nadeem M (2006) Magnetization of sol–gel prepared zinc ferrite nanoparticles: Effects of inversion and particle size. Solid State Commun 138:416–421. doi: 10.1016/j.ssc.2006.03.02310.1016/j.ssc.2006.03.023 ↗
4. Balaji G, Gajbhiye NS, Wilde G, Weissmüller J (2002) Magnetic properties of MnFe2O4 nanoparticles. J Magn Magn Mater 242–245:617–620. doi: 10.1016/S0304-8853(01)01043-510.1016/S0304-8853(01)01043-5 ↗
5. Chinnasamy CN, Narayanasamy A, Ponpandian N, Chattopadhyay K, Guerault H, Greneche J-M (2000) Magnetic properties of nanostructured ferrimagnetic zinc ferrite. J Phys 12:7795–7806. doi: 10.1088/0953-8984/12/35/314
6. Farea AMM, Kumar S, Batoo KM, Yousef A, Lee CG, Alimuddin (2008) Structure and electrical properties of Co0.5Cd x Fe2.5−x O4 ferrites. J Alloys Compd 464:361–369. doi: 10.1016/j.jallcom.2007.09.12610.1016/j.jallcom.2007.09.126 ↗
7. Ghasemi A, Hossienpour A, Morisako A, Saakhi A, Saleki M (2006) Electromagnetic properties and microwave absorbing characteristics of doped barium hexaferrite. J Magn Magn Mater 302:429–435. doi: 10.1016/j.jmmm.2005.10.00610.1016/j.jmmm.2005.10.006 ↗
8. Gul IH, Abbasi AZ, Amin F, Anis-ur-Rehman M, Maqsood A (2007) Structural, magnetic and electrical properties of Co1−x Zn x Fe2O4 synthesized by co-precipitation method. J Magn Magn Mater 311:494–499. doi: 10.1016/j.jmmm.2006.08.00510.1016/j.jmmm.2006.08.005 ↗
9. Kapse VD, Ghosh SA, Raghuwanshi FC, Kapse SD, Khandekar US (2009) Nanocrystalline Ni0.6Zn0.4Fe2O4: a novel semiconducting material for ethanol detection. Talanta 78:19–25. doi: 10.1016/j.talanta.2008.10.03110.1016/j.talanta.2008.10.031 ↗
10. Kasapoglu N, Baykal A, Köseoğlu Y, Toprak MS (2007) Microwave-assisted combustion synthesis of CoFe2O4 with urea, and its magnetic characterization. Scripta Mater 57:441–444. doi: 10.1016/j.scriptamat.2007.04.04210.1016/j.scriptamat.2007.04.042 ↗
11. Kavas H, Baykal A, Toprak MS, Köseoğlu Y, Sertkol M, Aktas B (2009) Cation distribution and magnetic properties of Zn doped NiFe2O4 nanoparticles synthesized by PEG-assisted hydrothermal route. J Alloys Compd 479:49–55. doi: 10.1016/j.jallcom.2009.01.01410.1016/j.jallcom.2009.01.014 ↗
12. Koops CG (1951) On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys Rev 83:121–124. doi: 10.1103/PhysRev.83.12110.1103/PhysRev.83.121 ↗
13. Köseoğlu Y, Kavas H (2008) Size and surface effects on magnetic properties of Fe3O4 nanoparticles. J Nanosci Nanotechnol 8:584–590. doi: 10.1166/jnn.2008.B01210.1166/jnn.2008.B012 ↗
14. Kuznetsov MV, Barquın LF, Pankhurst QA, Parkin IV (1999) Self-propagating high-temperature synthesis of barium-chromium ferrites BaFe12-x Cr x O19 (0 x6.0). J Phys D 32:2590–2598. doi: 10.1088/0022-3727/32/20/30210.1088/0022-3727/32/20/302 ↗
15. Li F, Wang H, Wang L, Wang J (2007) Magnetic properties of ZnFe2O4 nanoparticles produced by a low-temperature solid-state reaction method. J Magn Magn Mater 309:295–299. doi: 10.1016/j.jmmm.2006.07.01210.1016/j.jmmm.2006.07.012 ↗
16. Liu J, Xua T, Gong M, Yu F (2006) Fundamental studies of novel inorganic–organic charged zwitterionic hybrids: 4. New hybrid zwitterionic membranes prepared from polyethylene glycol (PEG) and silane coupling agent. J Membr Sci 283:190–200. doi: 10.1016/j.memsci.2006.06.02710.1016/j.memsci.2006.06.027 ↗
17. Maxwell JC (1973) Electricity and magnetism. Oxford University Press, NewYork, p 828
18. McMichael RD, Shull RD, Swartzendruber IJ, Bennett LH (1992) Magnetocaloric effect in superparamagnets. J Magn Magn Mater 111:29–33. doi: 10.1016/0304-8853(92)91049-Y10.1016/0304-8853(92)91049-Y ↗
19. Miroshkin VP, Panova YAI, Passynkov VV (1981) Dielectric relaxation in polycrystalline ferrites. Phys Stat Sol A 66:779–782. doi: 10.1002/pssa.221066024510.1002/pssa.2210660245 ↗
20. Mohammed EM, Malini KA, Kurian P, Anantharaman MR (2002) Modification of dielectric and mechanical properties of rubber ferrite composites containing manganese zinc ferrite. Mater Res Bull 37:753–768. doi: 10.1016/S0025-5408(02)00690-610.1016/S0025-5408(02)00690-6 ↗
21. Ozkaya T, Baykal A, Toprak MS, Köseoğlu Y, Durmus Z (2009) Reflux synthesis of Co3O4 nanoparticles and its magnetic characterization. J Magn Magn Mater 321:2145–2149. doi: 10.1016/j.jmmm.2009.01.00310.1016/j.jmmm.2009.01.003 ↗
22. Özkaya T, Toprak MS, Baykal A, Kavas H, Köseoğlu Y, Aktaş Synthesis B (2009) Synthesis of Fe3O4 nanoparticles at 100 °C and its magnetic characterization. J Alloys Compd 472:18–23. doi: 10.1016/j.jallcom.2008.04.10110.1016/j.jallcom.2008.04.101 ↗
23. Pelecky DL, Rieke RD (1996) Magnetic properties of nanostructured materials. Chem Mater 8:1770–1783. doi: 10.1021/cm960077f10.1021/cm960077f ↗
24. Pielaszek R (2003) Analytical expression for diffraction line profile for polydispersive powders. Appl crystallogr. In: Proceedings of the XIX Conference, Krakow, Poland, pp 43–50
25. Ponpandian N, Narayanasamy A (2002) Influence of grain size and structural changes on the electrical properties of nanocrystalline zinc ferrite. J Appl Phys 92(5):2770–2778. doi: 10.1063/1.149888310.1063/1.1498883 ↗
26. Psarras GC (2006) Hopping conductivity in polymer matrix–metal particles composites. Compos A 37:1545–1553. doi: 10.1016/j.compositesa.2005.11.00410.1016/j.compositesa.2005.11.004 ↗
27. Rabinkin LI, Novikova ZI (1960) Ferrites. Minsk, p 146
28. Ravinder D, Reddy AVR, Rangamohan G (2002) Abnormal dielectric behaviour in polycrystalline zinc-substituted manganese ferrites at high frequencies. Mater Lett 52:259–265. doi: 10.1016/S0167-577X(01)00404-910.1016/S0167-577X(01)00404-9 ↗
29. Reddy SV, Radhe Shyam A, Dwivedi R, Gupta RK, Chumbale VR, Prasad R (2004) Ortho-selective vapour phase methylation of phenol over nanocrystalline ferrospinels of varying Zn2+/Mn2+ ionic composition. J Chem Technol Biotechnol 79:1057–1064. doi: 10.1002/jctb.106010.1002/jctb.1060 ↗
30. Rondinone AJ, Samia ACS, Zhang ZJ (1999) Superparamagnetic relaxation and magnetic anisotropy energy distribution in CoFe2O4 spinel ferrite nanocrystallites. J Phys Chem B 103:6876–6880. doi: 10.1021/jp991230710.1021/jp9912307 ↗
31. Sahoo Y, Cheon M, Wang S, Luo H, Furlani EP, Prasad PN (2004) Field-directed self-assembly of magnetic nanoparticles. J Phys Chem B 108:3380–3383. doi: 10.1021/jp031148i10.1021/jp031148i ↗
32. Sawatsky A, van der Woude F, Morrish AH (1968) Cation distributions in octahedral and tetrahedral sites of the ferrimagnetic spinel CoFe2O4. J Appl Phys 39:1204–1206. doi: 10.1063/1.165622410.1063/1.1656224 ↗
33. Sertkol M (2008) Synthesis and magnetic characterization of microwave absorbing materials. Master Thesis, Fatih University, Istanbul
34. Sertkol M, Köseoğlu Y, Baykal A, Kavas H, Basaran AC (2009a) Synthesis and magnetic characterization of Zn0.6Ni0.4Fe2O4 nanoparticles via a polyethylene glycol-assisted hydrothermal route. J Magn Magn Mater 321:157–162. doi: 10.1016/j.jmmm.2008.08.08310.1016/j.jmmm.2008.08.083 ↗
35. Sertkol M, Köseoğlu Y, Baykal A, Kavas H, Bozkurt A, Toprak MS (2009b) Microwave synthesis and characterization of Zn-doped nickel ferrite nanoparticles. J Alloys Compd 486:325–329. doi: 10.1016/j.jallcom.2009.06.12810.1016/j.jallcom.2009.06.128 ↗
36. Sertkol M, Köseoğlu Y, Baykal A, Kavas H, Toprak MS (2010) Synthesis and magnetic characterization of Zn0.7Ni0.3Fe2O4 nanoparticles via microwave-assisted combustion route. J Magn Magn Mater 322:866–871. doi: 10.1016/j.jmmm.2009.11.01810.1016/j.jmmm.2009.11.018 ↗
37. Shyam AR, Dwivedi R, Reddy VS, Chary KVR, Prasad R (2002) Vapour phase methylation of pyridine with methanol over the Zn1–x Mn x Fe2O4 (x = 0, 0.25, 0.50, 0.75 and 1) ferrite system. Green Chem 4:558–561. doi: 10.1039/b207410a10.1039/B207410A ↗
38. Smith J, Wijn HPJ (1959) Ferrites: physical properties of ferromagnetic oxides in relation to their technical applications. Wiley, New York
39. Upadhyay C, Verma HC, Sathe V, Pimpale AV (2007) Effect of size and synthesis route on the magnetic properties of chemically prepared nanosize ZnFe2O4. J Magn Magn Mater 312:271–279. doi: 10.1016/j.jmmm.2006.10.44810.1016/j.jmmm.2006.10.448 ↗
40. Viswanathan B, Murthy VRK (1990) Ferrite materials: science and technology. Springer-Verlag, Berlin and Heidelberg, GmbH & Co. KG
41. Wagner KW (1914) Arch Elektrotechn 2:37110.1007/BF01657322 ↗
42. Wejrzanowski T, Pielaszek R, Opalińska A, Matysiak H, Lojkowski W, Kurzydlowski KJ (2006) Quantitative methods for nanopowders characterization. Appl Surf Sci 253:204–208. doi: 10.1016/j.apsusc.2006.05.08910.1016/j.apsusc.2006.05.089 ↗
43. Xiaotun Y, Lingge X, Choon NS, Hardy CS (2003) Magnetic and electrical properties of polypyrrole-coated γ-Fe2O3 nanocomposite particles. Nanotechnology 14:624–629. doi: 10.1088/0957-4484/14/6/31110.1088/0957-4484/14/6/311 ↗
44. Zhang ZJ, Chen XY, Wang BN, Shi CW (2008) Hydrothermal synthesis and self-assembly of magnetite (Fe3O4) nanoparticles with the magnetic and electrochemical properties. J Cryst Growth 310:5453–5457. doi: 10.1016/j.jcrysgro.2008.08.06410.1016/j.jcrysgro.2008.08.064 ↗
45. Zhou B, Zhang YW, Liao CS, Yan CH (2002) Magnetism and phase transition for CoFe2−x Mn x O4 nanocrystalline thin films and powders. J Magn Magn Mater 247:70–76. doi: 10.1016/S0304-8853(02)00150-610.1016/S0304-8853(02)00150-6 ↗
46. Zhou L, Cui Y, Hua Y, Yu L, Jin W, Feng S (2006) The magnetic properties of Ni0.7Mn0.3Gd x Fe2−x O4 ferrite. Mater Lett 60:104–108. doi: 10.1016/j.matlet.2005.07.08310.1016/j.matlet.2005.07.083 ↗