journal article·2016-01Open access

Morphology evolution of gold nanoparticles as function of time, temperature, and Au(III)/sodium ascorbate molar ratio

Ornella Priolisi, Alberto Fabrizi, Giovanna Deon, Franco Bonollo, Stefano Cattini

Journal of Nanoparticle Research· Volume 18· Issue 1

Abstract

In this work the morphology evolution of Au nanoparticles (AuNPs), obtained by direct reduction, was studied as a function of time, temperature, and Au(III)/sodium ascorbate molar ratio. The NPs morphology was examined by transmission electron microscope with image analysis, while time evolution was investigated by visible and near-infrared absorption spectroscopy and dynamic light scattering. It is found that initially formed star-like NPs transform in more spheroidal particles and the evolution appears more rapid by increasing the temperature while a large amount of reducing agent prevents the remodeling of AuNPs. An explication of morphology evolution is proposed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Nanoparticles: synthesis and applications · Laser-Ablation Synthesis of Nanoparticles

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (65)

Show source-provided references
1. Alivisatos AP (1996) Semiconductor clusters nanocrystals and quantum dots. Science 271:933–93710.1126/science.271.5251.933 ↗
2. Astruc D (2008) Nanoparticles and catalysis. Wiley-VCH, Germany
3. Bedeaux D, Vlieger J (1974) A statistical theory of the dielectric properties of thin island films. I-The surface material coefficients. Physica 73:287–31110.1016/0031-8914(74)90002-0 ↗
4. Bedeaux D, Vlieger J (1983) A statistical theory for the dielectric properties of thin island films - Application and comparison with experimental results. Thin Solid Films 102:265–28110.1016/0040-6090(83)90094-9 ↗
5. Bohren CF, Huffman DR (1983) Absorption and scattering of light by small particles. Wiley-VCH, Weinheim
6. Casu A, Cabrini E, Donà A, Falqui A, Diaz-Fernandez Y, Milanese C, Taglietti A, Pallavicini P (2012) Controlled synthesis of gold nanostars by using a zwitterionic surfactant. Chem Eur J 18:9381–939010.1002/chem.201201024 ↗
7. Chen S, Wang ZL, Ballato J, Foulger SH, Carroll DL (2003) Monopod, bipod, tripod and tetrapod gold nanocrystals. J Am Chem Soc 125:16186–1618710.1021/ja038927x ↗
8. Clippe P, Evrard R, Lucas AA (1976) Aggregation effect on the infrared absorption spectrum of small ionic crystals. Phys Rev B 14:1715–172110.1103/PhysRevB.14.1715 ↗
9. Compton OC, Osterloh FE (2007) Evolution of size and shape in the colloidal crystallization of gold nanoparticles. J Am Chem Soc 129:7793–779810.1021/ja069033q ↗
10. Daniel MC, Astruc D (2004) Gold nanoparticles: assembly supramolecular chemistry quantum-size-related properties and applications toward biology catalysis and nanotechnology. Chem Rev 104:293–34610.1021/cr030698+ ↗
11. Dıez Orrite S, Stoll S, Schurtenberger P (2005) Off-lattice Monte Carlo simulations of irreversible and reversible aggregation processes. Soft Matter 1:364–37110.1039/b510449a ↗
12. Dumur F, Guerlin A, Dumas E, Bertin D, Gigmes D, Mayer CR (2011) Controlled spontaneous generation of gold nanoparticles assisted by dual reducing and capping agents. Gold Bull 44:119–13710.1007/s13404-011-0018-5 ↗
13. Garnett JCM (1904) Colours in metal glasses and in metallic films. Philos Trans R Soc 203:385–42010.1098/rsta.1904.0024 ↗
14. Ghosh SK, Pal T (2007) Interparticle coupling effect on the surface plasmon resonance of gold nanoparticles: from theory to applications. Chem Rev 107:4797–486210.1021/cr0680282 ↗
15. Gorshkov V, Zavalov A, Privman V (2009) Shape selection in diffusive growth of colloids and nanoparticles. Langmuir 25:7940–795310.1021/la900613p ↗
16. Goia DV, Matijević E (1999) Tailoring the particle size of monodispersed colloidal gold. Colloid Surf A 146:139–15210.1016/S0927-7757(98)00790-0 ↗
17. Guerrero-Martínez A, Barbosa S, Pastoriza-Santos I, Liz-Marzán LM (2011) Nanostars shine bright for you: colloidal synthesis properties and applications of branched metallic nanoparticles. Curr Opin Colloid Interface Sci 16:118–12710.1016/j.cocis.2010.12.007 ↗
18. Haiss W, Thanh NTK, Aveyard J, Ferning DG (2007) Determination of size and concentration of gold nanoparticles from UV–Vis spectra. Anal Chem 79:4215–422110.1021/ac0702084 ↗
19. Hayat MA (1991) Colloidal gold: principles, methods and applications. Academic Press, San Diego
20. Henry AI, Bingham JM, Ringe E, Marks LD, Schatz GC, Van Duyne RP (2011) Correlated structure and optical property studies of plasmonic nanoparticles. J Phys Chem C 115:9291–930510.1021/jp2010309 ↗
21. Hofmeister H (2009) Shape variations and anisotropic growth of multiply twinned nanoparticles. Z Kristallogr 224:528–53810.1524/zkri.2009.1034 ↗
22. Hornyak G, Moore JJ, Tibbals HF, Dutta J (2009) Fundamentals of nanotechnology. CRC Press, Florida
23. Kelly KL, Coronado E, Zhao LL, Schatz GC (2003) The optical properties of metal nanoparticles: the influence of size shape and dielectric environment. J Phys Chem B 107:668–67710.1021/jp026731y ↗
24. Kimling J, Maier M, Okenve B, Kotaidis V, Ballot H, Plech A (2006) Turkevich method for gold nanoparticle synthesis revisited. J Phys Chem B 110:15700–1570710.1021/jp061667w ↗
25. Kreibig U, Vollmer M (1995) Optical properties of metal cluster. Springer, Heidelberg10.1007/978-3-662-09109-8 ↗
26. Kumar PS, Pastoriza-Santos I, Rodrıguez-Gonzalez B, Garcıa de Abajo FJ, Liz-Marzan LM (2008) High-yield synthesis and optical response of gold nanostars. Nanotechnology 19:015606–01561210.1088/0957-4484/19/01/015606 ↗
27. LaMer VK, Dinegar RH (1950) Theory production and mechanism of formation of monodispersed hydrosols. J Am Chem Soc 72:4847–485410.1021/ja01167a001 ↗
28. Link S, El-Sayed MA (1999) Size and temperature dependence of the plasmon absorption of colloidal gold nanoparticles. J Phys Chem B 103:4212–421710.1021/jp984796o ↗
29. Louis C, Pluchery O (2012) Gold nanoparticles for physics, chemistry and biology. Imperial College Press, London10.1142/p815 ↗
30. Lu X, Rycenga M, Skrabalak SE, Wiley B, Xia Y (2009) Chemical synthesis of novel plasmonic nanoparticles. Annu Rev Phys Chem 60:167–19210.1146/annurev.physchem.040808.090434 ↗
31. Luty-Błocho M, Pacławski K, Wojnicki M, Fitzner K (2013) The kinetics of redox reaction of gold(III) chloride complex ions with L-ascorbic acid. Inorg Chim Acta 395:189–19610.1016/j.ica.2012.10.031 ↗
32. Marqusee JA, Ross J (1983) Kinetics of phase transitions: theory of Ostwald ripening. J Chem Phys 79:373–37810.1063/1.445532 ↗
33. Marqusee JA, Ross J (1984) Theory of Ostwald ripening: competitive growth and its dependence on volume fraction. J Chem Phys 80:536–54310.1063/1.446427 ↗
34. Mayergoyz ID (2013) Plasmon resonances in nanoparticles. World Scientific Publishing Co, Singapore10.1142/8158 ↗
35. Mazzucco S, Stéphan O, Colliex C, Pastoriza-Santos I, Liz-Marzán LM, García de Abajo J, Kociak M (2011) Spatially resolved measurements of plasmonic eigenstates in complex-shaped asymmetric nanoparticles: gold nanostars. Eur Phys J Appl Phys 54:3351210.1051/epjap/2011100443 ↗
36. McClurg RB (2002) Nucleation rate and primary particle size distribution. J Chem Phys 117:5328–533610.1063/1.1496478 ↗
37. Murphy CJ, Sau TK, Gole AM, Orendorff CJ, Gao J, Gou L, Hunyadi SE, Li TJ (2005) Anisotropic metal nanoparticles: synthesis assembly and optical applications. J Phys Chem B 109:13857–1387010.1021/jp0516846 ↗
38. Pallavicini P, Chirico G, Collini M, Dacarro G, Donà A, D’Alfonso L, Falqui A, Diaz-Fernandez Y, Freddi S, Garofalo B et al (2011) Synthesis of branched Au nanoparticles with tunable near-infrared LSPR using a zwitterionic surfactant. Chem Commun 47:1315–131710.1039/C0CC02682D ↗
39. Pallavicini P, Donà A, Casu A, Chirico G, Collini M, Dacarro G, Falqui A, Milanese C, Sironi L, Taglietti A (2013) Triton X-100 for three-plasmon gold nanostars with two photothermally active NIR (near IR) and SWIR (short-wavelength IR) channels. Chem Commun 49:6265–626710.1039/c3cc42999g ↗
40. Park J, Privman V, Matijevic E (2001) Model of formation of monodispersed colloids. J Phys Chem B 105:11630–1163510.1021/jp011306a ↗
41. Patala S, Marks LD, Olvera de la Cruz M (2013) Thermodynamic analysis of multiply-twinned particles: surface stress effects. J Phys Chem Lett 4:3089–309410.1021/jz401496d ↗
42. Pong BK, Elim HI, Chong JX, Ji W, Trout BL, Lee JY (2007) New insights on the nanoparticle growth mechanism in the citrate reduction of gold(III) salt: formation of the Au nanowire intermediate and its nonlinear optical properties. J Phys Chem C 111:6281–628710.1021/jp068666o ↗
43. Privman V, Goia DV, Park J, Matijevic E (1999) Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors. J Colloid Interface Sci 213:36–4510.1006/jcis.1999.6106 ↗
44. Richards V (2010) Nucleation control in size and dispersity in metallic nanoparticles: the prominent role of particle aggregation. Dissertation: Washington University
45. Ringe E, Langille MR, Sohn K, Zhang J, Huang JX, Mirkin CA, Van Duyne RP, Marks LD (2012) Plasmon length: a universal parameter to describe size effects in gold nanoparticles. J Phys Chem Lett 3:1479–148310.1021/jz300426p ↗
46. Robb DT, Privman V (2008) Model of nanocrystal formation in solution by burst nucleation and diffusional growth. Langmuir 24:26–3510.1021/la702097g ↗
47. Robb DT, Halaciuga I, Privman V, Goia DV (2008) Computational model for the formation of uniform silver spheres by aggregation of nanosize precursors. J Chem Phys 129:184705–18471110.1063/1.3009625 ↗
48. Romero I, Aizpurua J, Bryant GW, García de Abajo FJ (2006) Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers. Opt Express 14:9988–999910.1364/OE.14.009988 ↗
49. Sarid D, Challener WA (2009) Modern introduction to surface plasmons. Cambridge University Press, Cambridge
50. Schoenauer D, Kreibig U (1985) Topography of samples with variably aggregated metal particles. Surf Sci 156:100–11110.1016/0039-6028(85)90562-X ↗
51. Shore JD, Perchak D, Shnidman Y (2000) Simulations of the nucleation of AgBr from solution. J Chem Phys 113:6276–628410.1063/1.1308517 ↗
52. Sperling RA, Rivera GP, Zhang F, Zanella M, Parak WJ (2008) Biological applications of gold nanoparticles. Chem Soc Rev 37:1896–190810.1039/b712170a ↗
53. Stathis EC, Fabrikanos A (1958) Preparation of colloidal gold. Chem Ind 27:860–861
54. Streszewskia B, Jaworski W, Pacławski K, Csapo E, Dekany I, Fitzner K (2012) Gold nanoparticles formation in the aqueous system of gold(III) chloride complex ions and hydrazine sulfate—kinetic studies. Colloids Surf A 397:63–7210.1016/j.colsurfa.2012.01.031 ↗
55. Turkevich J (1985a) Colloidal gold. Part I. Gold Bull 18:86–9110.1007/BF03214690 ↗
56. Turkevich J (1985b) Colloidal gold. Part II. Gold Bull 18:125–13110.1007/BF03214694 ↗
57. Turkevich J, Stevenson PC, Hillier J (1951) A study of the nucleation and growth process in the synthesis of colloidal gold. Discuss Faraday Soc 11:55–7510.1039/df9511100055 ↗
58. Turkevich J, Stevenson PC, Hillier J (1953) The formation of colloidal gold. J Phys Chem 57:670–67310.1021/j150508a015 ↗
59. Van de Broek B, Grandjean D, Trekker J, Ye J, Verstreken K, Maes G, Borghs G, Nikitenko S, Lagae L, Bartic C, Temst K et al (2011) Temperature determination of resonantly excited plasmonic branched gold nanoparticles by X-ray absorption spectroscopy. Small 7:2498–250610.1002/smll.201100089 ↗
60. Vlieger J, Bedeaux D (1985) A statistical theory for the dielectric properties of thin island films: application and comparison with experimental results. Thin Solid Films 102:265–281
61. Voorhees PW (1985) The theory of Ostwald ripening. J Stat Phys 38:231–25210.1007/BF01017860 ↗
62. Voorhees PW, Glicksman ME (1984) Solution to the multi-particle diffusion problem with applications to Ostwald ripening—I theory. Acta Metall 32:2001–201110.1016/0001-6160(84)90180-9 ↗
63. Watzky MA, Finke RG (1997) Transition metal nanocluster formation kinetic and mechanistic studies. A new mechanism when hydrogen is the reductant: slow continuous nucleation and fast autocatalytic surface growth. J Am Chem Soc 119:10382–1040010.1021/ja9705102 ↗
64. Xia Y, Xiong Y, Lim Skrabalak SE (2009) Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew Chem Int Ed Eng 48:60–10310.1002/anie.200802248 ↗
65. Zumreoglu-Karan J (2009) A rationale on the role of intermediate Au(III)–vitamin C complexation in the production of gold nanoparticles. J Nanopart Res 11:1099–110510.1007/s11051-008-9498-5 ↗