journal article·2015-03Open access

Is orthorhombic iron tetraboride superhard?

Qianqian Wang, Julong He, Wentao Hu, Zhisheng Zhao, Chao Zhang, Kun Luo, Yifei Lü, Chunxue Hao, Weiming Lü, Zhongyuan Liu, Dongli Yu, Yongjun Tian, Bo Xu

Journal of Materiomics· Volume 1· Issue 1

Abstract

Millimeter-sized FeB4 bulks were synthesized under high pressure of 15 GPa and 1600 °C. Multiple analysis methodologies including XRD, SEM, TEM, and Raman spectroscopy verified this new phase with an oP10 crystal structure. A relatively low hardness of 15.4 GPa, which is consistent with hardness estimated from both macroscopic and microscopic hardness models, excludes FeB4 as a superhard material. Magnetization and resistance measurements do not indicate superconductivity in FeB4 for temperature as low as 2.5 K. Previously reported superconductivity in FeB4 needs a further investigation, especially for structural imperfections, unidentified phases, and/or contaminations.
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Research context

OpenAlex topics: Boron and Carbon Nanomaterials Research · Rare-earth and actinide compounds · Metal and Thin Film Mechanics

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