journal article·2016-06Open access

Enhanced thermoelectric performance of MnTe via Cu doping with optimized carrier concentration

Yangyang Ren, Qinghui Jiang, Junyou Yang, Yubo Luo, Dan Zhang, Yudong Cheng, Zhiwei Zhou

Journal of Materiomics· Volume 2· Issue 2

Abstract

Polycrystalline Mn1-xCuxTe (x = 0, 0.025, 0.05, 0.075) thermoelectric materials were prepared by a combined method of melt-quenching and hot press. The effect of Cu doping on the electrical resistivity, band gap, the Seebeck coefficient and thermal conductivity was investigated. The power factors of the Cu-doped samples increase greatly due to the decrease of electrical resistivity and the higher Seebeck coefficient in high temperatures. In addition, the thermal conductivities of the Cu-doped samples also reduce due to the extra phonon scattering from the point defects introduced by Cu doping. As a result, the thermoelectric performance of MnTe is greatly enhanced, and a maximum ZT value of ∼0.55 in the Mn0.925Cu0.075Te sample at 773 K is achieved, which is 35% greater than that of the pristine MnTe sample.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Chalcogenide Semiconductor Thin Films · Heusler alloys: electronic and magnetic properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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