Cephalopod-inspired soft composite with liquid metal inclusions for tunable infrared modulation
Source abstract
Abstract
Artificial adaptive soft infrared (IR) materials, mimicking the color-changing abilities observed in soft organisms such as cephalopods, hold significant promise in various emerging technologies, including unconventional flexible displays, intelligent camouflage systems, and advanced sensors. In this study, we integrated inherently deformable liquid metal (LM) microdroplets randomly into an elastomer matrix, creating a fully soft material that exhibits elastic compliance akin to soft biological tissue and adaptive IR-reflecting properties in response to compression. Under compressive strains, each LM inclusion behaves as a unit of dynamic IR reflector, transitioning between a contracted droplet with a corrugated surface and an expanded plate-like filler with a relatively smooth surface. These alterations in shape, size, and surface structure allow dynamic modulation of incident IR radiation’s reflection, resulting in reversible changes in IR color ( i.e. , detected temperature). This mechanism replicates the dynamic alterations observed in cephalopod skin, where chromatophores dynamically manipulate visible light reflection by changing their size and morphology. We demonstrate proof-of-concept applications of this material, showing its ability to modify IR appearance through compression for visualization, with its localized color-change mechanism enabling its use as a tactile sensor in vision-based tactile grippers. These illustrate the potential of this material in emerging adaptive flexible electronics. • Present an entirely soft composite with compression-tuned IR reflectance. • Compression-induced changes in LM morphologies are responsible for the dynamic IR reflection. • The composite can dynamically change its IR appearance.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Thermal Radiation and Cooling Technologies · Infrared Target Detection Methodologies · Transition Metal Oxide Nanomaterials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (62)
Show source-provided references
1. Adaptive infrared-reflecting systems inspired by cephalopods10.1126/science.aar5191 ↗
2. Manipulating metals for adaptive thermal camouflage10.1126/sciadv.aba3494 ↗
3. Dynamic gating of infrared radiation in a textile10.1126/science.aau1217 ↗
4. Smart materials for dynamic thermal radiation regulation10.1002/smll.202100446 ↗
5. Thermo-optically designed scalable photonic films with high thermal conductivity for subambient and above-ambient radiative cooling
6. Shape memory active thermal-moisture management textiles10.1016/j.compositesa.2022.107037 ↗
7. Thermal camouflaging metamaterials10.1016/j.mattod.2020.11.013 ↗
8. High-temperature infrared camouflage with efficient thermal management10.1038/s41377-020-0300-5 ↗
9. Camouflage and display for soft machines10.1126/science.1222149 ↗
10. Dynamic camouflage characteristics of a thermal infrared film inspired by honeycomb structure10.1007/s42235-021-00141-5 ↗
11. Thermally controlled, active imperceptible artificial skin in visible-to-infrared range10.1002/adfm.202003328 ↗
12. An adaptive and wearable thermal camouflage device10.1002/adfm.201909788 ↗
13. Fast adaptive thermal camouflage based on flexible VO2/Graphene/CNT thin films10.1021/acs.nanolett.5b04090 ↗
14. Thermal camouflage based on the phase-changing material GST10.1038/s41377-018-0038-5 ↗
15. Multi-stimulus perception and visualization by an intelligent liquid metal-elastomer architecture10.1126/sciadv.adp5215 ↗
16. Li4Ti5O12: a visible-to-infrared broadband electrochromic material for optical and thermal management10.1002/adfm.201802180 ↗
17. Preparation and performances of all-solid-state variable infrared emittance devices based on amorphous and crystalline WO3 electrochromic thin films10.1016/j.solmat.2019.109916 ↗
18. Multispectral graphene-based electro-optical surfaces with reversible tunability from visible to microwave wavelengths10.1038/s41566-021-00791-1 ↗
19. Large-scale multifunctional carbon nanotube thin film as effective mid-infrared radiation modulator with long-term stability10.1002/adom.202001216 ↗
20. Flexible mid-infrared radiation modulator with multilayer graphene thin film by ionic liquid gating10.1021/acsami.8b21900 ↗
21. A bistable variable infrared rmissivity device based on reversible silver electrodeposition10.1002/adfm.202202661 ↗
22. Nonvolatile optically reconfigurable radiative metasurface with visible tunability for anticounterfeiting10.1021/acs.nanolett.1c01396 ↗
23. Hybrid graphene metasurfaces for high-speed mid-infrared light modulation and single-pixel imaging10.1038/s41377-018-0055-4 ↗
24. Tuneable thermal emission using chalcogenide metasurface10.1002/adom.201800169 ↗
25. Ultrathin titanium carbide (MXene) films for high-temperature thermal camouflage10.1002/adfm.202101381 ↗
26. Thermal camouflaging MXene robotic skin with bio-Inspired stimulus sensation and wireless communication10.1002/adfm.202110534 ↗
27. Dynamic thermal radiation modulators via mechanically tunable surface emissivity10.1016/j.mattod.2020.12.001 ↗
28. Spatial and temporal modulation of thermal emission10.1002/adma.201701275 ↗
29. Reconfigurable room temperature metamaterial infrared emitter10.1364/OPTICA.4.000430 ↗
30. Controlling silk fibroin conformation for dynamic, responsive, multifunctional, micropatterned surfaces10.1073/pnas.1911563116 ↗
31. A triple-mode midinfrared modulator for radiative heat management of objects with various rmissivity10.1021/acs.nanolett.1c01147 ↗
32. A dynamic mechanical stimulated and thermal-healed infrared modulator based on elastomer matrix with metal layer inspired by squid skin
33. A dynamic thermoregulatory material inspired by squid skin10.1038/s41467-019-09589-w ↗
34. Stretchable cephalopod-inspired multimodal camouflage systems10.1002/adma.201905717 ↗
35. Cephalopod-inspired polymer composites with mechanically tunable infrared properties10.1016/j.scib.2023.10.039 ↗
36. Chameleon-inspired tunable multi-layered infrared-modulating system via stretchable liquid metal microdroplets in elastomer film10.1038/s41467-024-49849-y ↗
37. The structure-function relationships of a natural nanoscale photonic device in cuttlefish chromatophores10.1098/rsif.2013.0942 ↗
38. Natural light-scattering nanoparticles enable visible through short-wave infrared color modulation
39. Highly stretchable polymer composite with strain-enhanced electromagnetic interference shielding effectiveness10.1002/adma.201907499 ↗
40. B · 1968
41. Silver nanowires for anti-counterfeiting10.1016/j.jmat.2020.01.008 ↗
42. Surface optics and color effects of liquid metal materials10.1002/adma.202210515 ↗
43. Ultrasensitive, highly stable, and stretchable strain sensor using gated liquid metal channel10.1002/adfm.202314298 ↗
44. Flexible bioelectronics for physiological signals sensing and disease treatment10.1016/j.jmat.2019.12.005 ↗
45. Precise regulation of Ga-based liquid metal oxidation10.1021/accountsmr.1c00173 ↗
46. A liquid metal reaction environment for the room-temperature synthesis of atomically thin metal oxides10.1126/science.aao4249 ↗
47. A novel strategy of fabricated flexible ITO electrode by liquid metal ultra-thin oxide film10.1016/j.jmat.2022.05.006 ↗
48. Pressure-activated thermal transport via oxide shell rupture in liquid metal capsule beds10.1021/acsami.9b17358 ↗
49. Surface tension of the oxide skin of gallium-based liquid metals10.1021/acs.langmuir.1c00966 ↗
50. Bioadhesive ultrasound for long-term continuous imaging of diverse organs10.1126/science.abo2542 ↗
51. Mechanical behaviour of skin: a review
52. High thermal conductivity in soft elastomers with elongated liquid metal inclusions10.1073/pnas.1616377114 ↗
53. Hydrogen-doped viscoplastic liquid metal microparticles for stretchable printed metal lines10.1038/s41563-020-00863-7 ↗
54. Deformability of thin metal films on elastomer substrates10.1016/j.ijsolstr.2005.04.034 ↗
55. Biaxially stretchable “wavy” silicon nanomembranes10.1021/nl0706244 ↗
56. A stretchable form of single-crystal silicon for high-performance electronics on rubber substrates10.1126/science.1121401 ↗
57. Highly stretchable wrinkled gold thin film wires10.1063/1.4941439 ↗
58. Transferred wrinkled Al2O3 for highly stretchable and transparent graphene-carbon nanotube transistors10.1038/nmat3572 ↗
59. Effects of particle size and oxide shell on variable stiffness performance of phase-changing materials10.1177/00219983221129252 ↗
60. Ultra-conformable liquid metal particle monolayer on air/water interface for substrate-free E-tattoo10.1038/s41528-023-00263-2 ↗
61. The emissivity of transparent materials10.1111/j.1151-2916.1956.tb15833.x ↗
62. Visualizing unleashed latent heat of liquid metal for soft intelligence10.1007/s11708-024-0951-7 ↗