Copper(II) complex anchored on magnetic chitosan functionalized trichlorotriazine: An efficient heterogeneous catalyst for the synthesis of tetrazole derivatives
Source abstract
Abstract
Abstract In this work, a method has been developed for the synthesis of magnetic chitosan functionalized trichlorotriazine-5-amino-1H-tetrazole copper(II) complex (Fe3O4@CS-TCT-Tet-Cu(II)). The synthesized Fe3O4@CS-TCT-Tet-Cu(II) was characterized using XRD, EDS, elemental mapping, STEM, FT-IR, TG/DTA, FFT, ICP-MS, and TEM analyses. Fe3O4@CS-TCT-Tet-Cu(II) was then applied in the synthesis of N-sulfonyl-N-aryl tetrazoles and 5-arylamino-1H-tetrazoles via the reaction of sodium azide with N-sulfonyl-N-arylcyanamides and arylcyanamides, respectively in DMF solvent. The synthesized Fe3O4@CS-TCT-Tet-Cu(II) can be recycled and reused for five cycles with no considerable loss of catalytic performance.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Synthesis of Tetrazole Derivatives · Synthesis and Characterization of Heterocyclic Compounds · Multicomponent Synthesis of Heterocycles
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. A recyclable AgI/OAc− catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure10.1039/C7GC00276A ↗
2. An eco-friendly catalytic system for one-pot multicomponent synthesis of diverse and densely functionalized pyranopyrazole and benzochromene derivatives10.1002/jhet.3564 ↗
3. Synthesis of antioxidant for natural rubber using new heterogeneous catalytic system10.1007/s11696-019-00851-5 ↗
4. Titanium-based nanoparticles: a novel, facile and efficient catalytic system for one-pot synthesis of quinoline derivatives10.1016/j.cdc.2018.08.001 ↗
5. Scope and challenge of computational methods for studying mechanism and reactivity in homogeneous catalysis10.1021/acscatal.9b01537 ↗
6. Heterogeneous catalysis: a central science for a sustainable future10.1021/acs.accounts.6b00510 ↗
7. Heterogeneous catalysis on metal oxides10.3390/catal7110341 ↗
8. Development and functionalization of magnetic nanoparticles as powerful and green catalysts for organic synthesis
9. Mn modified Ni/bentonite for CO2 methanation10.3390/catal8120646 ↗
10. Prompt removal of antibiotic by adsorption/electro-Fenton degradation using an iron-doped perlite as heterogeneous catalyst10.1016/j.psep.2020.07.021 ↗
11. Polystyrene supported zinc complex as an efficient catalyst for cyclic carbonate formation via CO2 fixation under atmospheric pressure and organic carbamates production
12. Palladium coordination biopolymer: a versatile access to highly porous dispersed catalyst for Suzuki reaction10.1021/cm8020337 ↗
13. Magnetic nanomaterials in catalysis: advanced catalysts for magnetic separation and beyond10.1039/c4gc00164h ↗
14. Supported molybdenum on graphene oxide/Fe3O4: An efficient, magnetically separable catalyst for one-pot construction of spiro-oxindole dihydropyridines in deep eutectic solvent under microwave irradiation10.1016/j.catcom.2016.09.028 ↗
15. A magnetic metal organic framework material as a highly efficient and recyclable catalyst for synthesis of cyclohexenone derivatives10.1016/j.jcat.2020.04.013 ↗
16. Magnetic nanocatalysts: synthesis and application in multicomponent reactions10.1016/j.cogsc.2018.08.009 ↗
17. Starch, cellulose, pectin, gum, alginate, chitin and chitosan derived (nano) materials for sustainable water treatment: a review
18. The use of chitosan-based metal catalysts in organic transformations10.1016/j.ccr.2019.02.018 ↗
19. Chitosan as an environment friendly biomaterial–a review on recent modifications and applications10.1016/j.ijbiomac.2019.10.113 ↗
20. Antimicrobial chitosan and chitosan derivatives: a review of the structure-activity relationship10.1021/acs.biomac.7b01058 ↗
21. Synthesis and characterization of novel cu(II) complex coated Fe3O4@SiO2 nanoparticles for catalytic performance10.1016/j.molstruc.2018.02.026 ↗
22. 5-substituted-1H-tetrazoles as carboxylic acid isosteres: medicinal chemistry and synthetic methods10.1016/S0968-0896(02)00239-0 ↗
23. Synthesis of 5-arylamino-1H (2H)-tetrazoles and 5-amino-1-aryl-1H-tetrazoles from secondary arylcyanamides in glacial acetic acid: a simple and efficient method
24. Dynamic 1H NMR spectroscopic study of the restricted SN rotation in aryl-N-(arylsulfonyl)-N-(triphenylphosphoranylidene) imidocarbamates10.1016/j.molstruc.2006.11.058 ↗
25. Magnetic chitosan-copper nanocomposite: a plant assembled catalyst for the synthesis of amino-and N-sulfonyl tetrazoles in eco-friendly media10.1016/j.carbpol.2019.115819 ↗
26. In situ green synthesis of cu-Ni bimetallic nanoparticles supported on reduced graphene oxide as an effective and recyclable catalyst for the synthesis of N-benzyl-N-aryl-5-amino-1H-tetrazoles10.1002/aoc.4938 ↗
27. The synthesis of aminoiminoethanenitriles, 5-aminotetrazoles, N-cyanoguanidines, and N-hydroxyguanidines from aminoiminomethanesulfonic acids10.1080/00397919008052286 ↗
28. Solid-phase synthesis of 5-aminotetrazoles10.1016/j.tetlet.2004.07.160 ↗
29. Synthesis of 5-N-substituted tetrazole derivatives of the potent NK1 receptor antagonist GR20304010.1055/s-1996-5420 ↗
30. One-pot syntheses of 5-amino-1-aryltetrazole derivatives10.1055/s-2006-926403 ↗
31. Efficient synthesis of arylaminotetrazoles in water10.1016/j.tet.2010.03.003 ↗
32. Preparation of a stable and robust nanobiocatalyst by efficiently immobilizing of pectinase onto cyanuric chloride-functionalized chitosan grafted magnetic nanoparticles10.1016/j.jcis.2018.10.053 ↗
33. Ultrasound-assisted fabrication of N-cyano-N-arylbenzenesulfonamides at ambient temperature: improvements with biosynthesized Ag/feldspar nanocomposite10.1007/s10098-019-01779-w ↗
34. Synthesis of novel N-aryl-N-(1H-tetrazol-5-yl) benzenesulfonamides in water10.1002/aoc.5706 ↗
35. Triazoles and tetrazoles: prime ligands to generate remarkable coordination materials10.1016/j.ccr.2010.10.038 ↗
36. Crystal structure and physical properties of the new 2D polymeric compound bis(1,5-diaminotetrazole)dichlorocopper(II)10.1016/j.ica.2005.03.005 ↗
37. Synthesis and characterisation of new ditetrazole-ligands as more rigid building blocks of envisaged iron(II) spin-crossover coordination polymers10.1016/j.molstruc.2005.02.007 ↗
38. A new family of spin-crossover complexes based on a FeII(Tetrazolyl)4(MeCN)2-type core10.1021/ic8002993 ↗
39. A new route to N(1)-5R-tetrazole complexes via azidation to nitriles coordinated to Pt(II) and Pt(IV)10.1016/j.ica.2011.05.011 ↗
40. Cu(II) coordination polymers with nitrogen catenation ligands for efficient photocatalytic water oxidation10.1039/C8CC02359J ↗
41. Copper(II) and cobalt(II) tetrazole-saccharinate complexes as effective catalysts for oxidation of secondary alcohols10.1016/j.molcata.2016.10.023 ↗
42. Targeted water soluble copper-tetrazolate complexes: interactions with biomolecules and catecholase like activities10.1039/C5DT01471A ↗
43. Anisotropic shaped Fe3O4 nanoparticles: microwave-assisted thermal decomposition synthesis and their electromagnetic properties10.1063/5.0013782 ↗