Oxidation Protection of High-Temperature Coatings on the Surface of Mo-Based Alloys—A Review
Source abstract
Abstract
Molybdenum and its alloys, with high melting points, excellent corrosion resistance and high temperature creep resistance, are a vital high-temperature structural material. However, the poor oxidation resistance at high temperatures is a major barrier to their application. This work provides a summary of surface modification techniques for Mo and its alloys under high-temperature aerobic conditions of nearly half a century, including slurry sintering technology, plasma spraying technology, chemical vapor deposition technology, and liquid phase deposition technology. The microstructure and oxidation behavior of various coatings were analyzed. The advantages and disadvantages of various processes were compared, and the key measures to improve oxidation resistance of coatings were also outlined. The future research direction in this field is set out.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: High-Temperature Coating Behaviors · Advanced materials and composites · Metal and Thin Film Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Metallurgical Engineering, Anhui University of Technology, Maanshan 243002, China
Funding
Anhui Province Science Foundation for Excellent Young Scholars · National Natural Science Foundation of China
References (91)
Show source-provided references
1. Hot deformation behaviour of Mo-TZM and understanding the restoration processes involved10.1016/j.actamat.2018.10.037 ↗
2. Production and characterization of TZM based TiC or ZrC reinforced composites prepared by spark plasma sintering (SPS)10.1016/j.jallcom.2018.11.383 ↗
3. Critical Assessment 4: Challenges in developing high temperature materials10.1179/1743284714Y.0000000580 ↗
4. A study on preparation of Mo–30W alloy by aluminothermic co-reduction of mixed oxides10.1016/j.jallcom.2004.10.053 ↗
5. Ultra-high temperature oxidation behavior of micro-laminated ZrC/MoSi2 coating on C/C composite10.1016/j.corsci.2017.12.034 ↗
6. Comparison of two types of plasma in contact with water during the formation of molybdenum oxide10.1016/j.cap.2020.09.012 ↗
7. Reductive-annealing-induced changes in Mo valence states on the surfaces of MoO3 single crystals and their high temperature transport10.1016/j.cap.2019.09.001 ↗
8. Oxidation state of Mo affects dissolution and visible-light photocatalytic activity of MoO3 nanostructures10.1016/j.jcat.2019.11.035 ↗
9. Oxidation and volatilization of TZM alloy in air10.1016/S0022-3115(00)00303-2 ↗
10. A study of hot deformation behavior and microstructural characterization of Mo–TZM alloy10.1016/j.jnucmat.2008.12.049 ↗
11. Acid sites on silica-supported molybdenum oxides probed by ammonia adsorption: Experiment and theory
12. Structural identification of phases in Mo–Re alloys within the range from 5 to 95% Re10.1016/S0924-0136(03)00342-X ↗
13. Cui, K.K., Zhang, Y.Y., Fu, T., Hussain, S., Algarni, T.S., Wang, J., Zhang, X., and Ali, S. (2021). Effects of Cr2O3 Content on Microstructure and Mechanical Properties of Al2O3 Matrix Composites. Coatings, 11.10.3390/coatings11020234 ↗
14. Fracture resistance of hierarchical Cu–Mo nanocomposite thin films10.1016/j.msea.2020.139891 ↗
15. Influence of noble metals on the electronic and optical properties of the monoclinic ZrO2: A first-principles study10.1016/j.vacuum.2021.110112 ↗
16. The role of Re in improving the oxidation-resistance of a Re modified PtAl coating on Mo-rich single crystal superalloy10.1016/j.jmst.2020.03.054 ↗
17. Studies on growth mechanism of intermediate layer of (Mo,W)5Si3 and interdiffusion in the (Mo,W)-(Mo,W)Si2 system prepared by pack cementation coating
18. The structural, mechanical and thermodynamic properties of the orthorhombic TMAl (TM=Ti, Y, Zr and Hf) aluminides from first-principles calculations10.1016/j.vacuum.2020.109742 ↗
19. Microstructures and mechanical properties of TiC-particulate-reinforced Ti–Mo–Al intermetallic matrix composites10.1016/j.msea.2020.139523 ↗
20. Microstructure and mechanical properties of CaAl12O19 reinforced Al2O3-Cr2O3 composites10.1016/j.jeurceramsoc.2021.08.024 ↗
21. A crack-free SiC nanowire-toughened Si-Mo-W-C coating prepared on graphite materials for enhancing the oxidation resistance10.1016/j.surfcoat.2018.02.109 ↗
22. Evolution of surface morphology, roughness and texture of tungsten disilicide coatings on tungsten substrate10.1016/j.vacuum.2021.110297 ↗
23. Ab initio investigation and thermodynamic modeling of the Mo–Ti–Zr system10.1016/j.mtla.2020.100701 ↗
24. Microstructure and oxidation mechanism of multiphase Mo–Ti–Si–B alloys at 800 °C10.1016/j.corsci.2021.109518 ↗
25. CALPHAD-type modeling of the C–Hf–Mo system over the whole composition and temperature ranges10.1016/j.tca.2020.178716 ↗
26. Fu, T., Cui, K.K., Zhang, Y.Y., Wang, J., Zhang, X., Shen, F.Q., Yu, L.H., and Mao, H.B. (2021). Microstructure and Oxidation Behavior of Anti-Oxidation Coatings on Mo-Based Alloys through HAPC Process: A Review. Coatings, 11.10.3390/coatings11080883 ↗
27. Investigation on compression behavior of TZM and La2O3 doped TZM Alloys at high temperature10.1016/j.msea.2017.01.059 ↗
28. Oxidation behavior of magnetron sputtered double layer coatings containing molybdenum, silicon and boron10.1016/j.intermet.2013.09.007 ↗
29. MoSi2 coating on molybdenum using molten salt10.1016/S0925-8388(00)00792-1 ↗
30. Synthesis of molybdenum borides and molybdenum silicides in molten salts and their oxidation behavior in an air–water mixture10.1016/j.surfcoat.2004.05.021 ↗
31. Magnetron Sputtered Silicon Coatings as Oxidation Protection for Mo-Based Alloys10.1002/adem.202000218 ↗
32. Mao, H., Shen, F., Zhang, Y., Wang, J., Cui, K., Wang, H., Lv, T., Fu, T., and Tan, T. (2021). Microstructure and Mechanical Properties of Carbide Reinforced TiC-Based Ultra-High Temperature Ceramics: A Review. Coatings, 11.10.3390/coatings11121444 ↗
33. Microstructure and anti-oxidation behavior of laser clad Ni–20Cr coating on molybdenum surface10.1016/j.surfcoat.2010.08.021 ↗
34. Oxidation behavior of (Mo,W)Si2–Si3N4 composite coating on molybdenum substrate at 1600 °C10.1016/j.ceramint.2015.08.012 ↗
35. Effect of ammonia nitridation on the microstructure of MoSi2 coatings formed by chemical vapor deposition of Si on Mo substrates10.1016/S0257-8972(02)00379-1 ↗
36. Microstructure and properties of Mo-based double-layer MoSi2 thick coating by a new two-step method10.1016/j.surfcoat.2020.125840 ↗
37. Microstructure evolution and growth mechanism of Si-MoSi2 composite coatings on TZM (Mo-0.5Ti-0.1Zr-0.02 C) alloy10.1016/j.jallcom.2021.162403 ↗
38. Oxidation protection of tungsten alloys for nuclear fusion applications: A comprehensive review10.1016/j.jallcom.2021.161057 ↗
39. Invited Review Paper in Commemoration of Over 50 Years of Oxidation of Metals: Addressing the Role of Water Vapor on Long-Term Stainless Steel Oxidation Behavior10.1007/s11085-020-10012-9 ↗
40. Cui, K.K., Zhang, Y.Y., Fu, T., Wang, J., and Zhang, X. (2020). Toughening Mechanism of Mullite Matrix Composites: A Review. Coatings, 10.10.3390/coatings10070672 ↗
41. Slurry erosion–corrosion wear behavior in SiC-containing NaOH solutions of Mo2NiB2 cermets prepared by reactive sintering10.1016/j.ijrmhm.2018.09.017 ↗
42. A novel slurry blending method for a uniform dispersion of carbon nanotubes in natural rubber composites10.1016/j.rinp.2019.102720 ↗
43. MoSi2/(Mo, Ti)Si2 dual-phase composite coating for oxidation protection of molybdenum alloy10.1016/j.jallcom.2017.08.173 ↗
44. Oxidation behavior and microstructural evolution of a slurry sintered Si-Mo coating on Mo alloy at 1650 °C10.1016/j.surfcoat.2017.05.054 ↗
45. Development of Protective Coating of MoSi2 over TZM Alloy Substrate by Slurry Coating Technique10.1016/j.matpr.2016.09.022 ↗
46. Formation and oxidation resistance of a new YSZ modified silicide coating on Mo-based alloy10.1016/j.matdes.2018.06.011 ↗
47. MoSi2 coating on Mo substrate for short-term oxidation protection in air10.1016/j.jallcom.2009.07.141 ↗
48. Microstructure and mechanical properties of a MoSi2-Mo5Si3 eutectic composite processed by laser surface melting10.1016/j.matchar.2018.12.016 ↗
49. Oxidation behavior of Zr-Y alloyed Mo-Si-B based alloys10.1016/j.ijrmhm.2020.105200 ↗
50. ShafirovichE. Mechanically activated combustion synthesis of molybdenum silicides and borosilicides for ultrahigh-temperature structural applications10.1016/j.proci.2014.05.019 ↗
51. The effect of phase chemistry on the extent of strengthening mechanisms in model Ni-Cr-Al-Ti-Mo based superalloys10.1016/j.actamat.2018.04.064 ↗
52. Steam Oxidation Evaluation of Fe–Cr Alloys for Accident Tolerant Nuclear Fuel Cladding10.1007/s11085-017-9754-0 ↗
53. Formation of complex intermetallic phases in novel refractory high-entropy alloys NbMoCrTiAl and TaMoCrTiAl: Thermodynamic assessment and experimental validation
54. Development of bending tests for near shear mode interfacial toughness measurement of EB-PVD thermal barrier coatings10.1016/j.engfracmech.2016.11.009 ↗
55. Design of high lifetime suspension plasma sprayed thermal barrier coatings10.1016/j.jeurceramsoc.2019.10.061 ↗
56. Oxidation mechanisms of lanthanum-alloyed Mo–Si–B10.1016/j.corsci.2014.07.058 ↗
57. Preparation and characterization of molybdenum disilicide coating on molybdenum substrate by air plasma spraying10.1016/j.apsusc.2013.08.029 ↗
58. Microstructure and oxidation resistance of a multiphase Mo-Si-B ceramic coating on Mo substrates deposited by a plasma transferred arc process10.1016/j.ceramint.2018.09.182 ↗
59. Microstructure, properties and oxidation behavior of MoSi2-MoB-ZrO2 coating for Mo substrate using spark plasma sintering10.1016/j.surfcoat.2019.08.002 ↗
60. Studies on the development of TZM alloy by aluminothermic coreduction process and formation of protective coating over the alloy by plasma spray technique10.1016/j.ijrmhm.2011.04.010 ↗
61. A novel approach to boriding of TZM by spark plasma sintering method10.1016/j.ijrmhm.2018.10.006 ↗
62. Dense yttria-stabilized zirconia coatings fabricated by plasma spray-physical vapor deposition10.1016/j.ceramint.2016.11.014 ↗
63. Microstructure and mechanical properties of yttria stabilized zirconia coatings prepared by plasma spray physical vapor deposition10.1016/j.ceramint.2015.02.141 ↗
64. Experimental visualization of microstructure evolution during suspension plasma spraying of thermal barrier coatings10.1016/j.jeurceramsoc.2018.09.023 ↗
65. Comparative study of suspension plasma sprayed and suspension high velocity oxy-fuel sprayed YSZ thermal barrier coatings10.1016/j.surfcoat.2014.11.054 ↗
66. Investigation the effect of B 4 C addition on properties of TZM alloy prepared by spark plasma sintering10.1016/j.ijrmhm.2016.04.020 ↗
67. Porous architecture and thermal properties of thermal barrier coatings deposited by suspension plasma spray10.1016/j.surfcoat.2020.125462 ↗
68. Comparative study of the failure mechanism of atmospheric and suspension plasma sprayed thermal barrier coatings10.1016/j.surfcoat.2019.03.013 ↗
69. Effect of nitrogen on the formation and oxidation behavior of iron aluminide coatings10.1016/j.surfcoat.2005.07.081 ↗
70. Practical aspects of deposition of CVD SiC and boron silicon carbide onto high temperature composites10.1016/S0257-8972(96)03011-3 ↗
71. Formation of MoSi2–SiO2 coatings on molybdenum substrates by CVD/MOCVD10.1016/j.surfcoat.2005.02.212 ↗
72. Low-temperature cyclic oxidation behavior of MoSi2/Si3N4 nanocomposite coating formed on Mo substrate at 773 K10.1016/j.surfcoat.2005.01.035 ↗
73. Synthesis and characterization of oxidation-resistant TiB2 coating on molybdenum substrate by chemical vapor deposition10.1016/j.matlet.2018.05.080 ↗
74. Surface characterization of CVD tungsten coating on molybdenum substrate10.1016/j.surfcoat.2004.10.130 ↗
75. Low-Temperature Cyclic Oxidation Behavior of MoSi2/SiC Nanocomposite Coating Formed on Mo Substrate10.2320/matertrans.45.2435 ↗
76. Novel Mo–Si3N4 based selective coating for high temperature concentrating solar power applications10.1016/j.solmat.2013.12.005 ↗
77. Microstructures of diffusion bonded SiC ceramics using Ti and Mo interlayers10.1016/j.jnucmat.2013.07.008 ↗
78. Investigation of mechanical properties and oxidation resistance of CVD TiB2 ceramic coating on molybdenum10.1016/j.jmrt.2019.10.056 ↗
79. Graded PVD Mo-Si interlayer between Si coating and Mo-Si-B alloys: Investigation of oxidation behaviour10.1016/j.corsci.2021.109843 ↗
80. PVD thermal barrier coating systems for M-Si-B alloys10.1080/09603409.2017.1404686 ↗
81. Mechanically alloyed Mo–Si–B alloys with a continuous α-Mo matrix and improved mechanical properties10.1016/j.intermet.2008.04.015 ↗
82. Microstructure and Mechanical Properties of MoSi2 Coating Deposited on Mo Substrate by Hot Dipping Processes10.1166/jno.2019.2676 ↗
83. Synthesis WSi2 coating on W substrate by HDS method with various deposition times10.1016/j.apsusc.2020.145551 ↗
84. Effect of hot dip silicon-plating temperature on microstructure characteristics of silicide coating on tungsten substrate10.1016/j.ceramint.2019.10.270 ↗
85. Microstructure and oxidation behavior of Si–MoSi2 functionally graded coating on Mo substrate10.1016/j.ceramint.2017.02.024 ↗
86. The Characters of Mo-MoSi2 Functionally Graded Coating10.1515/htmp-2013-0046 ↗
87. Effect of hot-dip siliconizing time on phase composition and microstructure of Mo–MoSi2 high temperature structural materials10.1016/j.ceramint.2018.12.018 ↗
88. Morphology of composite coatings formed on Mo1 substrate using hot-dip aluminising and micro-arc oxidation techniques10.1016/j.apsusc.2019.144761 ↗
89. Investigation of morphology and texture properties of WSi2 coatings on W substrate based on contact-mode AFM and EBSD10.1016/j.surfcoat.2020.125966 ↗
90. Microstructure and oxidation resistance of Si-MoSi2 ceramic coating on TZM (Mo-0.5Ti-0.1Zr-0.02C) alloy at 1500 °C10.1016/j.surfcoat.2021.128037 ↗
91. Formation of MoSi2 and Si/MoSi2 coatings on TZM (Mo–0.5Ti–0.1Zr–0.02C) alloy by hot dip silicon-plating method10.1016/j.ceramint.2021.05.020 ↗