Nanostructured Cellulose Acetate Membranes Embedded with Al2O3 Nanoparticles for Sustainable Wastewater Treatment
Source abstract
Abstract
Electrospun nanofiber membranes based on cellulose acetate (CA) have gained increasing attention for wastewater treatment due to their high surface area, tuneable structure, and ease of functionalization. In this study, the performance of CA membranes was enhanced by incorporating aluminum oxide (Al2O3) nanoparticles (NPs) at varying concentrations (0–2 wt.%). The structural, morphological, and thermal properties of the resulting CA/Al2O3 nanocomposite membranes were investigated through FTIR, XRD, SEM, water contact angle (WCA), pore size measurements, and DSC analyses. FTIR and XRD confirmed strong interactions and the uniform dispersion of the Al2O3 NPs within the CA matrix. The incorporation of Al2O3 improved membrane hydrophilicity, reducing the WCA from 107° to 35°, and increased the average pore size from 0.62 µm to 0.86 µm. These modifications led to enhanced filtration performance, with the membrane containing 2 wt.% Al2O3 achieving a 99% removal efficiency for Indigo Carmine (IC) dye, a maximum adsorption capacity of 45.59 mg/g, and a high permeate flux of 175.47 L·m−2 h−1 bar−1. Additionally, phytotoxicity tests using Lactuca sativa seeds showed a significant increase in germination index from 20% (untreated) to 88% (treated), confirming the safety of the permeate for potential reuse in agricultural irrigation. These results highlight the effectiveness of Al2O3-modified CA electrospun membranes for sustainable wastewater treatment and water reuse.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Membrane Separation Technologies · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Physical Chemistry Laboratory of Mineral Materials and their Applications, National Center for Research in Materials Sciences, Technopark Borj Cedria, P.O. Box 73, Soliman 8027, Tunisia
Institute on Membrane Technology (CNR-ITM), Via P. Bucci 17 c, 87036 Rende, CS, Italy
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