journal article·2026-02-08Open access

Sub-Ablative Femtosecond Laser Modification of the Nonlinear Optical Response of Amorphous TiO2 Thin Films

Victoria Atanassova, Georgi Yankov, Krum Shumanov, Stefan Karatodorov, Ilko Miloushev, Tihomir Tenev, Ekaterina Iordanova, Velichka Strijkova, Vesela Katrova, Ivan Zahariev

Coatings· Volume 16· Issue 2

Abstract

Femtosecond laser processing has emerged as a promising post-deposition method for tailoring the properties of dielectric thin films, offering localized modification without thermal damage. This study investigates the effect of sub-ablative femtosecond laser irradiation on the nonlinear optical response of a TiO2 single-layer coating deposited on soda-lime glass by electron-beam evaporation. The coating was modified using 35 fs pulses at 800 nm delivered at a repetition rate of 1 kHz and a fluence of 0.083 J/cm2 while varying the number of pulses per spot. The effective nonlinear refractive index (n2,eff) and effective nonlinear absorption coefficient (βeff) were measured using the z-scan technique with femtosecond excitation. The as-deposited TiO2 coating exhibited a negative effective nonlinear refractive index, signifying a self-defocusing nonlinear response, while femtosecond laser irradiation leads to pronounced changes in the effective nonlinear parameters. An increase in the magnitude of both effective nonlinear coefficients and a reversal of the sign of the effective nonlinear refractive index are experimentally observed after irradiation with higher pulse numbers. These findings provide experimental evidence that sub-ablative femtosecond laser processing can be used as a post-deposition tool to control the nonlinear optical response of TiO2 thin films.
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Research context

OpenAlex topics: Nonlinear Optical Materials Studies · Laser Material Processing Techniques · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Georgi Nadjakov Institute of Solid State Physics, Bulgarian Academy of Sciences, 72 Tzarigradsko Chaussee Blvd, 1784 Sofia, Bulgaria

Institute of Optical Materials and Technologies “Acad. Yordan Malinovski”, Bulgarian Academy of Sciences, “Acad. G. Bontchev” Str. 109, 1113 Sofia, Bulgaria

Rostislaw Kaischew Institute of Physical Chemistry, Bulgarian Academy of Sciences, Akad. G. Bonchev Str., bl. 11, 1113 Sofia, Bulgaria

Funding

BULGARIAN NATIONAL SCIENCE FUND

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