Research on the Thickness and Microstructure of Plate-like TiO2 by the Nanosheet-Seeding Growth Technique

The nanosheet-seeding growth (NSG) technique is an interesting synthesis method for preparing two-dimensional (2D) materials by employing ultrathin nanosheets as templates. In this work, the synthesis of 2D TiO2 nanoplates using Ti0.87O2 nanosheets via the NSG process is thoroughly studied to achieve a better understanding of this process. The influence of various synthesis conditions on the morphology and phase composition has been carefully examined. The study of synthesis time reveals that the TiO2 grows in the Stranski–Krastanov mode on the templates and the growth follows second-order kinetics. It is also found that the concentration of precursors and the synthesis time are the effective parameters in controlling the thickness of TiO2 nanoplates. The phase of the sample changes from anatase TiO2 to NH4TiOF3 and the morphology changes from flake to disk with the increase in the precursor concentration. The synthesis temperature has a large influence on the morphology and thickness of the sample but has little effect on the phase composition. However, the synthesis temperature changes the color of the sample, and a high temperature enlarges the light absorption range of the sample.