Assessing of New Coatings for Iron Artifacts Conservation by Recurrence Plots Analysis
Source abstract
Abstract
Cast iron has stood for centuries of invention. It is a very versatile and durable material. Coating systems are a low-maintenance protection method. The purpose of this research is to increase the Paraloid coating’s resistance when applied to iron in high humidity atmospheres, with the addition of caffeine (1,3,7-dimethylxanthine) and nicotine (S)-3-(1-methylpyrrolidin-2-yl) pyridine as corrosion inhibitors; the resistance of protection versus exposure time will be evaluated by using electrochemical noise. A statistical analysis of the electrochemical noise signals was carried out. Recurrence plots were used as a powerful tool in the analysis to complement the data obtained and they predicted the evaluation of coatings behaviors performance versus time. The outcomes show that the addition of inhibitors increases and improves the performance as a temporary protection of Paraloid and that protection in high relative humidity was improved. Recurrence plots and parameter quantification show the variances in the surface corrosion dynamics.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · Non-Destructive Testing Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Departamento de Ingeniería Metalúrgica, Facultad de Química, Universidad Nacional Autónoma de México, C.U., Ciudad de Mexico, C.P. 04510, Mexico
Centro de Investigación en Corrosión (CICORR), Universidad Autónoma de Campeche, Av. A. Melgar s/n, Col. Buenavista, Campeche, Cam, C.P. 24030, Mexico
Funding
Consejo Nacional de Ciencia y Tecnología
References (46)
Show source-provided references
1. Caple, C. (2012). Conservation Skills: Judgement, Method and Decision Making, Routledge.10.4324/9780203086261 ↗
2. Aspects of chemical research in conservation: The deterioration process10.1179/019713694806124784 ↗
3. González, M.L.G., and Gomez, M.L. (1998). La Restauración: Examen Científico Aplicado a la Conservación de Obras de arte, Cátedra. (In Spanish).
4. Garcia, E., and Díaz, S. (2011). Técnicas Metodológicas Aplicadas a la Conservación-Restauración del Patrimonio Metálico, Ministerio de Cultura. (In Spanish).
5. A complementary set of electrochemical and X-ray synchrotron techniques to determine the passivation mechanism of iron treated in a new corrosion inhibitor solution specifically developed for the preservation of metallic artefacts10.1007/s00339-010-5674-4 ↗
6. Dillmann, P., Beranger, G., Piccardo, P., and Matthiessen, H. (2014). Corrosion of Metallic Heritage Artefacts: Investigation, Conservation and Prediction of Long Term Behaviour, Elsevier.
7. Cano, E., and Lafuente, D. (2013). Corrosion inhibitors for the preservation of metallic heritage artefacts. Corrosion and Conservation of Cultural Heritage Metallic Artefacts, Elsevier.10.1533/9781782421573.5.570 ↗
8. Complexing agent study via computational chemistry for environmentally friendly silver electrodeposition and the application of a silver deposit10.1039/C4RA05869K ↗
9. Evaluation of new non-toxic corrosion inhibitors for conservation of iron artefacts10.1179/147842210X12732285051311 ↗
10. Electrochemical characterization of organic coatings for protection of historic steel artefacts10.1007/s10008-009-0907-1 ↗
11. Satri, V. (2011). Green Corrosion Inhibitors: Theory and Practice, John Wiley & Sons.10.1002/9781118015438 ↗
12. Struggle against corrosion: Protection by triazoles compounds of ancient and modern bronzes covered with patina
13. Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media10.1016/j.arabjc.2012.01.015 ↗
14. Inhibitory action of Phyllanthus amarus extracts on the corrosion of mild steel in acidic media10.1016/j.corsci.2008.05.009 ↗
15. Electrochemical impedance and electrical resistance sensors for the evaluation of anticorrosive coating degradation10.1515/corrrev-2016-0055 ↗
16. Assessing atmospheric corrosion of metals by a novel electrochemical sensor combining with a thin insulating net using electrochemical noise technique10.1016/j.snb.2017.05.179 ↗
17. Electrochemical noise monitoring of the atmospheric corrosion of steels: Identifying corrosion form using wavelet analysis
18. The application of organic coatings in conservation of archaeological objects excavated from the sea10.1016/j.porgcoat.2016.05.001 ↗
19. In situ study of coatings using embedded electrodes for ENM measurements10.1016/S0300-9440(02)00186-8 ↗
20. Electrochemical noise analysis of polyurethane-coated steel subjected to erosion-corrosion10.1016/S0043-1648(99)00226-4 ↗
21. Analysis of electrochemical impedance and noise data for polymer coated metals10.1016/S0010-938X(97)83346-X ↗
22. Characterization of coatings performance using electrochemical noise-analysis10.1016/0033-0655(91)80019-F ↗
23. On the interpretation of the electrochemical noise data for coatings10.1016/S0300-9440(00)00096-5 ↗
24. Methyl-modified hybrid organic-inorganic coatings for the conservation of copper10.1016/j.culher.2013.06.002 ↗
25. Testing coatings for enameled metal artifacts
26. Developments in the electrochemical noise method (ENM) to make it more practical for assessment of anti-corrosive coatings10.1016/j.electacta.2013.09.067 ↗
27. (2014). ASTM b499–09 Standard Test Method for Measurement of Coating Thicknesses by the Magnetic Method: Nonmagnetic Coatings on Magnetic Basis Metals, ASTM International.
28. Electrochemical sensors for atmospheric corrosion rates—A new design10.1179/000705984798273399 ↗
29. Electrochemical sensor for in-situ monitoring of coated metals degradation under atmospheric conditions
30. (2012). ASTM e104–02 Standard Practice for Maintaining Constant Relative Humidity by Means of Aqueous Solutions, ASTM International.
31. Shot noise and statistical parameters for the estimation of corrosion mechanisms10.1016/j.corsci.2005.05.047 ↗
32. Noise resistance applied to corrosion measurements I. Theoretical analysis10.1149/1.1837361 ↗
33. Kearns, J.R., and Metals, A.C.G. (1996). Electrochemical Noise Measurement for Corrosion Applications, ASTM.10.1520/STP1277-EB ↗
34. Cottis, R., and Turgoose, S. (1999). Electrochemical Impedance and Noise, NACE International.
35. Developments of the electrochemical noise method (ENM) for more practical assessment of anti-corrosion coatings10.1016/j.porgcoat.2006.09.017 ↗
36. Localization index obtained from electrochemical noise analysis10.5006/1.3283926 ↗
37. Measures for the detection of localized corrosion with electrochemical noise10.1016/S0013-4686(01)00645-4 ↗
38. The electrochemical noise technique—Applications in corrosion research10.1063/1.2036830 ↗
39. From fuzzy recurrence plots to scalable recurrence networks of time series10.1209/0295-5075/118/20003 ↗
40. Recurrence plots of dynamical systems10.1209/0295-5075/4/9/004 ↗
41. Embeddings and delays as derived from quantification of recurrence plots10.1016/0375-9601(92)90426-M ↗
42. Recurrence quantification analysis of the logistic equation with transients10.1016/S0375-9601(96)00741-4 ↗
43. Chaos versus noise in experimental data10.1142/S021812749300060X ↗
44. Application of recurrence plots as a new tool in the analysis of electrochemical oscillations of copper10.1016/j.jelechem.2005.03.046 ↗
45. Webber, C.L., Ioana, C., and Marwan, N. (2016). Recurrence Plots and Their Quantifications: Expanding Horizons, Springer International Publishing.10.1007/978-3-319-29922-8 ↗
46. Webber, C.L., and Marwan, N. (2014). Recurrence Quantification Analysis: Theory and Best Practices, Springer.10.1007/978-3-319-07155-8 ↗