journal article·2017-10-01Open access

Chemical Vapor Deposition of Bi-Te-Ni-Fe on Magnesium Oxide Substrate and Its Seebeck Effect

Yong Gan, Anan Hamdan, Jeremy Gan, Mingheng Li

Coatings· Volume 7· Issue 10

Abstract

In this work, a Bi-Te-Ni-Fe complex coating material was obtained on magnesium oxide substrate by a single step ambient pressure chemical vapor deposition (CVD). Nickel acetate, bismuth acetate, iron (III) nitrate, and tellurium (IV) chloride dissolved in N,N-dimethylformamide (DMF) served as the metal sources for Ni, Bi, Fe, and Te, respectively. Hydrogen was used as the carrier gas. The substrate was kept at 500 °C in a quartz tube reaction chamber. The chemical vapor deposition time was two hours. Scanning electron microscopic observation revealed porous morphology of the deposited material with a needle-like submicron fine structure. These needle-like entities form networks with fairly uniform distribution on the substrate. Thermoelectric property test showed that the coating is p-type with a Seebeck coefficient of 179 µV/K. Time-dependent potential data were obtained to show the sensitivity of the Seebeck effect to temperature changes.
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Research context

OpenAlex topics: Advanced Thermoelectric Materials and Devices · Advanced Thermodynamics and Statistical Mechanics · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Mechanical Engineering, College of Engineering, California State Polytechnic University, Pomona, 3801 W Temple Avenue, Pomona, CA 91768, USA

Department of Electromechanical Engineering Technology, California State Polytechnic University, Pomona, 3801 W Temple Avenue, Pomona, CA 91768, USA

Diamond Bar High School, 21400 Pathfinder Road, Diamond Bar, CA 91765, USA

Department of Chemical and Materials Engineering, California State Polytechnic University, Pomona, 3801 W Temple Avenue, Pomona, CA 91768, USA

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