journal article·2022-09-28Open access

Comparative Analysis of Raman Signal Amplifying Effectiveness of Silver Nanostructures with Different Morphology

Dzmitry Yakimchuk, Soslan Khubezhov, Uladzislau Prigodich, Daria Tishkevich, Sergei Trukhanov, Alex Trukhanov, Vladimir Sivakov, Egor Kaniukov

Coatings· Volume 12· Issue 10

Abstract

To increase the attractiveness of the practical application of molecular sensing methods, the experimental search for the optimal shape of silver nanostructures allowing to increase the Raman cross section by several orders of magnitude is of great interest. This paper presents a detailed study of spatially separated plasmon-active silver nanostructures grown in SiO2/Si template pores with crystallite, dendrite, and “sunflower-like” nanostructures shapes. Nile blue and 2-mercaptobenzothiazole were chosen as the model analytes for comparative evaluation of the Raman signal amplification efficiency using these structures. It was discussed the features of the structures for the enhancement of Raman intensity. Finally, we showed that silver crystals, dendrites, and “sunflower-like” nanostructures in SiO2/Si template could be used as the relevant materials for Raman signal amplification, but with different efficiency.
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Research context

OpenAlex topics: Gold and Silver Nanoparticles Synthesis and Applications · Nonlinear Optical Materials Studies · Plasmonic and Surface Plasmon Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Scientific-Practical Materials Research Centre of NAS of Belarus, 19 St. P.Brovka, 220072 Minsk, Belarus

Southern Federal University, 2 St. Shevchenko, 347922 Taganrog, Russia

ITMO University, 9 St. Lomonosova, 191002 St. Petersburg, Russia

North Ossetian State University, 44-46 St. Vatutina, 362025 Vladikavkaz, Russia

Laboratory of Single Crystal Growth, South Ural State University, 454080 Chelyabinsk, Russia

Department of electronic Materials technology, National University of Science and Technology MISiS, 119049 Moscow, Russia

Leibniz Institute of Photonic Technology, Albert-Einstein Str. 9, 07745 Jena, Germany

Funding

Belarusian Foundation for Basic Research · Scientific-technical program ‘Technology-SG’ · RFBR and BRFBR · Ministry of Science and Higher Education of the Russian Federation

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