journal article·2023-07-14

Palladium-Nanoparticle-Decorated Covalent Organic Framework Nanosheets for Effective Hydrogen Gas Sensors

Valle Krishnaveni, Marilyn Esclance DMello, Priyabrata Sahoo, Nany Thokala, Vasudeva Rao Bakuru, Kiran Vankayala, Keloth Basavaiah, Suresh Babu Kalidindi

ACS Applied Nano Materials· Volume 6· Issue 13
Publisher page

Abstract

Covalent organic frameworks (COFs) are attractive for chemical sensing applications because their structures contain delocalized π electrons and active sites that are evenly distributed. COF-based chemical sensors are largely restricted to luminescence and absorption-based mechanisms of sensing. The present study demonstrates the potentiality of exfoliated COF nanosheets hybridized with palladium nanoparticles (Pd NPs) for effective chemiresistive H 2 sensing, for the first time. The hybridization of Pd NPs with the nanosheets of an imine-based covalent organic framework ( e Pd@TpPa-SO 3 H COF) has turned an innocent bulk COF into an effective chemiresistive H 2 sensor.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Andhra University, Visakhapatnam 530003, India

Materials Science Division, Poornaprajna Institute of Scientific Research, Bidalur Post, Devanahalli, Bengaluru 562110, India

Energy Materials Laboratory, Centre for Nano and Soft Matter Sciences, Bengaluru 562162, India

IMCN, MOST, Université catholique de Louvain, Ottignies-Louvain-la-Neuve 1348, Belgium

Department of Chemistry, Birla Institute of Technology and Science, Pilani, K. K. Birla Goa Campus, Goa 403726, India

Central Tribal University of Andhra Pradesh (CTUAP), AU PG Centre, Kondakarakam Village Cantonment Area, Vizianagaram, Andhra Pradesh 535 003, India

Funding

University Grants Commission · Science and Engineering Research Board

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