journal article·2007-10-31

Star-Shaped Oligofluorenes End-Capped with Carboxylic Groups: Syntheses and Self-Assembly at the Liquid–Solid Interface

Zhun Ma, Yan-Yan Wang, Pei Wang, Wei Huang, Yi-Bao Li, Sheng-Bin Lei, Yan-Lian Yang, Xiao-Lin Fan, Chen Wang

ACS Nano· Volume 1· Issue 3
Publisher page

Abstract

A series of star-shaped oligofluorenes end-capped with carboxylic acid groups were synthesized. Different numbers of carboxyl groups that can form hydrogen bonds, and long alkane chains that have stabilizing effects, were intentionally introduced. The resulting molecular architectures of the so-prepared star-shaped oligofluorenes at the liquid-solid interface were investigated by scanning tunneling microscopy. It is found that the number of hydrogen-bonding groups and the symmetry of the target molecules have crucial influences on the structures of the ordered assemblies.
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Research context

OpenAlex topics: Surface Chemistry and Catalysis · Molecular Junctions and Nanostructures · Block Copolymer Self-Assembly

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Advanced Materials, Fudan University, Shanghai 200433, China

Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210003, China

National Center of Nanoscience and Technology, Beijing 100080, China

College of Chemistry and Life Science, Gannan Normal University, Jiangxi 341000, China

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