Hydroxyapatite coating on micropore-formed titanium alloy utilizing electrochemical deposition

Abstract The purpose of this study was to investigate hydroxyapatite coatings on micropore-formed titanium alloy, utilizing an electrochemical deposition method. A commercially pure titanium surface was used as a substrate for calcium phosphate (CaP) deposition on micropores formed after anodization. Prepared surfaces were anodized in 1 M H 3 PO 4 solution, and CaP deposition was performed with a potentiostat at cathodic potential in an electrolyte containing 0.042 M Ca(NO 3 ) 2 and 0.025 M NH 4 H 2 PO 4 . Micropores acted as growth sites for nanophase CaP crystals. Flake-like CaP and needle-like CaP were observed at 25 °C and 85 °C, respectively. If the specimen was not heat-treated, octacalcium phosphate and hydroxyapatite were observed, whereas slight CaP decomposition to tricalcium phosphate occurred with heat treatment at 700 °C. The phenomena involved in CaP deposition were affected by the electrolyte temperature for both morphology and nucleation site.