journal article·2016-10

Al doping effect on the morphological, structural and photocatalytic properties of TiO2 thin layers

F. Bensouici, M. Bououdina, A.A. Dakhel, T. Souier, R. Tala-Ighil, M. Toubane, A. Iratni, S. Liu, W. Cai

Thin Solid Films· Volume 616
Publisher page

Abstract

Abstract In this study, Al-doped TiO2 films are deposited by sol-gel dip-coating method. Structure, surface morphology, optical properties and photocatalytic degradation of Methylene blue have been investigated. The films are characterized by X-ray diffraction (XRD), atomic force microscopy (AFM), UV–Visible spectroscopy and scanning electron microscope (SEM) equipped with electron dispersive X-ray (EDX). XRD analysis confirms the formation of single nanocrystalline anatase phase. The crystallite size is in the order of 17 nm and seems not affected by the presence of Al. AFM analysis reveals that the surface topography of TiO2:Al films is significantly affected by Al content. The optical properties are found not affected and all TiO2:Al thin films show high visible infrared transmission and high optical gap energy. The phocatalytic efficiency has been improved by Al doping; with the highest degradation rate of methylene blue observed for TiO2:0.2% Al.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: TiO2 Photocatalysis and Solar Cells · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Synthesis, characterization and photocatalytic activity of CuO nanoflowers10.1016/j.saa.2013.02.028 ↗
2. Efficient catalytic effect of CuO nanostructures on the degradation of organic dyes10.1016/j.jpcs.2012.07.005 ↗
3. Photocatalytic degration of organic dyes under visible light irradiation by floral-like LaFeO3 nanostructures comprised of nanosheet petals10.1039/C4NJ01029A ↗
4. Photocatalytic properties of WO3 nanoparticles obtained by precipitation in presence of urea as complexing agent10.1016/j.apcata.2011.03.034 ↗
5. Environmental applications of semiconductor photocatalysis10.1021/cr00033a004 ↗
6. Singlet oxygen formation in photocatalytic TiO2 aqueous suspension10.1039/b405084c ↗
7. Photocatalytic OH radical formation in TiO2 aqueous suspension studied by several detection methods10.1039/B307433A ↗
8. Singlet oxygen photogeneration at surface modified titanium dioxide10.1021/ja065970m ↗
9. Behavior of superoxide radicals formed on TiO2 powder photocatalysts studied by a chemiluminescent probe method10.1039/b108441k ↗
10. Photoinduced changes of adsorbed water on a TiO2 photocatalytic film as studied by 1H NMR spectroscopy10.1021/jp035526v ↗
11. Titanium dioxide photocatalysis: present situation and future approaches10.1016/j.crci.2005.02.055 ↗
12. Heterogeneous photocatalysis: from water photolysis to applications in environmental cleanup10.1016/j.ijhydene.2006.09.009 ↗
13. Light-induced amphiphilic surfaces10.1038/41233 ↗
14. Electronic and optical of anatase TiO210.1103/PhysRevB.61.7459 ↗
15. Optical properties of rutile near its fundamental band gap10.1103/PhysRevB.51.6842 ↗
16. Electrochemical comparative study of titania (anatase, brookite and rutile) nanoparticles synthesized in aqueous medium10.1016/j.tsf.2003.11.150 ↗
17. Catalytic activity of Au nanoparticles10.1016/S1748-0132(07)70113-5 ↗
18. The nature of defects in fluorine-doped TiO210.1021/jp8004184 ↗
19. Visible light induced water cleavage in colloidal solutions of chromium-doped titanium dioxide particles10.1021/ja00375a010 ↗
20. Cobalt ion-doped TiO2 photocatalyst response to visible light10.1006/jcis.1999.6694 ↗
21. Visible light driven V-doped TiO2 photocatalyst and its photooxidation of ethanol10.1021/jp004295e ↗
22. Fe3+-TiO2 photocatalysts prepared by combining sol–gel method with hydrothermal treatment and their characterization10.1016/j.jphotochem.2005.10.017 ↗
23. Switching redox site of photocatalytic reaction on titanium (IV) oxide particles modified with transition-metal ion controlled by irradiation wavelength10.1016/j.apcata.2008.06.040 ↗
24. Development of a visible-light-responsive rutile rod by site-selective modification of iron(III) ion on {111} exposed crystal faces10.1016/j.apcatb.2010.03.030 ↗
25. A review on the visible light active titanium dioxide photocatalysts for environmental applications10.1016/j.apcatb.2012.05.036 ↗
26. Synthesis of M@TiO2 (M=Au, Pd, Pt) core–shell nanocomposites with tunable photoreactivity10.1021/jp2009989 ↗
27. Visible-light-induced photocatalysis through surface plasmon excitation of gold on titania surfaces10.1039/b917399d ↗
28. Plasmonic enhancement of photocatalytic decomposition of methyl orange under visible light10.1016/j.jcat.2010.11.001 ↗
29. Size effects of gold nanaoparticles on plasmon-induced photocurrents of gold–TiO2 nanocomposites10.1039/B610720F ↗
30. Improving the photocatalytic performance of mesoporous titania films by modification with gold nanostructures10.1021/jp900766g ↗
31. Comparative study of the photo-deposition of Pt, Au and Pd on pre-sulphated TiO2 for the photocatalytic decomposition of phenol10.1016/j.jphotochem.2010.10.020 ↗
32. Mechanisms and applications of plasmon-induced charge separation at TiO2 films loaded with gold nanoparticles10.1021/ja042192u ↗
33. Study of Au/Au3+-TiO2photocatalysts toward visible photo-oxidation for water and waste water treatment10.1021/es001752w ↗
34. Kinetics of hydrogen production upon reduction of aqueous TiO2 nanoparticles catalyzed by Pd0, Pt0, or Au0 coatings and an unusual hydrogen abstraction; steady state and pulse radiolysis study10.1021/jp060971m ↗
35. Photocatalytic performance of plasma sprayed Pt-modified TiO2 coatings under visible light irradiation10.1016/j.catcom.2006.09.023 ↗
36. Preparation and photocatalytic properties of Fe3+-doped Ag@TiO2 core–shell nanoparticles10.1016/j.jcis.2008.03.043 ↗
37. A novel deposition precipitation method for preparation of Ag-loaded titanium dioxide10.1007/s10562-005-5863-5 ↗
38. Synthesis, characterization and photocatalytic behavior of Ag doped TiO2 thin film10.1016/j.spmi.2015.05.028 ↗
39. Effect of acid nature in the starting solution on surface and photocatalytic properties of TiO2 thin films10.1016/j.surfcoat.2014.04.021 ↗
40. Swanson · J. Res. Natl. Bur. Stand. · 1951 · 46
41. Kittel · 1996 · 614
42. Synthesis of nano-sized Al doped TiO2 powders using thermal plasma10.1016/j.tsf.2003.12.027 ↗
43. Characterization of individual particles in the phoenix urban aerosol using electron-beam instruments10.1021/es00119a009 ↗
44. Gwyddion: an open-source software for SPM data analysis
45. Extraction of extinction coefficient of weak absorbing thin films from spectral absorption10.1088/0022-3727/22/9/024 ↗
46. Tauc · 1969
47. Investigation of photocatalytic activity of metal-doped TiO2 nanoparticles prepared by Pechini method10.1007/s10971-012-2910-8 ↗
48. Effect of Nb, Cr, Sn additions on gas sensing properties of TiO2 thin films10.1016/S0040-6090(97)00401-X ↗
49. Fogler · 2005
50. Photoinduced reactivity of titanium dioxide10.1016/j.progsolidstchem.2004.08.001 ↗