Preparation and photoelectrochemical properties of a hybrid electrode composed of polypyrrole encapsulated in highly ordered titanium dioxide nanotube array

Abstract We demonstrated in this paper that polypyrrole encapsulated in highly ordered TiO 2 nanotubes array (PPy/TiO 2 NTs) electrode could be obtained via two steps: (1) electrosynthesis of TiO 2 nanotube array in HF solution by anodization method; (2) followed by electropolymerization of pyrrole encapsulated in the TiO 2 nanotubes array. The morphological characteristics and structures of PPy/TiO 2 NTs electrode were examined by field-emission scanning electron microscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy. The photoelectrochemical properties were studied in a three-electrode cell with 0.5 M Na 2 SO 4 solution as supporting electrolyte. The photocurrent was dramatically enhanced on the PPy/TiO 2 NTs electrode, comparing with that on bare TiO 2 NTs electrode. A photocurrent density of 1.52 mA cm − 2 and the incident photon to electron conversion efficiency of 73.21% were obtained under an UV illumination of 10 mW cm − 2 .