DataVXChemNanoMatPaper
journal article·2020-04

An Approach to the Synthesis of a Two‐Dimensional Polymer Using a Preorganized Host‐Guest Network by Self‐Assembly at the Liquid/Solid Interface

Kohei Iritani, Kyohei Kaneko, Kazukuni Tahara, Steven De Feyter, Yoshito Tobe

ChemNanoMat· Volume 6· Issue 4
Publisher page
Source abstract

Abstract

An approach to synthesize a two-dimensional polymer (2DP) by imine bond formation using a preorganized host-guest network at the liquid/solid interface is presented. STM observations at the 1-phenyloctane/highly oriented pyrolytic graphite (HOPG) interface revealed that the guest was observed as a fuzzy feature in the host matrix. By addition of trifluoroacetic acid, the guest molecules became visualized clearly indicating fixation to the host network. Detailed analysis of the distances of the host matrix by STM indicates the imine bond formation in a diagonal direction. However, the bond formation was incomplete meaning that the periodic pattern of 2DP was not achieved. More information can be found in the Full Paper by Yoshito Tobe et al.
Source: openalex_inverted_index · Quality: baseline

Research context

Polymers

OpenAlex topics: Covalent Organic Framework Applications · Conducting polymers and applications · Supramolecular Self-Assembly in Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Division of Frontier Materials Science Graduate School of Engineering Science Osaka University 1-3 Machikaneyama Toyonaka Osaka 560-8531 Japan

Department of Applied Chemistry School of Engineering Tokyo University of Technology 1404-1, Katakura-cho Hachioji Tokyo 192-0982 Japan

Department of Applied Chemistry School of Science and Technology Meiji University 1-1-1 Higashimita, Tama-ku Kawasaki Kanagawa 214-8571 Japan

Department of Chemistry KU Leuven Celestijnenlaan 200F Leuven 3001 Belgium

The Institute of Scientific and Industrial Research Osaka University 8-1, Mihogaoka Ibaraki Osaka 567-0047 Japan

Department of Applied Chemistry National Chiao Tung University 1001 Ta-Hsueh Road Hsinchu 30010 Taiwan

References

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