Large-Area Transfer of Nanometer-Thin C₆₀ Films

Fullerenes, with well-defined molecular structures and high scalability, hold promise as fundamental building blocks for creating a variety of carbon materials. The fabrication and transfer of large-area films with precisely controlled thicknesses and morphologies on desired surfaces are crucial for designing and developing fullerene-based materials and devices. In this work, we present strategies for solid-state transferring C 60 molecular nanometer-thin films, with dimensions of centimeters in lateral size and thicknesses controlled in the range of 1–20 nm, onto various substrates. Furthermore, we have successfully fabricated centimeter-wide graphene/C 60 /graphene heterostructures through layer-by-layer stacking of C 60 and graphene films. This transfer methodology is versatile, allowing for the complete transfer of chemically modified C 60 films, including oxygenated C 60 films and C 60 Pd n organometallic polymer films. Additionally, direct solid-state transfer of C 60 and C 60 Pd n films onto electrode surfaces has enabled their electrocatalytic performance for the hydrogen evolution reaction to be probed directly. This thin-film transfer strategy allows precise manipulation of large-area, ultrathin C 60 films on various substrates, providing a platform for fullerene chemistry and the experimental synthesis of artificial carbon structures.